4-cyanophenylimino heterocycles

ABSTRACT

Herbicidal 4-cyanophenylimino heterocycles of the formula ##STR1## in which R 1  represents hydrogen or halogen, 
     R 2  represents halogen, cyano, hydroxyl, amini, X--R 3 , --N(R 4 )--CO--R 5  or --N(R 4 )--SO 2  R 5 , 
     X represents oxygen, sulphur or a single bond, 
     A represents alkanediyl or alkenediyl each of which is optionally substituted, 
     E represents nitrogen or carbon, and 
     G represents nitrogen or represents carbon which is bonded to hydrogen or alkyl via an exo single bond or to oxygen or sulphur via an exo double bond, with some exceptions.

This application is a division of U.S. Pat. No. 08/321,295 filed on Oct. 11,1994, now abandoned.

The invention relates to novel 4-cyanophenylimino heterocycles, to processes for their preparation, and to their use as herbicides, as well as to novel intermediates for their synthesis.

It is already known that certain halogenoarylimino heterocycles exhibit herbicidal properties (cf. EP-A 238711, EP-A 273417, EP-A 312064, EP-A 410265, EP-A 457714, WO-A 92/21684). However, the herbicidal activity of these known compounds, and their ability to be tolerated by cultivated plants, is not always entirely satisfactory.

Novel 4-cyanophenylimino heterocycles of the general formula (I) ##STR2## have now been found, in which R¹ represents hydrogen or halogen,

R² represents halogen, cyano, hydroxyl, amino, or one of the following groupings --X--R³, --N(R⁴)--CO--R⁵ or --N(R⁴)--SO₂ R⁵, where

X represents oxygen, sulphur or a single bond,

R³ represents alkyl, alkenyl, alkinyl, cycloalkyl, cycloalkylalkyl, aryl, arylalkyl, heterocyclyl or heterocyclylalkyl each of which is optionally substituted,

R⁴ represents hydrogen or alkyl, and

R⁵ represents alkyl, alkenyl, alkinyl, cycloalkyl, cycloalkylalkyl, aryl or arylalkyl each of which is optionally substituted,

A represents alkanediyl or alkenediyl each of which is optionally substituted,

E represents nitrogen or carbon, and

G represents nitrogen or represents carbon which is bonded to hydrogen or alkyl via an exo single bond or to oxygen or sulphur via an exo double bond,

where, for the case where E represents nitrogen, A does not represent optionally substituted trimethylene.

The novel 4-cyanophenylimino heterocycles of the general formula (I) are obtained when

a) substituted thiocarbonylamino compounds of the general formula (II) ##STR3## in which A, R¹ and R² have the abovementioned meanings,

are reacted with oxidizing agents or dehydrogenating agents, optionally in the presence of a reaction auxiliary and optionally in the presence of a diluent, or when

b) substituted thiocarbonylamino compounds of the general formula (III) ##STR4## in which A, R¹ and R² have the abovementioned meanings, are reacted with phosgene, optionally in the presence of a diluent,

or when

c) 4-cyanophenylimino heterocycles of the general formula (Ia) ##STR5## in which R¹, A, E and G have the abovementioned meanings, and

X¹ represents halogen,

are reacted with nucleophilic compounds of the general formulae (IV) or (V)

H--X--R³ (IV) H--N(R⁴)--SO₂ R⁵ (V)

in which

X, R³, R⁴ and R⁵ have the abovementioned meanings,

or with alkali metal salts of these compounds

optionally in the presence of an acid acceptor and optionally in the presence of a diluent.

The novel compounds of the formula (I) may also be obtained by reacting imino heterocycles of the general formula (VI) with 4-halogenobenzonitriles of the general formula (VII) in accordance with the following formula scheme (R¹, R², A, E and G defined as above, X² : halogen): ##STR6##

The novel 4-cyanophenylimino heterocycles of the general formula (I) are notable for their strong and selective herbicidal activity.

In the definitions, the saturated or unsaturated hydrocarbon chains, such as alkyl, alkanediyl, alkenyl, alkenediyl or alkinyl, are in each case straight-chain or branched.

Halogen generally represents fluorine, chlorine, bromine or iodine, preferably represents fluorine, chlorine or bromine, and in particular represents fluorine or chlorine.

The invention preferably relates to compounds of the formula (I) in which

R¹ represents hydrogen, fluorine, chlorine or bromine,

R² represents fluorine, chlorine, bromine, cyano, hydroxyl, amino, or one of the following groupings --X--R³ --, --N(R⁴)--CO--R⁵ or --N (R⁴)--SO₂ R⁵, where

X represents oxygen, sulphur or a single bond,

R³ represents alkyl having 1 to 8 carbon atoms and which is optionally substituted by fluorine, chlorine, bromine, cyano, carboxyl, C₁ -C₄ -alkoxy, C₁ -C₄ -alkoxy-C₁ -C₄ -alkoxy, C₁ -C₄ -alkylthio, C₁ -C₄ -alkylcarbonyl, C₁ -C₄ -alkoxy-carbonyl or C₅ -C₆ -cycloalkyloxycarbonyl,

R³ furthermore represents alkenyl or alkinyl having in each case 2 to 8 carbon atoms and which are in each case optionally substituted by fluorine, chlorine or bromine,

R³ furthermore represents cycloalkyl or cycloalkylalkyl having in each case 3 to 8 carbon atoms in the cycloalkyl moiety and optionally 1 to 4 carbon atoms in the alkyl moiety and which are in each case optionally substituted by fluorine, chlorine, bromine, cyano, carboxyl, C₁ -C₄ -alkyl or C₁ -C₄ -alkoxy-carbonyl, or represents phenyl, benzyl, phenylethyl, phenylpropyl or phenylbutyl each of which is optionally substituted, or represents in each case optionally substituted heterocyclyl, heterocyclylmethyl, heterocyclylethyl, heterocyclylpropyl or heterocyclylbutyl having in each case 3 to 8 ring members, of which at least one is an oxygen, sulphur or nitrogen atom and optionally 1 to 3 are additional nitrogen atoms, where the heterocyclyl group can be saturated or unsaturated and the abovementioned cyclic groups optionally contain substituents from the following list:

halogen, cyano, nitro, carboxyl, carbamoyl, C₁ -C₄ -alkyl, C₁ -C₄ -halogenoalkyl, C₁ -C₄ -alkoxy, C₁ -C₄ -halogenoalkoxy, C₁ -C₄ -alkylthio, C₁ -C₄ -halogenoalkylthio, C₁ -C₄ -alkylsulphinyl, C₁ -C₄ -halogenoalkylsulphinyl, C₁ -C₄ -alkylsulphonyl, C₁ -C₄ -halogenoalkylsulphonyl and C₁ -C₄ -alkoxycarbonyl,

R⁴ represents hydrogen or represents alkyl having 1 to 8 carbon atoms, and

R⁵ represents alkyl having 1 to 8 carbon atoms and which is optionally substituted by fluorine, chlorine, bromine, cyano, carboxyl, C₁ -C₄ -alkoxy, C₁ -C₄ -alkoxy-C₁ -C₄ -alkoxy, C₁ -C₄ -alkylthio, C₁ -C₄ -alkyl-carbonyl or C₁ -C₄ -alkoxy-carbonyl,

R⁵ furthermore represents alkenyl or alkinyl having in each case 2 to 8 carbon atoms and which are in each case optionally substituted by fluorine, chlorine or bromine,

R⁵ furthermore represents cycloalkyl or cycloalkylalkyl having in each case 3 to 8 carbon atoms in the cycloalkyl moiety and optionally 1 to 4 carbon atoms in the alkyl moiety and which are in each case optionally substituted by fluorine, chlorine, bromine, cyano, carboxyl, C₁ -C₄ -alkyl or C₁ -C₄ -alkoxy-carbonyl, or represents aryl or arylalkyl having 6 or 10 carbon atoms in the aryl moiety and optionally 1 to 4 carbon atoms in the alkyl moiety and which are in each case optionally substituted by fluorine, chlorine, bromine, cyano, nitro, carboxyl, carbamoyl, by C₁ -C₄ -alkyl, C₁ -C₄ -alkoxy, C₁ -C₄ -alkylthio, C₁ -C₄ -alkyl-sulphinyl or C₁ -C₄ -alkylsulphonyl (which are in each case optionally substituted by fluorine and/or chlorine), by dimethylaminosulphonyl or diethylaminosulphonyl, by C₁ -C₄ -alkoxy-carbonyl (which is optionally substituted by fluorine, chlorine, bromine, methoxy or ethoxy), by phenyl, phenylmethyl, phenoxy, phenylthio, phenylsulphinyl or phenylsulphonyl (which are in each case optionally substituted by fluorine, chlorine, bromine, cyano, methyl, methoxy, trifluoromethyl, difluoromethoxy and/or trifluoromethoxy),

A represents alkanediyl or alkenediyl having in each case 2 to 6 carbon atoms and which are in each case optionally substituted by fluorine, chlorine, bromine or C₁ -C₄ -alkyl (which is optionally substituted by fluorine and/or chlorine),

E represents nitrogen or carbon, and

G represents nitrogen or carbon which is bonded to hydrogen or C₁ -C₆ -alkyl via an exo single bond, or to oxygen or sulphur via an exo double bond,

where, for the case where E represents nitrogen, A does not represent optionally substituted trimethylene.

The invention relates, in particular, to compounds of the formula (I) in which

R¹ represents hydrogen, fluorine or chlorine,

R² represents fluorine, chlorine, bromine, cyano, hydroxyl, amino, or one of the following groupings --X--R³ --N(R⁴)--CO--R⁵ or --N(R⁴)--SO₂ R⁵, where

X represents oxygen, sulphur or a single bond,

R³ represents methyl, ethyl, n- or i-propyl or n-, i-, s- or t-butyl which are in each case optionally substituted by fluorine, chlorine, bromine, cyano, carboxyl, methoxy, ethoxy, methoxyethoxy, ethoxyethoxy, methylthio, ethylthio, acetyl, propionyl, methoxycarbonyl or ethoxycarbonyl,

R³ furthermore represents allyl, crotonyl, 1-methyl-allyl, propargyl or 1-methyl-propargyl which are in each case optionally substituted by fluorine or chlorine,

R³ furthermore represents cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl, cyclopropylmethyl, cyclobutylmethyl, cyclopentylmethyl or cyclohexylmethyl which are in each case optionally substituted by fluorine, chlorine, methyl, ethyl, n- or i-propyl, methoxycarbonyl or ethoxy-carbonyl,

R⁴ represents hydrogen, methyl, ethyl, n- or i-propyl or n-, i- or s-butyl,

R⁵ represents methyl, ethyl, n- or i-propyl or n-, i-, s- or t-butyl which are in each case optionally substituted by fluorine, chlorine, bromine, cyano, carboxyl, methoxy, ethoxy, methoxyethoxy, ethoxyethoxy, methylthio, ethylthio, acetyl, propionyl, methoxycarbonyl or ethoxycarbonyl,

R⁵ furthermore represents allyl, crotonyl, 1-methyl-allyl, propargyl or 1-methyl-propargyl which are in each case optionally substituted by fluorine or chlorine,

R⁵ furthermore represents cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl, cyclopropylmethyl, cyclobutylmethyl, cyclopentylmethyl or cyclohexylmethyl which are in each case optionally substituted by fluorine, chlorine, methyl, ethyl or n- or i-propyl,

R⁵ furthermore represents phenyl, naphthyl, benzyl or phenylethyl which are in each case optionally substituted by fluorine, chlorine, bromine, cyano, methyl, ethyl, n- or i-propyl, n-, i-, s- or t-butyl, methoxy, ethoxy, methylthio, ethylthio, methylsulphinyl, ethylsulphinyl, methylsulphonyl, ethylsulphonyl, trifluoromethyl, difluoromethoxy, trifluoromethoxy, trifluoromethylthio, trifluoromethylsulphinyl, trifluoromethylsulphonyl, dimethylaminosulphonyl, methoxycarbonyl, ethoxycarbonyl, phenyl, phenoxy or phenylsulphonyl,

A represents propane-1,3-diyl (trimethylene), butane-1,4-diyl (tetramethylene), 1-propene-1,3-diyl, 1-butene-1,4-diyl or 2-butene-1,4-diyl which are in each case optionally substituted by fluorine, chlorine, bromine, methyl, ethyl or n- or i-propyl,

E represents nitrogen or carbon, and

G represents nitrogen or carbon which is bonded to hydrogen, methyl, ethyl, n- or i-propyl or n-, i-, s- or t-butyl via an exo single bond, or to oxygen via an exo double bond,

where, for the case where E represents nitrogen, A does not represent optionally substituted trimethylene.

A particularly preferred group of compounds of the formula (I) are the compounds of the general formula (IA) ##STR7## in which R¹, R² and A have the meaning given above as being particularly preferred.

A further particularly preferred group of compounds of the formula (I) are the compounds of the general formula (IB) ##STR8## in which R¹, R² and A have the meaning given above as being particularly preferred.

Examples of the compounds of the formula (I) according to the invention are listed in Table 1 below. ##STR9##

                                      TABLE 1                                      __________________________________________________________________________     Examples of the compounds of the formula (I)                                   R.sup.1                                                                          R.sup.2            A             E   G                                       __________________________________________________________________________     F OCH(CH.sub.2 F).sub.2                                                                             (CH.sub.2).sub.4                                                                             N   CO                                      F OCH.sub.2C(CH.sub.3)CH.sub.2                                                                      (CH.sub.2).sub.4                                                                             N   CO                                                           (CH.sub.2).sub.4                                                                             N   CO                                      F                                                                                 ##STR10##         (CH.sub.2).sub.4                                                                             N   CO                                      F                                                                                 ##STR11##         (CH.sub.2).sub.4                                                                             N   CO                                      F                                                                                 ##STR12##         (CH.sub.2).sub.4                                                                             N   CO                                      F                                                                                 ##STR13##         (CH.sub.2).sub.4                                                                             N   CO                                      F                                                                                 ##STR14##         (CH.sub.2).sub.4                                                                             N   CO                                      F SCH.sub.2COOC.sub.5 H.sub.11 -n                                                                   (CH.sub.2).sub.4                                                                             N   CO                                      F                                                                                 ##STR15##         (CH.sub.2).sub.4                                                                             N   CO                                      F                                                                                 ##STR16##         (CH.sub.2).sub.4                                                                             N   CO                                      F OCH.sub.2 CH.sub.2OCH(CH.sub.2 F).sub.2                                                           (CH.sub.2).sub.4                                                                             N   CO                                      F SCH(CH.sub.3).sub.2                                                                               (CH.sub.2).sub.4                                                                             N   CO                                      F OCH.sub.2CClCH.sub.2                                                                              (CH.sub.2).sub.4                                                                             N   CO                                      F                                                                                 ##STR17##         (CH.sub.2).sub.4                                                                             N   CO                                      F OCH.sub.2 CN       (CH.sub.2).sub.4                                                                             N   CO                                      F OCH.sub.2 COOC.sub.2 H.sub.4OCH.sub.3                                                             (CH.sub.2).sub.4                                                                             N   CO                                      F OCH.sub.2COOCH(CH.sub.3)COOC.sub.2 H.sub.5                                                        (CH.sub.2).sub.4                                                                             N   CO                                      F OCH.sub.2COOCH.sub.2COOC.sub.2 H.sub.5                                                            (CH.sub.2).sub.4                                                                             N   CO                                      F OCHF.sub.2         (CH.sub.2).sub.4                                                                             N   CO                                      F OCH.sub.2 CH.sub.2OCH.sub.2 CF.sub.3                                                              (CH.sub.2).sub.4                                                                             N   CO                                      F OCH.sub.2 CF.sub.3 (CH.sub.2).sub.4                                                                             N   CO                                      F OCF.sub.3          (CH.sub.2).sub.4                                                                             N   CO                                      F OCH.sub.2 CH(CH.sub.3)OC.sub.2 H.sub.5                                                            (CH.sub.2).sub.4                                                                             N   CO                                      F                                                                                 ##STR18##         (CH.sub.2).sub.4                                                                             N   CO                                      F OCH.sub.2CHCH.sub.2                                                                               (CH.sub.2).sub.4                                                                             N   CO                                      F OH                 (CH.sub.2).sub.4                                                                             N   CO                                      F OCH.sub.2C CH      (CH.sub.2).sub.4                                                                             N   CO                                      F SCH.sub.2 C CH     (CH.sub.2).sub.4                                                                             N   CO                                      F OCH.sub.2 COOC.sub.2 H.sub.5                                                                      (CH.sub.2).sub.4                                                                             N   CO                                      F SC(CH.sub.3).sub.3 (CH.sub.2).sub.4                                                                             N   CO                                      F OCH.sub.2COOC.sub.5 H.sub.11 -n                                                                   (CH.sub.2).sub.4                                                                             N   CO                                      F OCH(CH.sub.3)COOC.sub.2 H.sub.5                                                                   (CH.sub.2).sub.4                                                                             N   CO                                      F OCH.sub.2 CH.sub.2OCH.sub.3                                                                       (CH.sub.2).sub.4                                                                             N   CO                                      F OCH.sub.2 CH.sub.2OC.sub.2 H.sub.5                                                                (CH.sub.2).sub.4                                                                             N   CO                                      F O(CH.sub.2 CH.sub.2 O).sub.2C.sub.2 H.sub.5                                                       (CH.sub.2).sub.4                                                                             N   CO                                      F SC.sub.3 H.sub.7 -n                                                                               (CH.sub.2).sub.4                                                                             N   CO                                      F SC.sub.2 H.sub.5   (CH.sub.2).sub.4                                                                             N   CO                                      F SCH.sub.3          (CH.sub.2).sub.4                                                                             N   CO                                      F SCH.sub.2 COOC.sub.2 H.sub.5                                                                      (CH.sub.2).sub.4                                                                             N   CO                                      F SCH.sub.2 CH.sub.2COOC.sub.2 H.sub.5                                                              (CH.sub.2).sub.4                                                                             N   CO                                      F OCH.sub.2C CCH.sub.3                                                                              (CH.sub.2).sub.4                                                                             N   CO                                      F OCH.sub.2CHCHCl    (CH.sub.2).sub.4                                                                             N   CO                                      F OCH(CH.sub.3)C CH  (CH.sub.2).sub.4                                                                             N   CO                                      F OCH(CH.sub.3)C CCH.sub.3                                                                          (CH.sub.2).sub.4                                                                             N   CO                                      F OCH(CH.sub.3)CHCH.sub.2                                                                           (CH.sub.2).sub.4                                                                             N   CO                                      F OCH.sub.2 CHCHCH.sub.3                                                                            (CH.sub.2).sub.4                                                                             N   CO                                      F OCH.sub.3          (CH.sub.2).sub.4                                                                             N   CO                                      F OC.sub.2 H.sub.5   (CH.sub.2).sub.4                                                                             N   CO                                      F OC.sub.3 H.sub.7 -n                                                                               (CH.sub.2).sub.4                                                                             N   CO                                      F OC.sub.3 H.sub.7 -iso                                                                             (CH.sub.2).sub.4                                                                             N   CO                                      F                                                                                 ##STR19##         (CH.sub.2).sub.4                                                                             N   CO                                      F                                                                                 ##STR20##         (CH.sub.2).sub.4                                                                             N   CO                                      F NHCH.sub.3         (CH.sub.2).sub.4                                                                             N   CO                                      F NHC.sub.2 H.sub.5  (CH.sub.2).sub.4                                                                             N   CO                                      F N(CH.sub.3).sub.2  (CH.sub.2).sub.4                                                                             N   CO                                      F NHCH.sub.2COOC.sub.2 H.sub.5                                                                      (CH.sub.2).sub.4                                                                             N   CO                                      F                                                                                 ##STR21##         (CH.sub.2).sub.4                                                                             N   CO                                      F                                                                                 ##STR22##         (CH.sub.2).sub.4                                                                             N   CO                                      F NHSO.sub.2 CH.sub.3                                                                               (CH.sub.2).sub.4                                                                             N   CO                                      F NHSO.sub.2 C.sub.2 H.sub.5                                                                        (CH.sub.2).sub.4                                                                             N   CO                                      F NHSO.sub.2 C.sub.3 H.sub.7 -n                                                                     (CH.sub.2).sub.4                                                                             N   CO                                      F NHSO.sub.2 C.sub.3 H.sub.7 -i                                                                     (CH.sub.2).sub.4                                                                             N   CO                                      F NHSO.sub.2 C.sub.4 H.sub.9 -n                                                                     (CH.sub.2).sub.4                                                                             N   CO                                      F NHSO.sub.2 C.sub.8 H.sub.17 -n                                                                    (CH.sub.2).sub.4                                                                             N   CO                                      F NHCOCH.sub.3       (CH.sub.2).sub.4                                                                             N   CO                                      F NHCOC.sub.2 H.sub.5                                                                               (CH.sub.2).sub.4                                                                             N   CO                                      F NHCOCF.sub.3       (CH.sub.2).sub.4                                                                             N   CO                                      F N(CH.sub.3)SO.sub.2 CH.sub.3                                                                      (CH.sub.2).sub.4                                                                             N   CO                                      F N(CH.sub.3)SO.sub.2 C.sub.2 H.sub.5                                                               (CH.sub.2).sub.4                                                                             N   CO                                      F N(CH.sub.3)SO.sub.2 C.sub.3 H.sub.7 -n                                                            (CH.sub.2).sub.4                                                                             N   CO                                      F NHSO.sub.2 CF.sub.3                                                                               (CH.sub.2).sub.4                                                                             N   CO                                      F                                                                                 ##STR23##         (CH.sub.2).sub.4                                                                             N   CO                                      F NHSO.sub.2C.sub.4 F.sub.9 -n                                                                      (CH.sub.2).sub.4                                                                             N   CO                                      F N(CH.sub.3)SO.sub.2 CF.sub.3                                                                      (CH.sub.2).sub.4                                                                             N   CO                                      F                                                                                 ##STR24##         (CH.sub.2).sub.4                                                                             N   CO                                      F                                                                                 ##STR25##         (CH.sub.2).sub.4                                                                             N   CO                                      F                                                                                 ##STR26##         (CH.sub.2).sub.4                                                                             N   CO                                      H OCH.sub.2 CF.sub.3 (CH.sub.2).sub.4                                                                             N   CO                                      H OCF.sub.3          (CH.sub.2).sub.4                                                                             N   CO                                      H OCH.sub.2 CH(CH.sub.3)OC.sub.2 H.sub.5                                                            (CH.sub.2).sub.4                                                                             N   CO                                      H                                                                                 ##STR27##         (CH.sub.2).sub.4                                                                             N   CO                                      H OCH.sub.2CHCH.sub.2                                                                               (CH.sub.2).sub.4                                                                             N   CO                                      H OH                 (CH.sub.2).sub.4                                                                             N   CO                                      H OCH.sub.2C CH      (CH.sub.2).sub.4                                                                             N   CO                                      H SCH.sub.2 C CH     (CH.sub.2).sub.4                                                                             N   CO                                      H OCH.sub.2 COOC.sub.2 H.sub.5                                                                      (CH.sub.2).sub.4                                                                             N   CO                                      H SC(CH.sub.3).sub.3 (CH.sub.2).sub.4                                                                             N   CO                                      H OCH.sub.2COOC.sub.5 H.sub.11 -n                                                                   (CH.sub.2).sub.4                                                                             N   CO                                      H OCH(CH.sub.3)COOC.sub.2 H.sub.5                                                                   (CH.sub.2).sub.4                                                                             N   CO                                      H OCH.sub.2 CH.sub.2OCH.sub.3                                                                       (CH.sub.2).sub.4                                                                             N   CO                                      H OCH.sub.2 CH.sub.2OC.sub.2 H.sub.5                                                                (CH.sub.2).sub.4                                                                             N   CO                                      H O(CH.sub.2 CH.sub.2 O).sub.2OC.sub.2 H.sub.5                                                      (CH.sub.2).sub.4                                                                             N   CO                                      H SC.sub.3 H.sub.7 -n                                                                               (CH.sub.2).sub.4                                                                             N   CO                                      H SC.sub.2 H.sub.5   (CH.sub.2).sub.4                                                                             N   CO                                      H SCH.sub.3          (CH.sub.2).sub.4                                                                             N   CO                                      H SCH.sub.2 COOC.sub.2 H.sub.5                                                                      (CH.sub.2).sub.4                                                                             N   CO                                      H SCH.sub.2 CH.sub.2COOC.sub.2 H.sub.5                                                              (CH.sub.2).sub.4                                                                             N   CO                                      H OCH.sub.3 C CCH.sub.3                                                                             (CH.sub.2).sub.4                                                                             N   CO                                      H OCH.sub.2CHCHCl    (CH.sub.2).sub.4                                                                             N   CO                                      H OCH(CH.sub.3)C CH  (CH.sub.2).sub.4                                                                             N   CO                                      H OCH(CH.sub.3)C CCH.sub.3                                                                          (CH.sub.2).sub.4                                                                             N   CO                                      H OCH(CH.sub.3)CHCH.sub.2                                                                           (CH.sub.2).sub.4                                                                             N   CO                                      H OCH.sub.2 CHCHCH.sub.3                                                                            (CH.sub.2).sub.4                                                                             N   CO                                      H OCH.sub.3          (CH.sub.2).sub.4                                                                             N   CO                                      H OC.sub.2 H.sub.5   (CH.sub.2).sub.4                                                                             N   CO                                      H OC.sub.3 H.sub.7 -n                                                                               (CH.sub.2).sub.4                                                                             N   CO                                      H OC.sub.3 H.sub.7 -iso                                                                             (CH.sub.2).sub.4                                                                             N   CO                                      H                                                                                 ##STR28##         (CH.sub.2).sub.4                                                                             N   CO                                      H                                                                                 ##STR29##         (CH.sub.2).sub.4                                                                             N   CO                                      H OCH(CH.sub.2 F).sub.2                                                                             (CH.sub.2).sub.4                                                                             N   CO                                      H OCH.sub.2C(CH.sub.3)CH.sub.2                                                                      (CH.sub.2).sub.4                                                                             N   CO                                      H                                                                                 ##STR30##         (CH.sub.2).sub.4                                                                             N   CO                                      H                                                                                 ##STR31##         (CH.sub.2).sub.4                                                                             N   CO                                      H                                                                                 ##STR32##         (CH.sub.2).sub.4                                                                             N   CO                                      H                                                                                 ##STR33##         (CH.sub.2).sub.4                                                                             N   CO                                      H                                                                                 ##STR34##         (CH.sub.2).sub.4                                                                             N   CO                                      H                                                                                 ##STR35##         (CH.sub.2).sub.4                                                                             N   CO                                      H SCH.sub.2COOC.sub.5 H.sub.11 -n                                                                   (CH.sub.2).sub.4                                                                             N   CO                                      H                                                                                 ##STR36##         (CH.sub.2).sub.4                                                                             N   CO                                      H                                                                                 ##STR37##         (CH.sub.2).sub.4                                                                             N   CO                                      H OCH.sub.2 CH.sub.2OCH(CH.sub.2 F).sub.2                                                           (CH.sub.2).sub.4                                                                             N   CO                                      H SCH(CH.sub.3).sub.2                                                                               (CH.sub.2).sub.4                                                                             N   CO                                      H OCH.sub.2CClCH.sub.2                                                                              (CH.sub.2).sub.4                                                                             N   CO                                      H                                                                                 ##STR38##         (CH.sub.2).sub.4                                                                             N   CO                                      H OCH.sub.2 CN       (CH.sub.2).sub.4                                                                             N   CO                                      H OCH.sub.2 COOC.sub.2 H.sub.4OCH.sub.3                                                             (CH.sub.2).sub.4                                                                             N   CO                                      H OCH.sub.2COOCH(CH.sub.3)COOC.sub.2 H.sub.5                                                        (CH.sub.2).sub.4                                                                             N   CO                                      H OCH.sub.2COOCH.sub.2COOC.sub.2 H.sub.5                                                            (CH.sub.2).sub.4                                                                             N   CO                                      H OCHF.sub.2         (CH.sub.2).sub.4                                                                             N   CO                                      H OCH.sub.2 CH.sub.2OCH.sub.2 CF.sub.3                                                              (CH.sub.2).sub.4                                                                             N   CO                                      H NHCH.sub.3         (CH.sub.2).sub.4                                                                             N   CO                                      H NHC.sub.2 H.sub.5  (CH.sub.2).sub.4                                                                             N   CO                                      H N(CH.sub.3).sub.2  (CH.sub.2).sub.4                                                                             N   CO                                      H NHCH.sub.2COOC.sub.2 H.sub.5                                                                      (CH.sub.2).sub.4                                                                             N   CO                                      H                                                                                 ##STR39##         (CH.sub.2).sub.4                                                                             N   CO                                      H                                                                                 ##STR40##         (CH.sub.2).sub.4                                                                             N   CO                                      H NHSO.sub.2 CH.sub.3                                                                               (CH.sub.2).sub.4                                                                             N   CO                                      H NHSO.sub.2 C.sub.2 H.sub.5                                                                        (CH.sub.2).sub.4                                                                             N   CO                                      H NHSO.sub.2 C.sub.3 H.sub.7 -n                                                                     (CH.sub.2).sub.4                                                                             N   CO                                      H NHSO.sub.2 C.sub.3 H.sub.7 -i                                                                     (CH.sub.2).sub.4                                                                             N   CO                                      H NHSO.sub.2 C.sub.4 H.sub.9 -n                                                                     (CH.sub.2).sub.4                                                                             N   CO                                      H NHSO.sub.2 C.sub.8 H.sub.17 -n                                                                    (CH.sub.2).sub.4                                                                             N   CO                                      H NHCOCH.sub.3       (CH.sub.2).sub.4                                                                             N   CO                                      H NHCOC.sub.2 H.sub.5                                                                               (CH.sub.2).sub.4                                                                             N   CO                                      H NHCOCF.sub.3       (CH.sub.2).sub.4                                                                             N   CO                                      H N(CH.sub.3)SO.sub.2 CH.sub.3                                                                      (CH.sub.2).sub.4                                                                             N   CO                                      H N(CH.sub.3)SO.sub.2 C.sub.2 H.sub.5                                                               (CH.sub.2).sub.4                                                                             N   CO                                      H N(CH.sub.3)SO.sub.2 C.sub.3 H.sub.7 -n                                                            (CH.sub.2).sub.4                                                                             N   CO                                      H NHSO.sub.2 CF.sub.3                                                                               (CH.sub.2).sub.4                                                                             N   CO                                      H                                                                                 ##STR41##         (CH.sub.2).sub.4                                                                             N   CO                                      H NHSO.sub.2C.sub.4 F.sub.9 -n                                                                      (CH.sub.2).sub.4                                                                             N   CO                                      H N(CH.sub.3)SO.sub.2 CF.sub.3                                                                      (CH.sub.2).sub.4                                                                             N   CO                                      H                                                                                 ##STR42##         (CH.sub.2).sub.4                                                                             N   CO                                      H                                                                                 ##STR43##         (CH.sub.2).sub.4                                                                             N   CO                                      H                                                                                 ##STR44##         (CH.sub.2).sub.4                                                                             N   CO                                      Cl                                                                               OCH.sub.2 CF.sub.3 (CH.sub.2).sub.4                                                                             N   CO                                      Cl                                                                               OCF.sub.3          (CH.sub.2).sub.4                                                                             N   CO                                      Cl                                                                               OCH.sub.2 CH(CH.sub.3)OC.sub.2 H.sub.5                                                            (CH.sub.2).sub.4                                                                             N   CO                                      Cl                                                                                ##STR45##         (CH.sub.2).sub.4                                                                             N   CO                                      Cl                                                                               OCH.sub.2CHCH.sub.2                                                                               (CH.sub.2).sub.4                                                                             N   CO                                      Cl                                                                               OH                 (CH.sub.2).sub.4                                                                             N   CO                                      Cl                                                                               OCH.sub.2C CH      (CH.sub.2).sub.4                                                                             N   CO                                      Cl                                                                               SCH.sub.2 C CH     (CH.sub.2).sub.4                                                                             N   CO                                      Cl                                                                               OCH.sub.2 COOC.sub.2 H.sub.5                                                                      (CH.sub.2).sub.4                                                                             N   CO                                      Cl                                                                               SC(CH.sub.3).sub.3 (CH.sub.2).sub.4                                                                             N   CO                                      Cl                                                                               OCH.sub.2COOC.sub.5 H.sub.11 -n                                                                   (CH.sub.2).sub.4                                                                             N   CO                                      Cl                                                                               OCH(CH.sub.3)COOC.sub.2 H.sub.5                                                                   (CH.sub.2).sub.4                                                                             N   CO                                      Cl                                                                               OCH.sub.2 CH.sub.2OCH.sub.3                                                                       (CH.sub.2).sub.4                                                                             N   CO                                      Cl                                                                               OCH.sub.2 CH.sub.2OC.sub.2 H.sub.5                                                                (CH.sub.2).sub.4                                                                             N   CO                                      Cl                                                                               O(CH.sub.2 CH.sub.2 O).sub.2OC.sub.2 H.sub.5                                                      (CH.sub.2).sub.4                                                                             N   CO                                      Cl                                                                               SC.sub.3 H.sub.7 -n                                                                               (CH.sub.2).sub.4                                                                             N   CO                                      Cl                                                                               SC.sub.2 H.sub.5   (CH.sub.2).sub.4                                                                             N   CO                                      Cl                                                                               SCH.sub.3          (CH.sub.2).sub.4                                                                             N   CO                                      Cl                                                                               SCH.sub.2 COOC.sub.2 H.sub.5                                                                      (CH.sub.2).sub.4                                                                             N   CO                                      Cl                                                                               SCH.sub.2 CH.sub.2COOC.sub.2 H.sub.5                                                              (CH.sub.2).sub.4                                                                             N   CO                                      Cl                                                                               OCH.sub.2C CCH.sub.3                                                                              (CH.sub.2).sub.4                                                                             N   CO                                      Cl                                                                               OCH.sub.2CHCHCl    (CH.sub.2).sub.4                                                                             N   CO                                      Cl                                                                               OCH(CH.sub.3)C CH  (CH.sub.2).sub.4                                                                             N   CO                                      Cl                                                                               OCH(CH.sub.3)C CCH.sub.3                                                                          (CH.sub.2).sub.4                                                                             N   CO                                      Cl                                                                               OCH(CH.sub.3)CHCH.sub.2                                                                           (CH.sub.2).sub.4                                                                             N   CO                                      Cl                                                                               OCH.sub.2 CHCHCH.sub.3                                                                            (CH.sub.2).sub.4                                                                             N   CO                                      Cl                                                                               OCH.sub.3          (CH.sub.2).sub.4                                                                             N   CO                                      Cl                                                                               OC.sub.2 H.sub.5   (CH.sub.2).sub.4                                                                             N   CO                                      Cl                                                                               OC.sub.3 H.sub.7 -n                                                                               (CH.sub.2).sub.4                                                                             N   CO                                      Cl                                                                               OC.sub.3 H.sub.7 -iso                                                                             (CH.sub.2).sub.4                                                                             N   CO                                      Cl                                                                                ##STR46##         (CH.sub.2).sub.4                                                                             N   CO                                      Cl                                                                                ##STR47##         (CH.sub.2).sub.4                                                                             N   CO                                      Cl                                                                               OCH(CH.sub.2 F).sub.2                                                                             (CH.sub.2).sub.4                                                                             N   CO                                      Cl                                                                               OCH.sub.2C(CH.sub.3)CH.sub.2                                                                      (CH.sub.2).sub.4                                                                             N   CO                                      Cl                                                                                ##STR48##         (CH.sub.2).sub.4                                                                             N   CO                                      Cl                                                                                ##STR49##         (CH.sub.2).sub.4                                                                             N   CO                                      Cl                                                                                ##STR50##         (CH.sub.2).sub.4                                                                             N   CO                                      Cl                                                                                ##STR51##         (CH.sub.2).sub.4                                                                             N   CO                                      Cl                                                                                ##STR52##         (CH.sub.2).sub.4                                                                             N   CO                                      Cl                                                                                ##STR53##         (CH.sub.2).sub.4                                                                             N   CO                                      Cl                                                                               SCH.sub.2COOC.sub.5 H.sub.11 -n                                                                   (CH.sub.2).sub.4                                                                             N   CO                                      Cl                                                                                ##STR54##         (CH.sub.2).sub.4                                                                             N   CO                                      Cl                                                                                ##STR55##         (CH.sub.2).sub.4                                                                             N   CO                                      Cl                                                                               OCH.sub.2 CH.sub.2OCH(CH.sub.2 F).sub.2                                                           (CH.sub.2).sub.4                                                                             N   CO                                      Cl                                                                               SCH(CH.sub.3).sub.2                                                                               (CH.sub.2).sub.4                                                                             N   CO                                      Cl                                                                               OCH.sub.2CClCH.sub.2                                                                              (CH.sub.2).sub.4                                                                             N   CO                                      Cl                                                                                ##STR56##         (CH.sub.2).sub.4                                                                             N   CO                                      Cl                                                                               OCH.sub.2 CN       (CH.sub.2).sub.4                                                                             N   CO                                      Cl                                                                               OCH.sub.2 COOC.sub.2 H.sub.4OCH.sub.3                                                             (CH.sub.2).sub.4                                                                             N   CO                                      Cl                                                                               OCH.sub.2COOCH(CH.sub.3)COOC.sub.2 H.sub.5                                                        (CH.sub.2).sub.4                                                                             N   CO                                      Cl                                                                               OCH.sub.2 COOCH.sub.2COOC.sub.2 H.sub.5                                                           (CH.sub.2).sub.4                                                                             N   CO                                      Cl                                                                               OCHF.sub.2         (CH.sub.2).sub.4                                                                             N   CO                                      Cl                                                                               OCH.sub.2 CH.sub.2OCH.sub.2 CF.sub.3                                                              (CH.sub.2).sub.4                                                                             N   CO                                      Cl                                                                               NHCH.sub.3         (CH.sub.2).sub.4                                                                             N   CO                                      Cl                                                                               NHC.sub.2 H.sub.5  (CH.sub.2).sub.4                                                                             N   CO                                      Cl                                                                               N(CH.sub.3).sub.2  (CH.sub.2).sub.4                                                                             N   CO                                      Cl                                                                               NHCH.sub.2COOC.sub.2 H.sub.5                                                                      (CH.sub.2).sub.4                                                                             N   CO                                      Cl                                                                                ##STR57##         (CH.sub.2).sub.4                                                                             N   CO                                      Cl                                                                                ##STR58##         (CH.sub.2).sub.4                                                                             N   CO                                      Cl                                                                               NHSO.sub.2 CH.sub.3                                                                               (CH.sub.2).sub.4                                                                             N   CO                                      Cl                                                                               NHSO.sub.2 C.sub.2 H.sub.5                                                                        (CH.sub.2).sub.4                                                                             N   CO                                      Cl                                                                               NHSO.sub.2 C.sub.3 H.sub.7 -n                                                                     (CH.sub.2).sub.4                                                                             N   CO                                      Cl                                                                               NHSO.sub.2 C.sub.3 H.sub.7 -i                                                                     (CH.sub.2).sub.4                                                                             N   CO                                      Cl                                                                               NHSO.sub.2 C.sub.4 H.sub.9 -n                                                                     (CH.sub.2).sub.4                                                                             N   CO                                      Cl                                                                               NHSO.sub.2 C.sub.8 H.sub.17 -n                                                                    (CH.sub.2).sub.4                                                                             N   CO                                      Cl                                                                               NHCOCH.sub.3       (CH.sub.2).sub.4                                                                             N   CO                                      Cl                                                                               NHCOC.sub.2 H.sub.5                                                                               (CH.sub.2).sub.4                                                                             N   CO                                      Cl                                                                               NHCOCF.sub.3       (CH.sub.2).sub.4                                                                             N   CO                                      Cl                                                                               N(CH.sub.3)SO.sub.2 CH.sub.3                                                                      (CH.sub.2).sub.4                                                                             N   CO                                      Cl                                                                               N(CH.sub.3)SO.sub.2 C.sub.2 H.sub.5                                                               (CH.sub.2).sub.4                                                                             N   CO                                      Cl                                                                               N(CH.sub.3)SO.sub.2 C.sub.3 H.sub.7 -n                                                            (CH.sub.2).sub.4                                                                             N   CO                                      Cl                                                                               NHSO.sub.2 CF.sub.3                                                                               (CH.sub.2).sub.4                                                                             N   CO                                      Cl                                                                                ##STR59##         (CH.sub.2).sub.4                                                                             N   CO                                      Cl                                                                               NHSO.sub.2C.sub.4 F.sub.9 -n                                                                      (CH.sub.2).sub.4                                                                             N   CO                                      Cl                                                                               N(CH.sub.3)SO.sub.2 CF.sub.3                                                                      (CH.sub.2).sub.4                                                                             N   CO                                      Cl                                                                                ##STR60##         (CH.sub.2).sub.4                                                                             N   CO                                      Cl                                                                                ##STR61##         (CH.sub.2).sub.4                                                                             N   CO                                      Cl                                                                                ##STR62##         (CH.sub.2).sub.4                                                                             N   CO                                      F OCH(CH.sub.2 F).sub.2                                                                             (CH.sub.2).sub.4                                                                             N   CO                                      F OCH.sub.2C(CH.sub.3)CH.sub.2                                                                      (CH.sub.2).sub.4                                                                             N   CO                                      F                                                                                 ##STR63##         (CH.sub.2).sub.4                                                                             N   CO                                      F                                                                                 ##STR64##         (CH.sub.2).sub.4                                                                             N   CO                                      F                                                                                 ##STR65##         (CH.sub.2).sub.4                                                                             N   CO                                      F                                                                                 ##STR66##         (CH.sub.2).sub.4                                                                             N   CO                                      F                                                                                 ##STR67##         (CH.sub.2).sub.4                                                                             N   CO                                      F                                                                                 ##STR68##         (CH.sub.2).sub.4                                                                             N   CO                                      F SCH.sub.2COOC.sub.5 H.sub.11 -n                                                                   (CH.sub.2).sub.4                                                                             N   CO                                      F                                                                                 ##STR69##         (CH.sub.2).sub.4                                                                             N   CO                                      F                                                                                 ##STR70##         (CH.sub.2).sub.4                                                                             N   CO                                      F OCH.sub.2 CH.sub.2OCH(CH.sub.2 F).sub.2                                                           (CH.sub.2).sub.4                                                                             N   CO                                      F SCH(CH.sub.3).sub.2                                                                               (CH.sub.2).sub.4                                                                             N   CO                                      F OCH.sub.2CClCH.sub.2                                                                              (CH.sub.2).sub.4                                                                             N   CO                                      F                                                                                 ##STR71##         (CH.sub.2).sub.4                                                                             N   CO                                      F OCH.sub.2 CN       (CH.sub.2).sub.4                                                                             N   CO                                      F OCH.sub.2 COOC.sub.2 H.sub.4OCH.sub.3                                                             (CH.sub.2).sub.4                                                                             N   CO                                      F OCH.sub.2COOCH(CH.sub.3)COOC.sub.2 H.sub.5                                                        (CH.sub.2).sub.4                                                                             N   CO                                      F OCH.sub.2COOCH.sub.2COOC.sub.2 H.sub.5                                                            (CH.sub.2).sub.4                                                                             N   CO                                      F OCHF.sub.2         (CH.sub.2).sub.4                                                                             N   CO                                      F OCH.sub.2 CH.sub.2OCH.sub.2 CF.sub.3                                                              (CH.sub.2).sub.4                                                                             N   CO                                      F OCH(CH.sub.2 F).sub.2                                                                             CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      F OCH.sub.2C(CH.sub.3)CH.sub.2                                                                      CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      F                                                                                 ##STR72##         CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      F                                                                                 ##STR73##         CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      F                                                                                 ##STR74##         CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      F                                                                                 ##STR75##         CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      F                                                                                 ##STR76##         CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      F                                                                                 ##STR77##         CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      F SCH.sub.2COOC.sub.5 H.sub.11 -n                                                                   CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      F                                                                                 ##STR78##         CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      F                                                                                 ##STR79##         CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      F OCH.sub.2 CH.sub.2OCH(CH.sub.2 F).sub.2                                                           CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      F SCH(CH.sub.3).sub.2                                                                               CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      F OCH.sub.2CClCH.sub.2                                                                              CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      F                                                                                 ##STR80##         CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      F OCH.sub.2 CN       CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      F OCH.sub.2 COOC.sub.2 H.sub.4OCH.sub.3                                                             CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      F OCH.sub.2COOCH(CH.sub.3)COOC.sub.2 H.sub.5                                                        CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      F OCH.sub.2COOCH.sub.2COOC.sub.2 H.sub.5                                                            CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      F OCHF.sub.2         CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      F OCH.sub.2 CH.sub.2OCH.sub.2 CF.sub.3                                                              CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      F OCH.sub.2 CF.sub.3 CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      F OCF.sub.3          CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      F OCH.sub.2 CH(CH.sub.3)OC.sub.2 H.sub.5                                                            CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      F                                                                                 ##STR81##         CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      F OCH.sub.2CHCH.sub.2                                                                               CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      F OH                 CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      F OCH.sub.2C CH      CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      F SCH.sub.2 C CH     CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      F OCH.sub.2 COOC.sub.2 H.sub.5                                                                      CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      F SC(CH.sub.3).sub.3 CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      F OCH.sub.2COOC.sub.5 H.sub.11 -n                                                                   CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      F OCH(CH.sub.3)COOC.sub.2 H.sub.5                                                                   CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      F OCH.sub.2 CH.sub.2OCH.sub.3                                                                       CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      F OCH.sub.2 CH.sub.2OC.sub.2 H.sub.5                                                                CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      F O(CH.sub.2 CH.sub.2 O).sub.2OC.sub.2 H.sub.5                                                      CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      F SC.sub.3 H.sub.7 -n                                                                               CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      F SC.sub.2 H.sub.5   CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      F SCH.sub.3          CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      F SCH.sub.2 COOC.sub.2 H.sub.5                                                                      CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      F SCH.sub.2 CH.sub.2COOC.sub.2 H.sub.5                                                              CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      F OCH.sub.2C CCH.sub.3                                                                              CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      F OCH.sub.2CHCHCl    CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      F OCH(CH.sub.3)C CH  CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      F OCH(CH.sub.3)C CCH.sub.3                                                                          CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      F OCH(CH.sub.3)CHCH.sub.2                                                                           CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      F OCH.sub.2 CHCHCH.sub.3                                                                            CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      F OCH.sub.3          CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      F OC.sub.2 H.sub.5   CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      F OC.sub.3 H.sub.7 -n                                                                               CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      F OC.sub.3 H.sub.7 -iso                                                                             CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      F                                                                                 ##STR82##         CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      F                                                                                 ##STR83##         CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      F NHCH.sub.3         CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      F NHC.sub.2 H.sub.5  CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      F N(CH.sub.3).sub.2  CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      F NHCH.sub.2COOC.sub.2 H.sub.5                                                                      CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      F                                                                                 ##STR84##         CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      F                                                                                 ##STR85##         CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      F NHSO.sub.2 CH.sub.3                                                                               CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      F NHSO.sub.2 C.sub.2 H.sub.5                                                                        CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      F NHSO.sub.2 C.sub.3 H.sub.7 -n                                                                     CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      F NHSO.sub.2 C.sub.3 H.sub.7 -i                                                                     CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      F NHSO.sub.2 C.sub.4 H.sub.9 -n                                                                     CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      F NHSO.sub.2 C.sub.8 H.sub.17 -n                                                                    CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      F NHCOCH.sub.3       CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      F NHCOC.sub.2 H.sub.5                                                                               CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      F NHCOCF.sub.3       CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      F N(CH.sub.3)SO.sub.2 CH.sub.3                                                                      CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      F N(CH.sub.3)SO.sub.2 C.sub.2 H.sub.5                                                               CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      F N(CH.sub.3)SO.sub.2 C.sub.3 H.sub.7 -n                                                            CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      F NHSO.sub.2 CF.sub.3                                                                               CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      F                                                                                 ##STR86##         CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      F NHSO.sub.2C.sub.4 F.sub.9 -n                                                                      CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      F N(CH.sub.3)SO.sub.2 CF.sub.3                                                                      CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      F                                                                                 ##STR87##         CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      F                                                                                 ##STR88##         CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      F                                                                                 ##STR89##         CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      H OCH.sub.2 CF.sub.3 CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      H OCF.sub.3          CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      H OCH.sub.2 CH(CH.sub.3)OC.sub.2 H.sub.5                                                            CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      H                                                                                 ##STR90##         CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      H OCH.sub.2CHCH.sub.2                                                                               CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      H OH                 CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      H OCH.sub.2C CH      CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      H SCH.sub.2 C CH     CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      H OCH.sub.2 COOC.sub.2 H.sub.5                                                                      CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      H SC(CH.sub.3).sub.3 CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      H OCH.sub.2COOC.sub.5 H.sub.11 -n                                                                   CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      H OCH(CH.sub.3)COOC.sub.2 H.sub.5                                                                   CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      H OCH.sub.2 CH.sub.2OCH.sub.3                                                                       CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      H OCH.sub.2 CH.sub.2OC.sub.2 H.sub.5                                                                CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      H O(CH.sub.2 CH.sub.2 O).sub.2OC.sub.2 H.sub.5                                                      CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      H SC.sub.3 H.sub.7 -n                                                                               CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      H SC.sub.2 H.sub.5   CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      H SCH.sub.3          CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      H SCH.sub.2 COOC.sub.2 H.sub.5                                                                      CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      H SCH.sub.2 CH.sub.2COOC.sub.2 H.sub.5                                                              CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      H OCH.sub.2C CCH.sub.3                                                                              CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      H OCH.sub.2CHCHCl    CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      H OCH(CH.sub.3)C CH  CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      H OCH(CH.sub.3)C CCH.sub.3                                                                          CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      H OCH(CH.sub.3)CHCH.sub.2                                                                           CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      H OCH.sub.2 CHCHCH.sub.3                                                                            CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      H OCH.sub.3          CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      H OC.sub.2 H.sub.5   CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      H OC.sub.3 H.sub.7 -n                                                                               CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      H OC.sub.3 H.sub.7 -iso                                                                             CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      H                                                                                 ##STR91##         CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      H                                                                                 ##STR92##         CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      H OCH(CH.sub.2 F).sub.2                                                                             CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      H OCH.sub.2C(CH.sub.3)CH.sub.2                                                                      CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      H                                                                                 ##STR93##         CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      H                                                                                 ##STR94##         CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      H                                                                                 ##STR95##         CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      H                                                                                 ##STR96##         CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      H                                                                                 ##STR97##         CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      H                                                                                 ##STR98##         CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      H SCH.sub.2COOC.sub.5 H.sub.11 -n                                                                   CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      H                                                                                 ##STR99##         CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      H                                                                                 ##STR100##        CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      H OCH.sub.2 CH.sub.2OCH(CH.sub.2 F).sub.2                                                           CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      H SCH(CH.sub.3).sub.2                                                                               CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      H OCH.sub.2CClCH.sub.2                                                                              CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      H                                                                                 ##STR101##        CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      H OCH.sub.2 CN       CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      H OCH.sub.2 COOC.sub.2 H.sub.4OCH.sub.3                                                             CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      H OCH.sub.2COOCH(CH.sub.3)COOC.sub.2 H.sub.5                                                        CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      H OCH.sub.2COOCH.sub.2COOC.sub.2 H.sub.5                                                            CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      H OCHF.sub.2         CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      H OCH.sub.2 CH.sub.2OCH.sub.2 CF.sub.3                                                              CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      H NHCH.sub.3         CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      H NHC.sub.2 H.sub.5  CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      H N(CH.sub.3).sub.2  CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      H NHCH.sub.2COOC.sub.2 H.sub.5                                                                      CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      H                                                                                 ##STR102##        CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      H                                                                                 ##STR103##        CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      H NHSO.sub.2 CH.sub.3                                                                               CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      H NHSO.sub.2 C.sub.2 H.sub.5                                                                        CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      H NHSO.sub.2 C.sub.3 H.sub.7 -n                                                                     CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      H NHSO.sub.2 C.sub.3 H.sub.7 -i                                                                     CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      H NHSO.sub.2 C.sub.4 H.sub.9 -n                                                                     CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      H NHSO.sub.2 C.sub.8 H.sub.17 -n                                                                    CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      H NHCOCH.sub.3       CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      H NHCOC.sub.2 H.sub.5                                                                               CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      H NHCOCF.sub.3       CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      H N(CH.sub.3)SO.sub.2 CH.sub.3                                                                      CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      H N(CH.sub.3)SO.sub.2 C.sub.2 H.sub.5                                                               CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      H N(CH.sub.3)SO.sub.2 C.sub.3 H.sub.7 -n                                                            CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      H NHSO.sub.2 CF.sub.3                                                                               CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      H                                                                                 ##STR104##        CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      H NHSO.sub.2C.sub.4 F.sub.9 -n                                                                      CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      H N(CH.sub.3)SO.sub.2 CF.sub.3                                                                      CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      H                                                                                 ##STR105##        CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      H                                                                                 ##STR106##        CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      H                                                                                 ##STR107##        CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      Cl                                                                               OCH.sub.2 CF.sub.3 CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      Cl                                                                               OCF.sub.3          CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      Cl                                                                               OCH.sub.2 CH(CH.sub.3)OC.sub.2 H.sub.5                                                            CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      Cl                                                                                ##STR108##        CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      Cl                                                                               OCH.sub.2CHCH.sub.2                                                                               CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      Cl                                                                               OH                 CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      Cl                                                                               OCH.sub.2C CH      CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      Cl                                                                               SCH.sub.2 C CH     CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      Cl                                                                               OCH.sub.2 COOC.sub.2 H.sub.5                                                                      CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      Cl                                                                               SC(CH.sub.3).sub.3 CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      Cl                                                                               OCH.sub.2COOC.sub.5 H.sub.11 -n                                                                   CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      Cl                                                                               OCH(CH.sub.3)COOC.sub.2 H.sub.5                                                                   CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      Cl                                                                               OCH.sub.2 CH.sub.2OCH.sub.3                                                                       CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      Cl                                                                               OCH.sub.2 CH.sub.2OC.sub.2 H.sub.5                                                                CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      Cl                                                                               O(CH.sub.2 CH.sub.2 O).sub.2OC.sub.2 H.sub.5                                                      CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      Cl                                                                               SC.sub.3 H.sub.7 -n                                                                               CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      Cl                                                                               SC.sub.2 H.sub.5   CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      Cl                                                                               SCH.sub.3          CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      Cl                                                                               SCH.sub.2 COOC.sub.2 H.sub.5                                                                      CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      Cl                                                                               SCH.sub.2 CH.sub.2COOC.sub.2 H.sub.5                                                              CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      Cl                                                                               OCH.sub.2C CCH.sub.3                                                                              CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      Cl                                                                               OCH.sub.2CHCHCl    CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      Cl                                                                               OCH(CH.sub.3)C CH  CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      Cl                                                                               OCH(CH.sub.3)C CCH.sub.3                                                                          CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      Cl                                                                               OCH(CH.sub.3)CHCH.sub.2                                                                           CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      Cl                                                                               OCH.sub.2 CHCHCH.sub.3                                                                            CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      Cl                                                                               OCH.sub.3          CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      Cl                                                                               OC.sub.2 H.sub.5   CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      Cl                                                                               OC.sub.3 H.sub.7 -n                                                                               CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      Cl                                                                               OC.sub.3 H.sub.7 -iso                                                                             CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      Cl                                                                                ##STR109##        CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      Cl                                                                                ##STR110##        CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      Cl                                                                               OCH(CH.sub.2 F).sub.2                                                                             CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      Cl                                                                               OCH.sub.2C(CH.sub.3)CH.sub.2                                                                      CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      Cl                                                                                ##STR111##        CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      Cl                                                                                ##STR112##        CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      Cl                                                                                ##STR113##        CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      Cl                                                                                ##STR114##        CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      Cl                                                                                ##STR115##        CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      Cl                                                                                ##STR116##        CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      Cl                                                                               SCH.sub.2COOC.sub.5 H.sub.11 -n                                                                   CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      Cl                                                                                ##STR117##        CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      Cl                                                                                ##STR118##        CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      Cl                                                                               OCH.sub.2 CH.sub.2OCH(CH.sub.2 F).sub.2                                                           CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      Cl                                                                               SCH(CH.sub.3).sub.2                                                                               CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      Cl                                                                               OCH.sub.2CClCH.sub.2                                                                              CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      Cl                                                                                ##STR119##        CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      Cl                                                                               OCH.sub.2 CN       CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      Cl                                                                               OCH.sub.2 COOC.sub.2 H.sub.4OCH.sub.3                                                             CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      Cl                                                                               OCH.sub.2COOCH(CH.sub.3)COOC.sub.2 H.sub.5                                                        CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      Cl                                                                               OCH.sub.2COOCH.sub.2COOC.sub.2 H.sub.5                                                            CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      Cl                                                                               OCHF.sub.2         CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      Cl                                                                               OCH.sub.2 CH.sub.2OCH.sub.2 CF.sub.3                                                              CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      Cl                                                                               NHCH.sub.3         CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      Cl                                                                               NHC.sub.2 H.sub.5  CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      Cl                                                                               N(CH.sub.3).sub.2  CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      Cl                                                                               NHCH.sub.2COOC.sub.2 H.sub.5                                                                      CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      Cl                                                                                ##STR120##        CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      Cl                                                                                ##STR121##        CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      Cl                                                                               NHSO.sub.2 CH.sub.3                                                                               CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      Cl                                                                               NHSO.sub.2 C.sub.2 H.sub.5                                                                        CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      Cl                                                                               NHSO.sub.2 C.sub.3 H.sub.7 -n                                                                     CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      Cl                                                                               NHSO.sub.2 C.sub.3 H.sub.7 -i                                                                     CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      Cl                                                                               NHSO.sub.2 C.sub.4 H.sub.9 -n                                                                     CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      Cl                                                                               NHSO.sub.2 C.sub.8 H.sub.17 -n                                                                    CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      Cl                                                                               NHCOCH.sub.3       CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      Cl                                                                               NHCOC.sub.2 H.sub.5                                                                               CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      Cl                                                                               NHCOCF.sub.3       CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      Cl                                                                               N(CH.sub.3)SO.sub.2 CH.sub.3                                                                      CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      Cl                                                                               N(CH.sub.3)SO.sub.2 C.sub.2 H.sub.5                                                               CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      Cl                                                                               N(CH.sub.3)SO.sub.2 C.sub.3 H.sub.7 -n                                                            CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      Cl                                                                               NHSO.sub.2 CF.sub.3                                                                               CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      Cl                                                                                ##STR122##        CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      Cl                                                                               NHSO.sub.2C.sub.4 F.sub.9 -n                                                                      CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      Cl                                                                               N(CH.sub.3)SO.sub.2 CF.sub.3                                                                      CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      Cl                                                                                ##STR123##        CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      Cl                                                                                ##STR124##        CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      Cl                                                                                ##STR125##        CH.sub.2CHCHCH.sub.2                                                                         N   CO                                      F OCH(CH.sub.2 F).sub.2                                                                             (CH.sub.2).sub.2CHCH                                                                         N   CO                                      F OCH.sub.2C(CH.sub.3)CH.sub.2                                                                      (CH.sub.2).sub.2CHCH                                                                         N   CO                                      F                                                                                 ##STR126##        (CH.sub.2).sub.2CHCH                                                                         N   CO                                      F                                                                                 ##STR127##        (CH.sub.2).sub.2CHCH                                                                         N   CO                                      F                                                                                 ##STR128##        (CH.sub.2).sub.2CHCH                                                                         N   CO                                      F                                                                                 ##STR129##        (CH.sub.2).sub.2CHCH                                                                         N   CO                                      F                                                                                 ##STR130##        (CH.sub.2).sub.2CHCH                                                                         N   CO                                      F                                                                                 ##STR131##        (CH.sub.2).sub.2CHCH                                                                         N   CO                                      F SCH.sub.2COOC.sub.5 H.sub.11 -n                                                                   (CH.sub.2).sub.2CHCH                                                                         N   CO                                      F                                                                                 ##STR132##        (CH.sub.2).sub.2CHCH                                                                         N   CO                                      F                                                                                 ##STR133##        (CH.sub.2).sub.2CHCH                                                                         N   CO                                      F OCH.sub.2 CH.sub.2OCH(CH.sub.2 F).sub.2                                                           (CH.sub.2).sub.2CHCH                                                                         N   CO                                      F SCH(CH.sub.3).sub.2                                                                               (CH.sub.2).sub.2CHCH                                                                         N   CO                                      F OCH.sub.2CClCH.sub.2                                                                              (CH.sub.2).sub.2CHCH                                                                         N   CO                                      F                                                                                 ##STR134##        (CH.sub.2).sub.2CHCH                                                                         N   CO                                      F OCH.sub.2 CN       (CH.sub.2).sub.2CHCH                                                                         N   CO                                      F OCH.sub.2 COOC.sub.2 H.sub.4OCH.sub.3                                                             (CH.sub.2).sub.2CHCH                                                                         N   CO                                      F OCH.sub.2COOCH(CH.sub.3)COOC.sub.2 H.sub.5                                                        (CH.sub.2).sub.2CHCH                                                                         N   CO                                      F OCH.sub.2COOCH.sub.2COOC.sub.2 H.sub.5                                                            (CH.sub.2).sub.2CHCH                                                                         N   CO                                      F OCHF.sub.2         (CH.sub.2).sub.2CHCH                                                                         N   CO                                      F OCH.sub.2 CH.sub.2OCH.sub.2 CF.sub.3                                                              (CH.sub.2).sub.2CHCH                                                                         N   CO                                      F OCH.sub.2 CF.sub.3 (CH.sub.2).sub.2CHCH                                                                         N   CO                                      F OCF.sub.3          (CH.sub.2).sub.2CHCH                                                                         N   CO                                      F OCH.sub.2 CH(CH.sub.3)OC.sub.2 H.sub.5                                                            (CH.sub.2).sub.2CHCH                                                                         N   CO                                      F                                                                                 ##STR135##        (CH.sub.2).sub.2CHCH                                                                         N   CO                                      F OCH.sub.2CHCH.sub.2                                                                               (CH.sub.2).sub.2CHCH                                                                         N   CO                                      F OH                 (CH.sub.2).sub.2CHCH                                                                         N   CO                                      F OCH.sub.2C CH      (CH.sub.2).sub.2CHCH                                                                         N   CO                                      F SCH.sub.2 C CH     (CH.sub.2).sub.2CHCH                                                                         N   CO                                      F OCH.sub.2 COOC.sub.2 H.sub.5                                                                      (CH.sub.2).sub.2CHCH                                                                         N   CO                                      F SC(CH.sub.3).sub.3 (CH.sub.2).sub.2CHCH                                                                         N   CO                                      F OCH.sub.2COOC.sub.5 H.sub.11 -n                                                                   (CH.sub.2).sub.2CHCH                                                                         N   CO                                      F OCH(CH.sub.3)COOC.sub.2 H.sub.5                                                                   (CH.sub.2).sub.2CHCH                                                                         N   CO                                      F OCH.sub.2 CH.sub.2OCH.sub.3                                                                       (CH.sub.2).sub.2CHCH                                                                         N   CO                                      F OCH.sub.2 CH.sub.2OC.sub.2 H.sub.5                                                                (CH.sub.2).sub.2CHCH                                                                         N   CO                                      F O(CH.sub.2 CH.sub.2 O).sub.2OC.sub.2 H.sub.5                                                      (CH.sub.2).sub.2CHCH                                                                         N   CO                                      F SC.sub.3 H.sub.7 -n                                                                               (CH.sub.2).sub.2CHCH                                                                         N   CO                                      F SC.sub.2 H.sub.5   (CH.sub.2).sub.2CHCH                                                                         N   CO                                      F SCH.sub.3          (CH.sub.2).sub.2CHCH                                                                         N   CO                                      F SCH.sub.2 COOC.sub.2 H.sub.5                                                                      (CH.sub.2).sub.2CHCH                                                                         N   CO                                      F SCH.sub.2 CH.sub.2COOC.sub.2 H.sub.5                                                              (CH.sub.2).sub.2CHCH                                                                         N   CO                                      F OCH.sub.2C CCH.sub.3                                                                              (CH.sub.2).sub.2CHCH                                                                         N   CO                                      F OCH.sub.2CHCHCl    (CH.sub.2).sub.2CHCH                                                                         N   CO                                      F OCH(CH.sub.3)C CH  (CH.sub.2).sub.2CHCH                                                                         N   CO                                      F OCH(CH.sub.3)C CCH.sub.3                                                                          (CH.sub.2).sub.2CHCH                                                                         N   CO                                      F OCH(CH.sub.3)CHCH.sub.2                                                                           (CH.sub.2).sub.2CHCH                                                                         N   CO                                      F OCH.sub.2 CHCHCH.sub.3                                                                            (CH.sub.2).sub.2CHCH                                                                         N   CO                                      F OCH.sub.3          (CH.sub.2).sub.2CHCH                                                                         N   CO                                      F OC.sub.2 H.sub.5   (CH.sub.2).sub.2CHCH                                                                         N   CO                                      F OC.sub.3 H.sub.7 -n                                                                               (CH.sub.2).sub.2CHCH                                                                         N   CO                                      F OC.sub.3 H.sub.7 -iso                                                                             (CH.sub.2).sub.2CHCH                                                                         N   CO                                      F                                                                                 ##STR136##        (CH.sub.2).sub.2CHCH                                                                         N   CO                                      F                                                                                 ##STR137##        (CH.sub.2).sub.2CHCH                                                                         N   CO                                      F NHCH.sub.3         (CH.sub.2).sub.2CHCH                                                                         N   CO                                      F NHC.sub.2 H.sub.5  (CH.sub.2).sub.2CHCH                                                                         N   CO                                      F N(CH.sub.3).sub.2  (CH.sub.2).sub.2CHCH                                                                         N   CO                                      F NHCH.sub.2COOC.sub.2 H.sub.5                                                                      (CH.sub.2).sub.2CHCH                                                                         N   CO                                      F                                                                                 ##STR138##        (CH.sub.2).sub.2CHCH                                                                         N   CO                                      F                                                                                 ##STR139##        (CH.sub.2).sub.2CHCH                                                                         N   CO                                      F NHSO.sub.2 CH.sub.3                                                                               (CH.sub.2).sub.2CHCH                                                                         N   CO                                      F NHSO.sub.2 C.sub.2 H.sub.5                                                                        (CH.sub.2).sub.2CHCH                                                                         N   CO                                      F NHSO.sub.2 C.sub.3 H.sub.7 -n                                                                     (CH.sub.2).sub.2CHCH                                                                         N   CO                                      F NHSO.sub.2 C.sub.3 H.sub.7 -i                                                                     (CH.sub.2).sub.2CHCH                                                                         N   CO                                      F NHSO.sub.2 C.sub.4 H.sub.9 -n                                                                     (CH.sub.2).sub.2CHCH                                                                         N   CO                                      F NHSO.sub.2 C.sub.8 H.sub.17 -n                                                                    (CH.sub.2).sub.2CHCH                                                                         N   CO                                      F NHCOCH.sub.3       (CH.sub.2).sub.2CHCH                                                                         N   CO                                      F NHCOC.sub.2 H.sub.5                                                                               (CH.sub.2).sub.2CHCH                                                                         N   CO                                      F NHCOCF.sub.3       (CH.sub.2).sub.2CHCH                                                                         N   CO                                      F N(CH.sub.3)SO.sub.2 CH.sub.3                                                                      (CH.sub.2).sub.2CHCH                                                                         N   CO                                      F N(CH.sub.3)SO.sub.2 C.sub.2 H.sub.5                                                               (CH.sub.2).sub.2CHCH                                                                         N   CO                                      F N(CH.sub.3)SO.sub.2 C.sub.3 H.sub.7 -n                                                            (CH.sub.2).sub.2CHCH                                                                         N   CO                                      F NHSO.sub.2 CF.sub.3                                                                               (CH.sub.2).sub.2CHCH                                                                         N   CO                                      F                                                                                 ##STR140##        (CH.sub.2).sub.2CHCH                                                                         N   CO                                      F NHSO.sub.2C.sub.4 F.sub.9 -n                                                                      (CH.sub.2).sub.2CHCH                                                                         N   CO                                      F N(CH.sub.3)SO.sub.2 CF.sub.3                                                                      (CH.sub.2).sub.2CHCH                                                                         N   CO                                      F                                                                                 ##STR141##        (CH.sub.2).sub.2CHCH                                                                         N   CO                                      F                                                                                 ##STR142##        (CH.sub.2).sub.2CHCH                                                                         N   CO                                      F                                                                                 ##STR143##        (CH.sub.2).sub.2CHCH                                                                         N   CO                                      H OCH.sub.2 CF.sub.3 (CH.sub.2).sub.2CHCH                                                                         N   CO                                      H OCF.sub.3          (CH.sub.2).sub.2CHCH                                                                         N   CO                                      H OCH.sub.2 CH(CH.sub.3)OC.sub.2 H.sub.5                                                            (CH.sub.2).sub.2CHCH                                                                         N   CO                                      H                                                                                 ##STR144##        (CH.sub.2).sub.2CHCH                                                                         N   CO                                      H OCH.sub.2CHCH.sub.2                                                                               (CH.sub.2).sub.2CHCH                                                                         N   CO                                      H OH                 (CH.sub.2).sub.2CHCH                                                                         N   CO                                      H OCH.sub.2C CH      (CH.sub.2).sub.2CHCH                                                                         N   CO                                      H SCH.sub.2 C CH     (CH.sub.2).sub.2CHCH                                                                         N   CO                                      H OCH.sub.2 COOC.sub.2 H.sub.5                                                                      (CH.sub.2).sub.2CHCH                                                                         N   CO                                      H SC(CH.sub.3).sub.3 (CH.sub.2).sub.2CHCH                                                                         N   CO                                      H OCH.sub.2COOC.sub.5 H.sub.11 -n                                                                   (CH.sub.2).sub.2CHCH                                                                         N   CO                                      H OCH(CH.sub.3)COOC.sub.2 H.sub.5                                                                   (CH.sub.2).sub.2CHCH                                                                         N   CO                                      H OCH.sub.2 CH.sub.2OCH.sub.3                                                                       (CH.sub.2).sub.2CHCH                                                                         N   CO                                      H OCH.sub.2 CH.sub.2OC.sub.2 H.sub.5                                                                (CH.sub.2).sub.2CHCH                                                                         N   CO                                      H O(CH.sub.2 CH.sub.2 O).sub.2OC.sub.2 H.sub.5                                                      (CH.sub.2).sub.2CHCH                                                                         N   CO                                      H SC.sub.3 H.sub.7 n (CH.sub.2).sub.2CHCH                                                                         N   CO                                      H SC.sub.2 H.sub.5   (CH.sub.2).sub.2CHCH                                                                         N   CO                                      H SCH.sub.3          (CH.sub.2).sub.2CHCH                                                                         N   CO                                      H SCH.sub.2 COOC.sub.2 H.sub.5                                                                      (CH.sub.2).sub.2CHCH                                                                         N   CO                                      H SCH.sub.2 CH.sub.2COOC.sub.2 H.sub.5                                                              (CH.sub.2).sub.2CHCH                                                                         N   CO                                      H OCH.sub.2C CCH.sub.3                                                                              (CH.sub.2).sub.2CHCH                                                                         N   CO                                      H OCH.sub.2CHCHCl    (CH.sub.2).sub.2CHCH                                                                         N   CO                                      H OCH(CH.sub.3)C CH  (CH.sub.2).sub.2CHCH                                                                         N   CO                                      H OCH(CH.sub.3)C CCH.sub.3                                                                          (CH.sub.2).sub.2CHCH                                                                         N   CO                                      H OCH(CH.sub.3)CHCH.sub.2                                                                           (CH.sub.2).sub.2CHCH                                                                         N   CO                                      H OCH.sub.2 CHCHCH.sub.3                                                                            (CH.sub.2).sub.2CHCH                                                                         N   CO                                      H OCH.sub.3          (CH.sub.2).sub.2CHCH                                                                         N   CO                                      H OC.sub.2 H.sub.5   (CH.sub.2).sub.2CHCH                                                                         N   CO                                      H OC.sub.3 H.sub.7 -n                                                                               (CH.sub.2).sub.2CHCH                                                                         N   CO                                      H OC.sub.3 H.sub.7 -iso                                                                             (CH.sub.2).sub.2CHCH                                                                         N   CO                                      H                                                                                 ##STR145##        (CH.sub.2).sub.2CHCH                                                                         N   CO                                      H                                                                                 ##STR146##        (CH.sub.2).sub.2CHCH                                                                         N   CO                                      H OCH(CH.sub.2 F).sub.2                                                                             (CH.sub.2).sub.2CHCH                                                                         N   CO                                      H OCH.sub.2C(CH.sub.3)CH.sub.2                                                                      (CH.sub.2).sub.2CHCH                                                                         N   CO                                      H                                                                                 ##STR147##        (CH.sub.2).sub.2CHCH                                                                         N   CO                                      H                                                                                 ##STR148##        (CH.sub.2).sub.2CHCH                                                                         N   CO                                      H                                                                                 ##STR149##        (CH.sub.2).sub.2CHCH                                                                         N   CO                                      H                                                                                 ##STR150##        (CH.sub.2).sub.2CHCH                                                                         N   CO                                      H                                                                                 ##STR151##        (CH.sub.2).sub.2CHCH                                                                         N   CO                                      H                                                                                 ##STR152##        (CH.sub.2).sub.2CHCH                                                                         N   CO                                      H SCH.sub.2COOC.sub.5 H.sub.11 -n                                                                   (CH.sub.2).sub.2CHCH                                                                         N   CO                                      H                                                                                 ##STR153##        (CH.sub.2).sub.2CHCH                                                                         N   CO                                      H                                                                                 ##STR154##        (CH.sub.2).sub.2CHCH                                                                         N   CO                                      H OCH.sub.2 CH.sub.2OCH(CH.sub.2 F).sub.2                                                           (CH.sub.2).sub.2CHCH                                                                         N   CO                                      H SCH(CH.sub.3).sub.2                                                                               (CH.sub.2).sub.2CHCH                                                                         N   CO                                      H OCH.sub.2CClCH.sub.2                                                                              (CH.sub.2).sub.2CHCH                                                                         N   CO                                      H                                                                                 ##STR155##        (CH.sub.2).sub.2CHCH                                                                         N   CO                                      H OCH.sub.2 CN       (CH.sub.2).sub.2CHCH                                                                         N   CO                                      H OCH.sub.2 COOC.sub.2 H.sub.4OCH.sub.3                                                             (CH.sub.2).sub.2CHCH                                                                         N   CO                                      H OCH.sub.2COOCH(CH.sub.3)COOC.sub.2 H.sub.5                                                        (CH.sub.2).sub.2CHCH                                                                         N   CO                                      H OCH.sub.2COOCH.sub.2COOC.sub.2 H.sub.5                                                            (CH.sub.2).sub.2CHCH                                                                         N   CO                                      H OCHF.sub.2         (CH.sub.2).sub.2CHCH                                                                         N   CO                                      H OCH.sub.2 CH.sub.2OCH.sub.2 CF.sub.3                                                              (CH.sub.2).sub.2CHCH                                                                         N   CO                                      H NHCH.sub.3         (CH.sub.2).sub.2CHCH                                                                         N   CO                                      H NHC.sub.2 H.sub.5  (CH.sub.2).sub.2CHCH                                                                         N   CO                                      H N(CH.sub.3).sub.2  (CH.sub.2).sub.2CHCH                                                                         N   CO                                      H NHCH.sub.2COOC.sub.2 H.sub.5                                                                      (CH.sub.2).sub.2CHCH                                                                         N   CO                                      H                                                                                 ##STR156##        (CH.sub.2).sub.2CHCH                                                                         N   CO                                      H                                                                                 ##STR157##        (CH.sub.2).sub.2CHCH                                                                         N   CO                                      H NHSO.sub.2 CH.sub.3                                                                               (CH.sub.2).sub.2CHCH                                                                         N   CO                                      H NHSO.sub.2 C.sub.2 H.sub.5                                                                        (CH.sub.2).sub.2CHCH                                                                         N   CO                                      H NHSO.sub.2 C.sub.3 H.sub.7 -n                                                                     (CH.sub.2).sub.2CHCH                                                                         N   CO                                      H NHSO.sub.2 C.sub.3 H.sub.7 -i                                                                     (CH.sub.2).sub.2CHCH                                                                         N   CO                                      H NHSO.sub.2 C.sub.4 H.sub.9 -n                                                                     (CH.sub.2).sub.2CHCH                                                                         N   CO                                      H NHSO.sub.2 C.sub.8 H.sub.17 -n                                                                    (CH.sub.2).sub.2CHCH                                                                         N   CO                                      H NHCOOCH.sub.3      (CH.sub.2).sub.2CHCH                                                                         N   CO                                      H NHCOC.sub.2 H.sub.5                                                                               (CH.sub.2).sub.2CHCH                                                                         N   CO                                      H NHCOCF.sub.3       (CH.sub.2).sub.2CHCH                                                                         N   CO                                      H N(CH.sub.3)SO.sub.2 CH.sub.3                                                                      (CH.sub.2).sub.2CHCH                                                                         N   CO                                      H N(CH.sub.3)SO.sub.2 C.sub.2 H.sub.5                                                               (CH.sub.2).sub.2CHCH                                                                         N   CO                                      H N(CH.sub.3)SO.sub.2 C.sub.3 H.sub.7 -n                                                            (CH.sub.2).sub.2CHCH                                                                         N   CO                                      H NHSO.sub.2 CF.sub.3                                                                               (CH.sub.2).sub.2CHCH                                                                         N   CO                                      H                                                                                 ##STR158##        (CH.sub.2).sub.2CHCH                                                                         N   CO                                      H NHSO.sub.2C.sub.4 F.sub.9 -n                                                                      (CH.sub.2).sub.2CHCH                                                                         N   CO                                      H N(CH.sub.3)SO.sub.2 CF.sub.3                                                                      (CH.sub.2).sub.2CHCH                                                                         N   CO                                      H                                                                                 ##STR159##        (CH.sub.2).sub.2CHCH                                                                         N   CO                                      H                                                                                 ##STR160##        (CH.sub.2).sub.2CHCH                                                                         N   CO                                      H                                                                                 ##STR161##        (CH.sub.2).sub.2CHCH                                                                         N   CO                                      Cl                                                                               OCH.sub.2 CF.sub.3 (CH.sub.2).sub.2CHCH                                                                         N   CO                                      Cl                                                                               OCF.sub.3          (CH.sub.2).sub.2CHCH                                                                         N   CO                                      Cl                                                                               OCH.sub.3 CH(CH.sub.3)OC.sub.2 H.sub.5                                                            (CH.sub.2).sub.2CHCH                                                                         N   CO                                      Cl                                                                                ##STR162##        (CH.sub.2).sub.2CHCH                                                                         N   CO                                      Cl                                                                               OCH.sub.2CHCH.sub.2                                                                               (CH.sub.2).sub.2CHCH                                                                         N   CO                                      Cl                                                                               OH                 (CH.sub.2).sub.2CHCH                                                                         N   CO                                      Cl                                                                               OCH.sub.2C CH      (CH.sub.2).sub.2CHCH                                                                         N   CO                                      Cl                                                                               SCH.sub.2 C CH     (CH.sub.2).sub.2CHCH                                                                         N   CO                                      Cl                                                                               OCH.sub.2 COOC.sub.2 H.sub.5                                                                      (CH.sub.2).sub.2CHCH                                                                         N   CO                                      Cl                                                                               SC(CH.sub.3).sub.3 (CH.sub.2).sub.2CHCH                                                                         N   CO                                      Cl                                                                               OCH.sub.2COOC.sub.5 H.sub.11 -n                                                                   (CH.sub.2).sub.2CHCH                                                                         N   CO                                      Cl                                                                               OCH(CH.sub.3)COOC.sub.2 H.sub.5                                                                   (CH.sub.2).sub.2CHCH                                                                         N   CO                                      Cl                                                                               OCH.sub.2 CH.sub.2OCH.sub.3                                                                       (CH.sub.2).sub.2CHCH                                                                         N   CO                                      Cl                                                                               OCH.sub.2 CH.sub.2OC.sub.2 H.sub.5                                                                (CH.sub.2).sub.2CHCH                                                                         N   CO                                      Cl                                                                               O(CH.sub.2 CH.sub.2 O).sub.2OC.sub.2 H.sub.5                                                      (CH.sub.2).sub.2CHCH                                                                         N   CO                                      Cl                                                                               SC.sub.3 H.sub.7 -n                                                                               (CH.sub.2).sub.2CHCH                                                                         N   CO                                      Cl                                                                               SC.sub.2 H.sub.5   (CH.sub.2).sub.2CHCH                                                                         N   CO                                      Cl                                                                               SCH.sub.3          (CH.sub.2).sub.2CHCH                                                                         N   CO                                      Cl                                                                               SCH.sub.2 COOC.sub.2 H.sub.5                                                                      (CH.sub.2).sub.2CHCH                                                                         N   CO                                      Cl                                                                               SCH.sub.2 CH.sub.2COOC.sub.2 H.sub.5                                                              (CH.sub.2).sub.2CHCH                                                                         N   CO                                      Cl                                                                               OCH.sub.2C CCH.sub.3                                                                              (CH.sub.2).sub.2CHCH                                                                         N   CO                                      Cl                                                                               OCH.sub.2CHCHCl    (CH.sub.2).sub.2CHCH                                                                         N   CO                                      Cl                                                                               OCH(CH.sub.3)C CH  (CH.sub.2).sub.2CHCH                                                                         N   CO                                      Cl                                                                               OCH(CH.sub.3)C CCH.sub.3                                                                          (CH.sub.2).sub.2CHCH                                                                         N   CO                                      Cl                                                                               OCH(CH.sub.3)CHCH.sub.2                                                                           (CH.sub.2).sub.2CHCH                                                                         N   CO                                      Cl                                                                               OCH.sub.2 CHCHCH.sub.3                                                                            (CH.sub.2).sub.2CHCH                                                                         N   CO                                      Cl                                                                               OCH.sub.3          (CH.sub.2).sub.2CHCH                                                                         N   CO                                      Cl                                                                               OC.sub.2 H.sub.5   (CH.sub.2).sub.2CHCH                                                                         N   CO                                      Cl                                                                               OC.sub.3 H.sub.7 -n                                                                               (CH.sub.2).sub.2CHCH                                                                         N   CO                                      Cl                                                                               OC.sub.3 H.sub.7 -iso                                                                             (CH.sub.2).sub.2CHCH                                                                         N   CO                                      Cl                                                                                ##STR163##        (CH.sub.2).sub.2CHCH                                                                         N   CO                                      Cl                                                                                ##STR164##        (CH.sub.2).sub.2CHCH                                                                         N   CO                                      Cl                                                                               OCH(CH.sub.2 F).sub.2                                                                             (CH.sub.2)CHCH                                                                               N   CO                                      Cl                                                                               OCH.sub.2C(CH.sub.3)CH.sub.2                                                                      (CH.sub.2)CHCH                                                                               N   CO                                      Cl                                                                                ##STR165##        (CH.sub.2)CHCH                                                                               N   CO                                      Cl                                                                                ##STR166##        (CH.sub.2)CHCH                                                                               N   CO                                      Cl                                                                                ##STR167##        (CH.sub.2)CHCH                                                                               N   CO                                      Cl                                                                                ##STR168##        (CH.sub.2)CHCH                                                                               N   CO                                      Cl                                                                                ##STR169##        (CH.sub.2)CHCH                                                                               N   CO                                      Cl                                                                                ##STR170##        (CH.sub.2)CHCH                                                                               N   CO                                      Cl                                                                               SCH.sub.2COOC.sub.5 H.sub.11 -n                                                                   (CH.sub.2)CHCH                                                                               N   CO                                      Cl                                                                                ##STR171##        (CH.sub.2)CHCH                                                                               N   CO                                      Cl                                                                                ##STR172##        (CH.sub.2)CHCH                                                                               N   CO                                      Cl                                                                               OCH.sub.2 CH.sub.2OCH(CH.sub.2 F).sub.2                                                           (CH.sub.2)CHCH                                                                               N   CO                                      Cl                                                                               SCH(CH.sub.3).sub.2                                                                               (CH.sub.2)CHCH                                                                               N   CO                                      Cl                                                                               OCH.sub.2CClCH.sub.2                                                                              (CH.sub.2)CHCH                                                                               N   CO                                      Cl                                                                                ##STR173##        (CH.sub.2)CHCH                                                                               N   CO                                      Cl                                                                               OCH.sub.2 CN       (CH.sub.2)CHCH                                                                               N   CO                                      Cl                                                                               OCH.sub.2 COOC.sub.2 H.sub.4OCH.sub.3                                                             (CH.sub.2)CHCH                                                                               N   CO                                      Cl                                                                               OCH.sub.2COOCH(CH.sub.3)COOC.sub.2 H.sub.5                                                        (CH.sub.2)CHCH                                                                               N   CO                                      Cl                                                                               OCH.sub.2COOCH.sub.2COOC.sub.2 H.sub.5                                                            (CH.sub.2)CHCH                                                                               N   CO                                      Cl                                                                               OCHF.sub.2         (CH.sub.2)CHCH                                                                               N   CO                                      Cl                                                                               OCH.sub.2 CH.sub.2OCH.sub.2 CF.sub.3                                                              (CH.sub.2)CHCH                                                                               N   CO                                      Cl                                                                               NHCH.sub.3         (CH.sub.2)CHCH                                                                               N   CO                                      Cl                                                                               NHC.sub.2 H.sub.5  (CH.sub.2)CHCH                                                                               N   CO                                      Cl                                                                               N(CH.sub.3).sub.2  (CH.sub.2)CHCH                                                                               N   CO                                      Cl                                                                               NHCH.sub.2COOC.sub.2 H.sub.5                                                                      (CH.sub.2)CHCH                                                                               N   CO                                      Cl                                                                                ##STR174##        (CH.sub.2)CHCH                                                                               N   CO                                      Cl                                                                                ##STR175##        (CH.sub.2)CHCH                                                                               N   CO                                      Cl                                                                               NHSO.sub.2 CH.sub.3                                                                               (CH.sub.2)CHCH                                                                               N   CO                                      Cl                                                                               NHSO.sub.2 C.sub.2 H.sub.5                                                                        (CH.sub.2)CHCH                                                                               N   CO                                      Cl                                                                               NHSO.sub.2 C.sub.3 H.sub.7 -n                                                                     (CH.sub.2)CHCH                                                                               N   CO                                      Cl                                                                               NHSO.sub.2 C.sub.3 H.sub.7 -i                                                                     (CH.sub.2)CHCH                                                                               N   CO                                      Cl                                                                               NHSO.sub.2 C.sub.4 H.sub.9 -n                                                                     (CH.sub.2)CHCH                                                                               N   CO                                      Cl                                                                               NHSO.sub.2 C.sub.8 H.sub.17 -n                                                                    (CH.sub.2)CHCH                                                                               N   CO                                      Cl                                                                               NHCOCH.sub.3       (CH.sub.2)CHCH                                                                               N   CO                                      Cl                                                                               NHCOC.sub.2 H.sub.5                                                                               (CH.sub.2)CHCH                                                                               N   CO                                      Cl                                                                               NHCOCF.sub.3       (CH.sub.2)CHCH                                                                               N   CO                                      Cl                                                                               N(CH.sub.3)SO.sub.2 CH.sub.3                                                                      (CH.sub.2)CHCH                                                                               N   CO                                      Cl                                                                               N(CH.sub.3)SO.sub.2 C.sub.2 H.sub.5                                                               (CH.sub.2)CHCH                                                                               N   CO                                      Cl                                                                               N(CH.sub.3)SO.sub.2 C.sub.3 H.sub.7 -n                                                            (CH.sub.2)CHCH                                                                               N   CO                                      Cl                                                                               NHSO.sub.2 CF.sub.3                                                                               (CH.sub.2)CHCH                                                                               N   CO                                      Cl                                                                                ##STR176##        (CH.sub.2)CHCH                                                                               N   CO                                      Cl                                                                               NHSO.sub.2C.sub.4 F.sub.9 -n                                                                      (CH.sub.2)CHCH                                                                               N   CO                                      Cl                                                                               N(CH.sub.3)SO.sub.2 CF.sub.3                                                                      (CH.sub.2)CHCH                                                                               N   CO                                      Cl                                                                                ##STR177##        (CH.sub.2)CHCH                                                                               N   CO                                      Cl                                                                                ##STR178##        (CH.sub.2)CHCH                                                                               N   CO                                      Cl                                                                                ##STR179##        (CH.sub.2)CHCH                                                                               N   CO                                      F O(CH.sub.2 F).sub.2                                                                               (CH.sub.2).sub.4                                                                              ##STR180##                                                                        N                                       F OCH.sub.2C(CH.sub.3)CH.sub.2                                                                      (CH.sub.2).sub.4                                                                              ##STR181##                                                                        N                                       F                                                                                 ##STR182##        (CH.sub.2).sub.4                                                                              ##STR183##                                                                        N                                       F                                                                                 ##STR184##        (CH.sub.2).sub.4                                                                              ##STR185##                                                                        N                                       F                                                                                 ##STR186##        (CH.sub.2).sub.4                                                                              ##STR187##                                                                        N                                       F                                                                                 ##STR188##        (CH.sub.2).sub.4                                                                              ##STR189##                                                                        N                                       F                                                                                 ##STR190##        (CH.sub.2).sub.4                                                                              ##STR191##                                                                        N                                       F                                                                                 ##STR192##        (CH.sub.2).sub.4                                                                              ##STR193##                                                                        N                                       F SCH.sub.2COOC.sub.5 H.sub.11 -n                                                                   (CH.sub.2).sub.4                                                                              ##STR194##                                                                        N                                       F                                                                                 ##STR195##        (CH.sub.2).sub.4                                                                              ##STR196##                                                                        N                                       F                                                                                 ##STR197##        (CH.sub.2).sub.4                                                                              ##STR198##                                                                        N                                       F OCH.sub.2 CH.sub.2OCH(CH.sub.2 F).sub.2                                                           (CH.sub.2).sub.4                                                                              ##STR199##                                                                        N                                       F SCH(CH.sub.3).sub.2                                                                               (CH.sub.2).sub.4                                                                              ##STR200##                                                                        N                                       F OCH.sub.2CClCH.sub.2                                                                              (CH.sub.2).sub.4                                                                              ##STR201##                                                                        N                                       F                                                                                 ##STR202##        (CH.sub.2).sub.4                                                                              ##STR203##                                                                        N                                       F OCH.sub.2 CN       (CH.sub.2).sub.4                                                                              ##STR204##                                                                        N                                       F OCH.sub.2 COOC.sub.2 H.sub.4OCH.sub.3                                                             (CH.sub.2).sub.4                                                                              ##STR205##                                                                        N                                       F OCH.sub.2COOCH(CH.sub.3)COOC.sub.2 H.sub.5                                                        (CH.sub.2).sub.4                                                                              ##STR206##                                                                        N                                       F OCH.sub.2COOCH.sub.2COOC.sub.2 H.sub.5                                                            (CH.sub.2).sub.4                                                                              ##STR207##                                                                        N                                       F OCHF.sub.2         (CH.sub.2).sub.4                                                                              ##STR208##                                                                        N                                       F OCH.sub.2 CH.sub.2OCH.sub.2 CF.sub.3                                                              (CH.sub.2).sub.4                                                                              ##STR209##                                                                        N                                       F OCH.sub.2 CF.sub.3 (CH.sub.2).sub.4                                                                              ##STR210##                                                                        N                                       F OCF.sub.3          (CH.sub.2).sub.4                                                                              ##STR211##                                                                        N                                       F OCH.sub.2 CH(CH.sub.3)OC.sub.2 H.sub.5                                                            (CH.sub.2).sub.4                                                                              ##STR212##                                                                        N                                       F                                                                                 ##STR213##        (CH.sub.2).sub.4                                                                              ##STR214##                                                                        N                                       F OCH.sub.2CHCH.sub.2                                                                               (CH.sub.2).sub.4                                                                              ##STR215##                                                                        N                                       F OH                 (CH.sub.2).sub.4                                                                              ##STR216##                                                                        N                                       F OCH.sub.2C CH      (CH.sub.2).sub.4                                                                              ##STR217##                                                                        N                                       F SCH.sub.2 C CH     (CH.sub.2).sub.4                                                                              ##STR218##                                                                        N                                       F OCH.sub.2 COOC.sub.2 H.sub.5                                                                      (CH.sub.2).sub.4                                                                              ##STR219##                                                                        N                                       F SC(CH.sub.3).sub.3 (CH.sub.2).sub.4                                                                              ##STR220##                                                                        N                                       F OCH.sub.2COOC.sub.5 H.sub.11 -n                                                                   (CH.sub.2).sub.4                                                                              ##STR221##                                                                        N                                       F OCH(CH.sub.3)COOC.sub.2 H.sub.5                                                                   (CH.sub.2).sub.4                                                                              ##STR222##                                                                        N                                       F OCH.sub.2 CH.sub.2OCH.sub.3                                                                       (CH.sub.2).sub.4                                                                              ##STR223##                                                                        N                                       F OCH.sub.2 CH.sub.2OC.sub.2 H.sub.5                                                                (CH.sub.2).sub.4                                                                              ##STR224##                                                                        N                                       F O(CH.sub.2 CH.sub.2 O).sub.2OC.sub.2 H.sub.5                                                      (CH.sub.2).sub.4                                                                              ##STR225##                                                                        N                                       F SC.sub.3 H.sub.7 -n                                                                               (CH.sub.2).sub.4                                                                              ##STR226##                                                                        N                                       F SC.sub.2 H.sub.5   (CH.sub.2).sub.4                                                                              ##STR227##                                                                        N                                       F SCH.sub.3          (CH.sub.2).sub.4                                                                              ##STR228##                                                                        N                                       F SCH.sub.2 COOC.sub.2 H.sub.5                                                                      (CH.sub.2).sub.4                                                                              ##STR229##                                                                        N                                       F SCH.sub.2 CH.sub.2COOC.sub.2 H.sub.5                                                              (CH.sub.2).sub.4                                                                              ##STR230##                                                                        N                                       F OCH.sub.2C CCH.sub.3                                                                              (CH.sub.2).sub.4                                                                              ##STR231##                                                                        N                                       F OCH.sub.2CHCHCl    (CH.sub.2).sub.4                                                                              ##STR232##                                                                        N                                       F OCH(CH.sub.3)C CH  (CH.sub.2).sub.4                                                                              ##STR233##                                                                        N                                       F OCH(CH.sub.3)C CCH.sub.3                                                                          (CH.sub.2).sub.4                                                                              ##STR234##                                                                        N                                       F OCH(CH.sub.3)CHCH.sub.2                                                                           (CH.sub.2).sub.4                                                                              ##STR235##                                                                        N                                       F OCH.sub.2 CHCHCH.sub.3                                                                            (CH.sub.2).sub.4                                                                              ##STR236##                                                                        N                                       F OCH.sub.3          (CH.sub.2).sub.4                                                                              ##STR237##                                                                        N                                       F OC.sub.2 H.sub.5   (CH.sub.2).sub.4                                                                              ##STR238##                                                                        N                                       F OC.sub.3 H.sub.7 -n                                                                               (CH.sub.2).sub.4                                                                              ##STR239##                                                                        N                                       F OC.sub.3 H.sub.7 -iso                                                                             (CH.sub.2).sub.4                                                                              ##STR240##                                                                        N                                       F                                                                                 ##STR241##        (CH.sub.2).sub.4                                                                              ##STR242##                                                                        N                                       F                                                                                 ##STR243##        (CH.sub.2).sub.4                                                                              ##STR244##                                                                        N                                       F NHCH.sub.3         (CH.sub.2).sub.4                                                                              ##STR245##                                                                        N                                       F NHC.sub.2 H.sub.5  (CH.sub.2).sub.4                                                                              ##STR246##                                                                        N                                       F N(CH.sub.3).sub.2  (CH.sub.2).sub.4                                                                              ##STR247##                                                                        N                                       F NHCH.sub.2COOC.sub.2 H.sub.5                                                                      (CH.sub.2).sub.4                                                                              ##STR248##                                                                        N                                       F                                                                                 ##STR249##        (CH.sub.2).sub.4                                                                              ##STR250##                                                                        N                                       F                                                                                 ##STR251##        (CH.sub.2).sub.4                                                                              ##STR252##                                                                        N                                       F NHSO.sub.2 CH.sub.3                                                                               (CH.sub.2).sub.4                                                                              ##STR253##                                                                        N                                       F NHSO.sub.2 C.sub.2 H.sub.5                                                                        (CH.sub.2).sub.4                                                                              ##STR254##                                                                        N                                       F NHSO.sub.2 C.sub.3 H.sub.7 -n                                                                     (CH.sub.2).sub.4                                                                              ##STR255##                                                                        N                                       F NHSO.sub.2 C.sub.3 H.sub.7 -i                                                                     (CH.sub.2).sub.4                                                                              ##STR256##                                                                        N                                       F NHSO.sub.2 C.sub.4 H.sub.9 -n                                                                     (CH.sub.2).sub.4                                                                              ##STR257##                                                                        N                                       F NHSO.sub.2 C.sub.8 H.sub.17 -n                                                                    (CH.sub.2).sub.4                                                                              ##STR258##                                                                        N                                       F NHCOCH.sub.3       (CH.sub.2).sub.4                                                                              ##STR259##                                                                        N                                       F NHCOC.sub.2 H.sub.5                                                                               (CH.sub.2).sub.4                                                                              ##STR260##                                                                        N                                       F NHCOCF.sub.3       (CH.sub.2).sub.4                                                                              ##STR261##                                                                        N                                       F N(CH.sub.3)SO.sub.2 CH.sub.3                                                                      (CH.sub.2).sub.4                                                                              ##STR262##                                                                        N                                       F N(CH.sub.3)SO.sub.2 C.sub.2 H.sub.5                                                               (CH.sub.2).sub.4                                                                              ##STR263##                                                                        N                                       F N(CH.sub.3)SO.sub.2 C.sub.3 H.sub.7 -n                                                            (CH.sub.2).sub.4                                                                              ##STR264##                                                                        N                                       F NHSO.sub.2 CF.sub.3                                                                               (CH.sub.2).sub.4                                                                              ##STR265##                                                                        N                                       F                                                                                 ##STR266##        (CH.sub.2).sub.4                                                                              ##STR267##                                                                        N                                       F NHSO.sub.2C.sub.4 F.sub.9 -n                                                                      (CH.sub.2).sub.4                                                                              ##STR268##                                                                        N                                       F N(CH.sub.3)SO.sub.2 CF.sub.3                                                                      (CH.sub.2).sub.4                                                                              ##STR269##                                                                        N                                       F                                                                                 ##STR270##        (CH.sub.2).sub.4                                                                              ##STR271##                                                                        N                                       F                                                                                 ##STR272##        (CH.sub.2).sub.4                                                                              ##STR273##                                                                        N                                       F                                                                                 ##STR274##        (CH.sub.2).sub.4                                                                              ##STR275##                                                                        N                                       H OCH.sub.2 CF.sub.3 (CH.sub.2).sub.4                                                                              ##STR276##                                                                        N                                       H OCF.sub.3          (CH.sub.2).sub.4                                                                              ##STR277##                                                                        N                                       H OCH.sub.2 CH(CH.sub.3)OC.sub.2 H.sub.5                                                            (CH.sub.2).sub.4                                                                              ##STR278##                                                                        N                                       H                                                                                 ##STR279##        (CH.sub.2).sub.4                                                                              ##STR280##                                                                        N                                       H OCH.sub.2CHCH.sub.2                                                                               (CH.sub.2).sub.4                                                                              ##STR281##                                                                        N                                       H OH                 (CH.sub.2).sub.4                                                                              ##STR282##                                                                        N                                       H OCH.sub.2C CH      (CH.sub.2).sub.4                                                                              ##STR283##                                                                        N                                       H SCH.sub.2 C CH     (CH.sub.2).sub.4                                                                              ##STR284##                                                                        N                                       H OCH.sub.2 COOC.sub.2 H.sub.5                                                                      (CH.sub.2).sub.4                                                                              ##STR285##                                                                        N                                       H SC(CH.sub.3).sub.3 (CH.sub.2).sub.4                                                                              ##STR286##                                                                        N                                       H OCH.sub.2COOC.sub.5 H.sub.11 -n                                                                   (CH.sub.2).sub.4                                                                              ##STR287##                                                                        N                                       H OCH(CH.sub.3)COOC.sub.2 H.sub.5                                                                   (CH.sub.2).sub.4                                                                              ##STR288##                                                                        N                                       H OCH.sub.2 CH.sub.2OCH.sub.3                                                                       (CH.sub.2).sub.4                                                                              ##STR289##                                                                        N                                       H OCH.sub.2 CH.sub.2OC.sub.2 H.sub.5                                                                (CH.sub.2).sub.4                                                                              ##STR290##                                                                        N                                       H O(CH.sub.2 CH.sub.2 O).sub.2OC.sub.2 H.sub.5                                                      (CH.sub.2).sub.4                                                                              ##STR291##                                                                        N                                       H SC.sub.3 H.sub.7 -n                                                                               (CH.sub.2).sub.4                                                                              ##STR292##                                                                        N                                       H SC.sub.2 H.sub.5   (CH.sub.2).sub.4                                                                              ##STR293##                                                                        N                                       H SCH.sub.3          (CH.sub.2).sub.4                                                                              ##STR294##                                                                        N                                       H SCH.sub.2 COOC.sub.2 H.sub.5                                                                      (CH.sub.2).sub.4                                                                              ##STR295##                                                                        N                                       H SCH.sub.2 CH.sub.2COOC.sub.2 H.sub.5                                                              (CH.sub.2).sub.4                                                                              ##STR296##                                                                        N                                       H OCH.sub.2C CCH.sub.3                                                                              (CH.sub.2).sub.4                                                                              ##STR297##                                                                        N                                       H OCH.sub.2CHCHCl    (CH.sub.2).sub.4                                                                              ##STR298##                                                                        N                                       H OCH(CH.sub.3)C CH  (CH.sub.2).sub.4                                                                              ##STR299##                                                                        N                                       H OCH(CH.sub.3)C CCH.sub.3                                                                          (CH.sub.2).sub.4                                                                              ##STR300##                                                                        N                                       H OCH(CH.sub.3)CHCH.sub.2                                                                           (CH.sub.2).sub.4                                                                              ##STR301##                                                                        N                                       H OCH.sub.2 CHCHCH.sub.3                                                                            (CH.sub.2).sub.4                                                                              ##STR302##                                                                        N                                       H OCH.sub.3          (CH.sub.2).sub.4                                                                              ##STR303##                                                                        N                                       H OC.sub.2 H.sub.5   (CH.sub.2).sub.4                                                                              ##STR304##                                                                        N                                       H OC.sub.3 H.sub.7 -n                                                                               (CH.sub.2).sub.4                                                                              ##STR305##                                                                        N                                       H OC.sub.3 H.sub.7 -iso                                                                             (CH.sub.2).sub.4                                                                              ##STR306##                                                                        N                                       H                                                                                 ##STR307##        (CH.sub.2).sub.4                                                                              ##STR308##                                                                        N                                       H                                                                                 ##STR309##        (CH.sub.2).sub.4                                                                              ##STR310##                                                                        N                                       H OCH(CH.sub.2 F).sub.2                                                                             (CH.sub.2).sub.4                                                                              ##STR311##                                                                        N                                       H OCH.sub.2C(CH.sub.3)CH.sub.2                                                                      (CH.sub.2).sub.4                                                                              ##STR312##                                                                        N                                       H                                                                                 ##STR313##        (CH.sub.2).sub.4                                                                              ##STR314##                                                                        N                                       H                                                                                 ##STR315##        (CH.sub.2).sub.4                                                                              ##STR316##                                                                        N                                       H                                                                                 ##STR317##        (CH.sub.2).sub.4                                                                              ##STR318##                                                                        N                                       H                                                                                 ##STR319##        (CH.sub.2).sub.4                                                                              ##STR320##                                                                        N                                       H                                                                                 ##STR321##        (CH.sub.2).sub.4                                                                              ##STR322##                                                                        N                                       H                                                                                 ##STR323##        (CH.sub.2).sub.4                                                                              ##STR324##                                                                        N                                       H SCH.sub.2COOC.sub.5 H.sub.11 -n                                                                   (CH.sub.2).sub.4                                                                              ##STR325##                                                                        N                                       H                                                                                 ##STR326##        (CH.sub.2).sub.4                                                                              ##STR327##                                                                        N                                       H                                                                                 ##STR328##        (CH.sub.2).sub.4                                                                              ##STR329##                                                                        N                                       H OCH.sub.2 CH.sub.2OCH(CH.sub.2 F).sub.2                                                           (CH.sub.2).sub.4                                                                              ##STR330##                                                                        N                                       H SCH(CH.sub.3).sub.2                                                                               (CH.sub.2).sub.4                                                                              ##STR331##                                                                        N                                       H OCH.sub.2CClCH.sub.2                                                                              (CH.sub.2).sub.4                                                                              ##STR332##                                                                        N                                       H                                                                                 ##STR333##        (CH.sub.2).sub.4                                                                              ##STR334##                                                                        N                                       H OCH.sub.2 CN       (CH.sub.2).sub.4                                                                              ##STR335##                                                                        N                                       H OCH.sub.2 COOC.sub.2 H.sub.4OCH.sub.3                                                             (CH.sub.2).sub.4                                                                              ##STR336##                                                                        N                                       H OCH.sub.2COOCH(CH.sub.3)COOC.sub.2 H.sub.5                                                        (CH.sub.2).sub.4                                                                              ##STR337##                                                                        N                                       H OCH.sub.2COOCH.sub.2COOC.sub.2 H.sub.5                                                            (CH.sub.2).sub.4                                                                              ##STR338##                                                                        N                                       H OCHF.sub.2         (CH.sub.2).sub.4                                                                              ##STR339##                                                                        N                                       H OCH.sub.2 CH.sub.2OCH.sub.2 CF.sub.3                                                              (CH.sub.2).sub.4                                                                              ##STR340##                                                                        N                                       H NHCH.sub.3         (CH.sub.2).sub.4                                                                              ##STR341##                                                                        N                                       H NHC.sub.2 H.sub.5  (CH.sub.2).sub.4                                                                              ##STR342##                                                                        N                                       H N(CH.sub.3).sub.2  (CH.sub.2).sub.4                                                                              ##STR343##                                                                        N                                       H NHCH.sub.2COOC.sub.2 H.sub.5                                                                      (CH.sub.2).sub.4                                                                              ##STR344##                                                                        N                                       H                                                                                 ##STR345##        (CH.sub.2).sub.4                                                                              ##STR346##                                                                        N                                       H                                                                                 ##STR347##        (CH.sub.2).sub.4                                                                              ##STR348##                                                                        N                                       H NHSO.sub.2 CH.sub.3                                                                               (CH.sub.2).sub.4                                                                              ##STR349##                                                                        N                                       H NHSO.sub.2 C.sub.2 H.sub.5                                                                        (CH.sub.2).sub.4                                                                              ##STR350##                                                                        N                                       H NHSO.sub.2 C.sub.3 H.sub.7 -n                                                                     (CH.sub.2).sub.4                                                                              ##STR351##                                                                        N                                       H NHSO.sub.2C.sub.3 H.sub.7 -i                                                                      (CH.sub.2).sub.4                                                                              ##STR352##                                                                        N                                       H NHSO.sub.2 C.sub.4 H.sub.9 -n                                                                     (CH.sub.2).sub.4                                                                              ##STR353##                                                                        N                                       H NHSO.sub.2 C.sub.8 H.sub.17 -n                                                                    (CH.sub.2).sub.4                                                                              ##STR354##                                                                        N                                       H NHCOCH.sub.3       (CH.sub.2).sub.4                                                                              ##STR355##                                                                        N                                       H NHCOC.sub.2 H.sub.5                                                                               (CH.sub.2).sub.4                                                                              ##STR356##                                                                        N                                       H NHCOCF.sub.3       (CH.sub.2).sub.4                                                                              ##STR357##                                                                        N                                       H N(CH.sub.3)SO.sub.2 CH.sub.3                                                                      (CH.sub.2).sub.4                                                                              ##STR358##                                                                        N                                       H N(CH.sub.3)SO.sub.2 C.sub.2 H.sub.5                                                               (CH.sub.2).sub.4                                                                              ##STR359##                                                                        N                                       H N(CH.sub.3)SO.sub.2 C.sub.3 H.sub.7 -n                                                            (CH.sub.2).sub.4                                                                              ##STR360##                                                                        N                                       H NHSO.sub.2 CF.sub.3                                                                               (CH.sub.2).sub.4                                                                              ##STR361##                                                                        N                                       H                                                                                 ##STR362##        (CH.sub.2).sub.4                                                                              ##STR363##                                                                        N                                       H NHSO.sub.2C.sub.4 F.sub.9 -n                                                                      (CH.sub.2).sub.4                                                                              ##STR364##                                                                        N                                       H N(CH.sub.3)SO.sub.2 CF.sub.3                                                                      (CH.sub.2).sub.4                                                                              ##STR365##                                                                        N                                       H                                                                                 ##STR366##        (CH.sub.2).sub.4                                                                              ##STR367##                                                                        N                                       H                                                                                 ##STR368##        (CH.sub.2).sub.4                                                                              ##STR369##                                                                        N                                       H                                                                                 ##STR370##        (CH.sub.2).sub.4                                                                              ##STR371##                                                                        N                                       Cl                                                                               OCH.sub.2 CF.sub.3 (CH.sub.2).sub.4                                                                              ##STR372##                                                                        N                                       Cl                                                                               OCF.sub.3          (CH.sub.2).sub.4                                                                              ##STR373##                                                                        N                                       Cl                                                                               OCH.sub.2 CH(CH.sub.3)OC.sub.2 H.sub.5                                                            (CH.sub.2).sub.4                                                                              ##STR374##                                                                        N                                       Cl                                                                                ##STR375##        (CH.sub.2).sub.4                                                                              ##STR376##                                                                        N                                       Cl                                                                               OCH.sub.2CHCH.sub.2                                                                               (CH.sub.2).sub.4                                                                              ##STR377##                                                                        N                                       Cl                                                                               OH                 (CH.sub.2).sub.4                                                                              ##STR378##                                                                        N                                       Cl                                                                               OCH.sub.2C CH      (CH.sub.2).sub.4                                                                              ##STR379##                                                                        N                                       Cl                                                                               SCH.sub.2 C CH     (CH.sub.2).sub.4                                                                              ##STR380##                                                                        N                                       Cl                                                                               OCH.sub.2 COOC.sub.2 H.sub.5                                                                      (CH.sub.2).sub.4                                                                              ##STR381##                                                                        N                                       Cl                                                                               SC(CH.sub.3).sub.3 (CH.sub.2).sub.4                                                                              ##STR382##                                                                        N                                       Cl                                                                               OCH.sub.2COOC.sub.5 H.sub.11 -n                                                                   (CH.sub.2).sub.4                                                                              ##STR383##                                                                        N                                       Cl                                                                               OCH(CH.sub.3)COOC.sub.2 H.sub.5                                                                   (CH.sub.2).sub.4                                                                              ##STR384##                                                                        N                                       Cl                                                                               OCH.sub.2 CH.sub.2OCH.sub.3                                                                       (CH.sub.2).sub.4                                                                              ##STR385##                                                                        N                                       Cl                                                                               OCH.sub.2 CH.sub.2OC.sub.2 H.sub.5                                                                (CH.sub.2).sub.4                                                                              ##STR386##                                                                        N                                       Cl                                                                               O(CH.sub.2 CH.sub.2 O).sub.2OC.sub.2 H.sub.5                                                      (CH.sub.2).sub.4                                                                              ##STR387##                                                                        N                                       Cl                                                                               SC.sub.3 H.sub.7 -n                                                                               (CH.sub.2).sub.4                                                                              ##STR388##                                                                        N                                       Cl                                                                               SC.sub.2 H.sub.5   (CH.sub.2).sub.4                                                                              ##STR389##                                                                        N                                       Cl                                                                               SCH.sub.3          (CH.sub.2).sub.4                                                                              ##STR390##                                                                        N                                       Cl                                                                               SCH.sub.2 COOC.sub.2 H.sub.5                                                                      (CH.sub.2).sub.4                                                                              ##STR391##                                                                        N                                       Cl                                                                               SCH.sub.2 CH.sub.2COOC.sub.2 H.sub.5                                                              (CH.sub.2).sub.4                                                                              ##STR392##                                                                        N                                       Cl                                                                               OCH.sub.2C CCH.sub.3                                                                              (CH.sub.2).sub.4                                                                              ##STR393##                                                                        N                                       Cl                                                                               OCH.sub.2CHCHCl    (CH.sub.2).sub.4                                                                              ##STR394##                                                                        N                                       Cl                                                                               OCH(CH.sub.3)C CH  (CH.sub.2).sub.4                                                                              ##STR395##                                                                        N                                       Cl                                                                               OCH(CH.sub.3)C CCH.sub.3                                                                          (CH.sub.2).sub.4                                                                              ##STR396##                                                                        N                                       Cl                                                                               OCH(CH.sub.3)CHCH.sub.2                                                                           (CH.sub.2).sub.4                                                                              ##STR397##                                                                        N                                       Cl                                                                               OCH.sub.2 CHCHCH.sub.3                                                                            (CH.sub.2).sub.4                                                                              ##STR398##                                                                        N                                       Cl                                                                               OCH.sub.3          (CH.sub.2).sub.4                                                                              ##STR399##                                                                        N                                       Cl                                                                               OC.sub.2 H.sub.5   (CH.sub.2).sub.4                                                                              ##STR400##                                                                        N                                       Cl                                                                               OC.sub.3 H.sub.7 -n                                                                               (CH.sub.2).sub.4                                                                              ##STR401##                                                                        N                                       Cl                                                                               OC.sub.3 H.sub.7 -iso                                                                             (CH.sub.2).sub.4                                                                              ##STR402##                                                                        N                                       Cl                                                                                ##STR403##        (CH.sub.2).sub.4                                                                              ##STR404##                                                                        N                                       Cl                                                                                ##STR405##        (CH.sub.2).sub.4                                                                              ##STR406##                                                                        N                                       Cl                                                                               OCH(CH.sub.2 F).sub.2                                                                             (CH.sub.2).sub.4                                                                              ##STR407##                                                                        N                                       Cl                                                                               OCH.sub.2C(CH.sub.3)CH.sub.2                                                                      (CH.sub.2).sub.4                                                                              ##STR408##                                                                        N                                       Cl                                                                                ##STR409##        (CH.sub.2).sub.4                                                                              ##STR410##                                                                        N                                       Cl                                                                                ##STR411##        (CH.sub.2).sub.4                                                                              ##STR412##                                                                        N                                       Cl                                                                                ##STR413##        (CH.sub.2).sub.4                                                                              ##STR414##                                                                        N                                       Cl                                                                                ##STR415##        (CH.sub.2).sub.4                                                                              ##STR416##                                                                        N                                       Cl                                                                                ##STR417##        (CH.sub.2).sub.4                                                                              ##STR418##                                                                        N                                       Cl                                                                                ##STR419##        (CH.sub.2).sub.4                                                                              ##STR420##                                                                        N                                       Cl                                                                               SCH.sub.2COOC.sub.5 H.sub.11 -n                                                                   (CH.sub.2).sub.4                                                                              ##STR421##                                                                        N                                       Cl                                                                                ##STR422##        (CH.sub.2).sub.4                                                                              ##STR423##                                                                        N                                       Cl                                                                                ##STR424##        (CH.sub.2).sub.4                                                                              ##STR425##                                                                        N                                       Cl                                                                               OCH.sub.2 CH.sub.2OCH(CH.sub.2 F).sub.2                                                           (CH.sub.2).sub.4                                                                              ##STR426##                                                                        N                                       Cl                                                                               SCH(CH.sub.3).sub.2                                                                               (CH.sub.2).sub.4                                                                              ##STR427##                                                                        N                                       Cl                                                                               OCH.sub.2CClCH.sub.2                                                                              (CH.sub.2).sub.4                                                                              ##STR428##                                                                        N                                       Cl                                                                                ##STR429##        (CH.sub.2).sub.4                                                                              ##STR430##                                                                        N                                       Cl                                                                               OCH.sub.2 CN       (CH.sub.2).sub.4                                                                              ##STR431##                                                                        N                                       Cl                                                                               OCH.sub.2 COOC.sub.2 H.sub.4OCH.sub.3                                                             (CH.sub.2).sub.4                                                                              ##STR432##                                                                        N                                       Cl                                                                               OCH.sub.2COOCH(CH.sub.3)COOC.sub.2 H.sub.5                                                        (CH.sub.2).sub.4                                                                              ##STR433##                                                                        N                                       Cl                                                                               OCH.sub.2COOCH.sub.2COOC.sub.2 H.sub.5                                                            (CH.sub.2).sub.4                                                                              ##STR434##                                                                        N                                       Cl                                                                               OCHF.sub.2         (CH.sub.2).sub.4                                                                              ##STR435##                                                                        N                                       Cl                                                                               OCH.sub.2 CH.sub.2OCH.sub.2 CF.sub.3                                                              (CH.sub.2).sub.4                                                                              ##STR436##                                                                        N                                       Cl                                                                               NHCH.sub.3         (CH.sub.2).sub.4                                                                              ##STR437##                                                                        N                                       Cl                                                                               NHC.sub.2 H.sub.5  (CH.sub.2).sub.4                                                                              ##STR438##                                                                        N                                       Cl                                                                               N(CH.sub.3).sub.2  (CH.sub.2).sub.4                                                                              ##STR439##                                                                        N                                       Cl                                                                               NHCH.sub.2COOC.sub.2 H.sub.5                                                                      (CH.sub.2).sub.4                                                                              ##STR440##                                                                        N                                       Cl                                                                               NHCOCH.sub.3       (CH.sub.2).sub.4                                                                              ##STR441##                                                                        N                                       Cl                                                                               NHCOC.sub.2 H.sub.5                                                                               (CH.sub.2).sub.4                                                                              ##STR442##                                                                        N                                       Cl                                                                               NHCOCF.sub.3       (CH.sub.2).sub.4                                                                              ##STR443##                                                                        N                                       Cl                                                                               N(CH.sub.3)SO.sub.2 CH.sub.3                                                                      (CH.sub.2).sub.4                                                                              ##STR444##                                                                        N                                       Cl                                                                               N(CH.sub.3)SO.sub.2 C.sub.2 H.sub.5                                                               (CH.sub.2).sub.4                                                                              ##STR445##                                                                        N                                       Cl                                                                               N(CH.sub.3)SO.sub.2 C.sub.3 H.sub.7 -n                                                            (CH.sub.2).sub.4                                                                              ##STR446##                                                                        N                                       Cl                                                                               NHSO.sub.2 CF.sub.3                                                                               (CH.sub.2).sub.4                                                                              ##STR447##                                                                        N                                       Cl                                                                                ##STR448##        (CH.sub.2).sub.4                                                                              ##STR449##                                                                        N                                       Cl                                                                                ##STR450##        (CH.sub.2).sub.4                                                                              ##STR451##                                                                        N                                       Cl                                                                                ##STR452##        (CH.sub.2).sub.4                                                                              ##STR453##                                                                        N                                       Cl                                                                               NHSO.sub.2 CH.sub.3                                                                               (CH.sub.2).sub.4                                                                              ##STR454##                                                                        N                                       Cl                                                                               NHSO.sub.2 C.sub.2 H.sub.5                                                                        (CH.sub.2).sub.4                                                                              ##STR455##                                                                        N                                       Cl                                                                               NHSO.sub.2 C.sub.3 H.sub.7 -n                                                                     (CH.sub.2).sub.4                                                                              ##STR456##                                                                        N                                       Cl                                                                               NHSO.sub.2 C.sub.3 H.sub.7 -i                                                                     (CH.sub.2).sub.4                                                                              ##STR457##                                                                        N                                       Cl                                                                               NHSO.sub.2 C.sub.4 H.sub.9 -n                                                                     (CH.sub.2).sub.4                                                                              ##STR458##                                                                        N                                       Cl                                                                               NHSO.sub.2 C.sub.8 H.sub.17 -n                                                                    (CH.sub.2).sub.4                                                                              ##STR459##                                                                        N                                       Cl                                                                               NHSO.sub.2C.sub.4 F.sub.9 -n                                                                      (CH.sub.2).sub.4                                                                              ##STR460##                                                                        N                                       Cl                                                                               N(CH.sub.3)SO.sub.2 CF.sub.3                                                                      (CH.sub.2).sub.4                                                                              ##STR461##                                                                        N                                       Cl                                                                                ##STR462##        (CH.sub.2).sub.4                                                                              ##STR463##                                                                        N                                       Cl                                                                                ##STR464##        (CH.sub.2).sub.4                                                                              ##STR465##                                                                        N                                       Cl                                                                                ##STR466##        (CH.sub.2).sub.4                                                                              ##STR467##                                                                        N                                       F OCH(CH.sub.2 F).sub.2                                                                             (CH.sub.2).sub.3                                                                              ##STR468##                                                                        N                                       F OCH.sub.2C(CH.sub.3)CH.sub.2                                                                      (CH.sub.2).sub.3                                                                              ##STR469##                                                                        N                                       F                                                                                 ##STR470##        (CH.sub.2).sub.3                                                                              ##STR471##                                                                        N                                       F                                                                                 ##STR472##        (CH.sub.2).sub.3                                                                              ##STR473##                                                                        N                                       F                                                                                 ##STR474##        (CH.sub.2).sub.3                                                                              ##STR475##                                                                        N                                       F                                                                                 ##STR476##        (CH.sub.2).sub.3                                                                              ##STR477##                                                                        N                                       F                                                                                 ##STR478##        (CH.sub.2).sub.3                                                                              ##STR479##                                                                        N                                       F                                                                                 ##STR480##        (CH.sub.2).sub.3                                                                              ##STR481##                                                                        N                                       F SCH.sub.2COOC.sub.5 H.sub.11 -n                                                                   (CH.sub.2).sub.3                                                                              ##STR482##                                                                        N                                       F                                                                                 ##STR483##        (CH.sub.2).sub.3                                                                              ##STR484##                                                                        N                                       F                                                                                 ##STR485##        (CH.sub.2).sub.3                                                                              ##STR486##                                                                        N                                       F OCH.sub.2 CH.sub.2OCH(CH.sub.2 F).sub.2                                                           (CH.sub.2).sub.3                                                                              ##STR487##                                                                        N                                       F SCH(CH.sub.3).sub.2                                                                               (CH.sub.2).sub.3                                                                              ##STR488##                                                                        N                                       F OCH.sub.2CClCH.sub.2                                                                              (CH.sub.2).sub.3                                                                              ##STR489##                                                                        N                                       F                                                                                 ##STR490##        (CH.sub.2).sub.3                                                                              ##STR491##                                                                        N                                       F OCH.sub.2 CN       (CH.sub.2).sub.3                                                                              ##STR492##                                                                        N                                       F OCH.sub.2 COOC.sub.2 H.sub.4OCH.sub.3                                                             (CH.sub.2).sub.3                                                                              ##STR493##                                                                        N                                       F OCH.sub.2COOCH(CH.sub.3)COOC.sub.2 H.sub.5                                                        (CH.sub.2).sub.3                                                                              ##STR494##                                                                        N                                       F OCH.sub.2COOCH.sub.2COOC.sub.2 H.sub.5                                                            (CH.sub.2).sub.3                                                                              ##STR495##                                                                        N                                       F OCHF.sub.2         (CH.sub.2).sub.3                                                                              ##STR496##                                                                        N                                       F OCH.sub.2 CH.sub.2OCH.sub.2 CF.sub.3                                                              (CH.sub.2).sub.3                                                                              ##STR497##                                                                        N                                       F OCH.sub.2 CF.sub.3 (CH.sub.2).sub.3                                                                              ##STR498##                                                                        N                                       F OCF.sub.3          (CH.sub.2).sub.3                                                                              ##STR499##                                                                        N                                       F OCH.sub.2 CH(CH.sub.3)OC.sub.2 H.sub.5                                                            (CH.sub.2).sub.3                                                                              ##STR500##                                                                        N                                       F                                                                                 ##STR501##        (CH.sub.2).sub.3                                                                              ##STR502##                                                                        N                                       F OCH.sub.2CHCH.sub.2                                                                               (CH.sub.2).sub.3                                                                              ##STR503##                                                                        N                                       F OH                 (CH.sub.2).sub.3                                                                              ##STR504##                                                                        N                                       F OCH.sub.2C CH      (CH.sub.2).sub.3                                                                              ##STR505##                                                                        N                                       F SCH.sub.2 C CH     (CH.sub.2).sub.3                                                                              ##STR506##                                                                        N                                       F OCH.sub.2 COOC.sub.2 H.sub.5                                                                      (CH.sub.2).sub.3                                                                              ##STR507##                                                                        N                                       F SC(CH.sub.3).sub.3 (CH.sub.2).sub.3                                                                              ##STR508##                                                                        N                                       F OCH.sub.2COOC.sub.5 H.sub.11 -n                                                                   (CH.sub.2).sub.3                                                                              ##STR509##                                                                        N                                       F OCH(CH.sub.3)COOC.sub.2 H.sub.5                                                                   (CH.sub.2).sub.3                                                                              ##STR510##                                                                        N                                       F OCH.sub.2 CH.sub.2OCH.sub.3                                                                       (CH.sub.2).sub.3                                                                              ##STR511##                                                                        N                                       F OCH.sub.2 CH.sub.2OC.sub.2 H.sub.5                                                                (CH.sub.2).sub.3                                                                              ##STR512##                                                                        N                                       F O(CH.sub.2 CH.sub.2 O).sub.2OC.sub.2 H.sub.5                                                      (CH.sub.2).sub.3                                                                              ##STR513##                                                                        N                                       F SC.sub.3 H.sub.7 -n                                                                               (CH.sub.2).sub.3                                                                              ##STR514##                                                                        N                                       F SC.sub.2 H.sub.5   (CH.sub.2).sub.3                                                                              ##STR515##                                                                        N                                       F SCH.sub.3          (CH.sub.2).sub.3                                                                              ##STR516##                                                                        N                                       F SCH.sub.2 COOC.sub.2 H.sub.5                                                                      (CH.sub.2).sub.3                                                                              ##STR517##                                                                        N                                       F SCH.sub.2 CH.sub.2COOC.sub.2 H.sub.5                                                              (CH.sub.2).sub.3                                                                              ##STR518##                                                                        N                                       F OCH.sub.2C CCH.sub.3                                                                              (CH.sub.2).sub.3                                                                              ##STR519##                                                                        N                                       F OCH.sub.2CHCHCl    (CH.sub.2).sub.3                                                                              ##STR520##                                                                        N                                       F OCH(CH.sub.3)C CH  (CH.sub.2).sub.3                                                                              ##STR521##                                                                        N                                       F OCH(CH.sub.3)C CCH.sub.3                                                                          (CH.sub.2).sub.3                                                                              ##STR522##                                                                        N                                       F OCH(CH.sub.3)CHCH.sub.2                                                                           (CH.sub.2).sub.3                                                                              ##STR523##                                                                        N                                       F OCH.sub.2 CHCHCH.sub.3                                                                            (CH.sub.2).sub.3                                                                              ##STR524##                                                                        N                                       F OCH.sub.3          (CH.sub.2).sub.3                                                                              ##STR525##                                                                        N                                       F OC.sub.2 H.sub.5   (CH.sub.2).sub.3                                                                              ##STR526##                                                                        N                                       F OC.sub.3 H.sub.7 -n                                                                               (CH.sub.2).sub.3                                                                              ##STR527##                                                                        N                                       F OC.sub.3 H.sub.7 -iso                                                                             (CH.sub.2).sub.3                                                                              ##STR528##                                                                        N                                       F                                                                                 ##STR529##        (CH.sub.2).sub.3                                                                              ##STR530##                                                                        N                                       F                                                                                 ##STR531##        (CH.sub.2).sub.3                                                                              ##STR532##                                                                        N                                       F NHCH.sub.3         (CH.sub.2).sub.3                                                                              ##STR533##                                                                        N                                       F NHC.sub.2 H.sub.5  (CH.sub.2).sub.3                                                                              ##STR534##                                                                        N                                       F N(CH.sub.3).sub.2  (CH.sub.2).sub.3                                                                              ##STR535##                                                                        N                                       F NHCH.sub.2COOC.sub.2 H.sub.5                                                                      (CH.sub.2).sub.3                                                                              ##STR536##                                                                        N                                       F                                                                                 ##STR537##        (CH.sub.2).sub.3                                                                              ##STR538##                                                                        N                                       F                                                                                 ##STR539##        (CH.sub.2).sub.3                                                                              ##STR540##                                                                        N                                       F NHSO.sub.2 CH.sub.3                                                                               (CH.sub.2).sub.3                                                                              ##STR541##                                                                        N                                       F NHSO.sub.2 C.sub.2 H.sub.5                                                                        (CH.sub.2).sub.3                                                                              ##STR542##                                                                        N                                       F NHSO.sub.2 C.sub.3 H.sub.7 -n                                                                     (CH.sub.2).sub.3                                                                              ##STR543##                                                                        N                                       F NHSO.sub.2 C.sub.3 H.sub.7 -i                                                                     (CH.sub.2).sub.3                                                                              ##STR544##                                                                        N                                       F NHSO.sub.2 C.sub.4 H.sub.9 -n                                                                     (CH.sub.2).sub.3                                                                              ##STR545##                                                                        N                                       F NHSO.sub.2 C.sub.8 H.sub.17 -n                                                                    (CH.sub.2).sub.3                                                                              ##STR546##                                                                        N                                       F NHCOCH.sub.3       (CH.sub.2).sub.3                                                                              ##STR547##                                                                        N                                       F NHCOC.sub.2 H.sub.5                                                                               (CH.sub.2).sub.3                                                                              ##STR548##                                                                        N                                       F NHCOCF.sub.3       (CH.sub.2).sub.3                                                                              ##STR549##                                                                        N                                       F N(CH.sub.3)SO.sub.2 CH.sub.3                                                                      (CH.sub.2).sub.3                                                                              ##STR550##                                                                        N                                       F N(CH.sub.3)SO.sub.2 C.sub.2 H.sub.5                                                               (CH.sub.2).sub.3                                                                              ##STR551##                                                                        N                                       F N(CH.sub.3)SO.sub.2 C.sub.3 H.sub.7 -n                                                            (CH.sub.2).sub.3                                                                              ##STR552##                                                                        N                                       F NHSO.sub.2 CF.sub.3                                                                               (CH.sub.2).sub.3                                                                              ##STR553##                                                                        N                                       F                                                                                 ##STR554##        (CH.sub.2).sub.3                                                                              ##STR555##                                                                        N                                       F NHSO.sub.2C.sub.4 F.sub.9 -n                                                                      (CH.sub.2).sub.3                                                                              ##STR556##                                                                        N                                       F N(CH.sub.3)SO.sub.2 CF.sub.3                                                                      (CH.sub.2).sub.3                                                                              ##STR557##                                                                        N                                       F                                                                                 ##STR558##        (CH.sub.2).sub.3                                                                              ##STR559##                                                                        N                                       F                                                                                 ##STR560##        (CH.sub.2).sub.3                                                                              ##STR561##                                                                        N                                       F                                                                                 ##STR562##        (CH.sub.2).sub.3                                                                              ##STR563##                                                                        N                                       H OCH.sub.2 CF.sub.3 (CH.sub.2).sub.3                                                                              ##STR564##                                                                        N                                       H OCF.sub.3          (CH.sub.2).sub.3                                                                              ##STR565##                                                                        N                                       H OCH.sub.2 CH(CH.sub.3)OC.sub.2 H.sub.5                                                            (CH.sub.2).sub.3                                                                              ##STR566##                                                                        N                                       H                                                                                 ##STR567##        (CH.sub.2).sub.3                                                                              ##STR568##                                                                        N                                       H OCH.sub.2CHCH.sub.2                                                                               (CH.sub.2).sub.3                                                                              ##STR569##                                                                        N                                       H OH                 (CH.sub.2).sub.3                                                                              ##STR570##                                                                        N                                       H OCH.sub.2C CH      (CH.sub.2).sub.3                                                                              ##STR571##                                                                        N                                       H SCH.sub.2 C CH     (CH.sub.2).sub.3                                                                              ##STR572##                                                                        N                                       H OCH.sub.2 COOC.sub.2 H.sub.5                                                                      (CH.sub.2).sub.3                                                                              ##STR573##                                                                        N                                       H SC(CH.sub.3).sub.3 (CH.sub.2).sub.3                                                                              ##STR574##                                                                        N                                       H OCH.sub.2COOC.sub.5 H.sub.11 -n                                                                   (CH.sub.2).sub.3                                                                              ##STR575##                                                                        N                                       H OCH(CH.sub.3)COOC.sub.2 H.sub.5                                                                   (CH.sub.2).sub.3                                                                              ##STR576##                                                                        N                                       H OCH.sub.2 CH.sub.2OCH.sub.3                                                                       (CH.sub.2).sub.3                                                                              ##STR577##                                                                        N                                       H OCH.sub.2 CH.sub.2OC.sub.2 H.sub.5                                                                (CH.sub.2).sub.3                                                                              ##STR578##                                                                        N                                       H O(CH.sub.2 CH.sub.2 O).sub.2OC.sub.2 H.sub.5                                                      (CH.sub.2).sub.3                                                                              ##STR579##                                                                        N                                       H SC.sub.3 H.sub.7 -n                                                                               (CH.sub.2).sub.3                                                                              ##STR580##                                                                        N                                       H SC.sub.2 H.sub.5   (CH.sub.2).sub.3                                                                              ##STR581##                                                                        N                                       H SCH.sub.3          (CH.sub.2).sub.3                                                                              ##STR582##                                                                        N                                       H SCH.sub.2 COOC.sub.2 H.sub.5                                                                      (CH.sub.2).sub.3                                                                              ##STR583##                                                                        N                                       H SCH.sub.2 CH.sub.2COOC.sub.2 H.sub.5                                                              (CH.sub.2).sub.3                                                                              ##STR584##                                                                        N                                       H OCH.sub.2C CCH.sub.3                                                                              (CH.sub.2).sub.3                                                                              ##STR585##                                                                        N                                       H OCH.sub.2CHCHCl    (CH.sub.2).sub.3                                                                              ##STR586##                                                                        N                                       H OCH(CH.sub.3)C CH  (CH.sub.2).sub.3                                                                              ##STR587##                                                                        N                                       H OCH(CH.sub.3)C CCH.sub.3                                                                          (CH.sub.2).sub.3                                                                              ##STR588##                                                                        N                                       H OCH(CH.sub.3)CHCH.sub.2                                                                           (CH.sub.2).sub.3                                                                              ##STR589##                                                                        N                                       H OCH.sub.2 CHCHCH.sub.3                                                                            (CH.sub.2).sub.3                                                                              ##STR590##                                                                        N                                       H OCH.sub.3          (CH.sub.2).sub.3                                                                              ##STR591##                                                                        N                                       H OC.sub.2 H.sub.5   (CH.sub.2).sub.3                                                                              ##STR592##                                                                        N                                       H OC.sub.3 H.sub.7 -n                                                                               (CH.sub.2).sub.3                                                                              ##STR593##                                                                        N                                       H OC.sub.3 H.sub.7 -iso                                                                             (CH.sub.2).sub.3                                                                              ##STR594##                                                                        N                                       H                                                                                 ##STR595##        (CH.sub.2).sub.3                                                                              ##STR596##                                                                        N                                       H                                                                                 ##STR597##        (CH.sub.2).sub.3                                                                              ##STR598##                                                                        N                                       H OCH(CH.sub.2 F).sub.2                                                                             (CH.sub.2).sub.3                                                                              ##STR599##                                                                        N                                       H OCH.sub.2C(CH.sub.3)CH.sub.2                                                                      (CH.sub.2).sub.3                                                                              ##STR600##                                                                        N                                       H                                                                                 ##STR601##        (CH.sub.2).sub.3                                                                              ##STR602##                                                                        N                                       H                                                                                 ##STR603##        (CH.sub.2).sub.3                                                                              ##STR604##                                                                        N                                       H                                                                                 ##STR605##        (CH.sub.2).sub.3                                                                              ##STR606##                                                                        N                                       H                                                                                 ##STR607##        (CH.sub.2).sub.3                                                                              ##STR608##                                                                        N                                       H                                                                                 ##STR609##        (CH.sub.2).sub.3                                                                              ##STR610##                                                                        N                                       H                                                                                 ##STR611##        (CH.sub.2).sub.3                                                                              ##STR612##                                                                        N                                       H SCH.sub.2COOC.sub.5 H.sub.11 -n                                                                   (CH.sub.2).sub.3                                                                              ##STR613##                                                                        N                                       H                                                                                 ##STR614##        (CH.sub.2).sub.3                                                                              ##STR615##                                                                        N                                       H                                                                                 ##STR616##        (CH.sub.2).sub.3                                                                              ##STR617##                                                                        N                                       H OCH.sub.2 CH.sub.2OCH(CH.sub.2 F).sub.2                                                           (CH.sub.2).sub.3                                                                              ##STR618##                                                                        N                                       H SCH(CH.sub.3).sub.2                                                                               (CH.sub.2).sub.3                                                                              ##STR619##                                                                        N                                       H OCH.sub.2CClCH.sub.2                                                                              (CH.sub.2).sub.3                                                                              ##STR620##                                                                        N                                       H                                                                                 ##STR621##        (CH.sub.2).sub.3                                                                              ##STR622##                                                                        N                                       H OCH.sub.2 CN       (CH.sub.2).sub.3                                                                              ##STR623##                                                                        N                                       H OCH.sub.2 COOC.sub.4 H.sub.4OCH.sub.3                                                             (CH.sub.2).sub.3                                                                              ##STR624##                                                                        N                                       H OCH.sub.2COOCH(CH.sub.3)COOC.sub.2 H.sub.5                                                        (CH.sub.2).sub.3                                                                              ##STR625##                                                                        N                                       H OCH.sub.2COOCH.sub.2COOC.sub.2 H.sub.5                                                            (CH.sub.2).sub.3                                                                              ##STR626##                                                                        N                                       H OCHF.sub.2         (CH.sub.2).sub.3                                                                              ##STR627##                                                                        N                                       H OCH.sub.2 CH.sub.2OCH.sub.2 CF.sub.3                                                              (CH.sub.2).sub.3                                                                              ##STR628##                                                                        N                                       H NHCH.sub.3         (CH.sub.2).sub.3                                                                              ##STR629##                                                                        N                                       H NHC.sub.2 H.sub.5  (CH.sub.2).sub.3                                                                              ##STR630##                                                                        N                                       H N(CH.sub.3).sub.2  (CH.sub.2).sub.3                                                                              ##STR631##                                                                        N                                       H NHCH.sub.2COOC.sub.2 H.sub.5                                                                      (CH.sub.2).sub.3                                                                              ##STR632##                                                                        N                                       H                                                                                 ##STR633##        (CH.sub.2).sub.3                                                                              ##STR634##                                                                        N                                       H                                                                                 ##STR635##        (CH.sub.2).sub.3                                                                              ##STR636##                                                                        N                                       H NHSO.sub.2 CH.sub.3                                                                               (CH.sub.2).sub.3                                                                              ##STR637##                                                                        N                                       H NHSO.sub.2 C.sub.2 H.sub.5                                                                        (CH.sub.2).sub.3                                                                              ##STR638##                                                                        N                                       H NHSO.sub.2 C.sub.3 H.sub.7 -n                                                                     (CH.sub.2).sub.3                                                                              ##STR639##                                                                        N                                       H NHSO.sub.2 C.sub.3 H.sub.7 -i                                                                     (CH.sub.2).sub.3                                                                              ##STR640##                                                                        N                                       H NHSO.sub.2 C.sub.4 H.sub.9 -n                                                                     (CH.sub.2).sub.3                                                                              ##STR641##                                                                        N                                       H NHSO.sub.2 C.sub.8 H.sub.17 -n                                                                    (CH.sub.2).sub.3                                                                              ##STR642##                                                                        N                                       H NHCOCH.sub.3       (CH.sub.2).sub.3                                                                              ##STR643##                                                                        N                                       H NHCOC.sub.2 H.sub.5                                                                               (CH.sub.2).sub.3                                                                              ##STR644##                                                                        N                                       H NHCOCF.sub.3       (CH.sub.2).sub.3                                                                              ##STR645##                                                                        N                                       H N(CH.sub.3)SO.sub.2 CH.sub.3                                                                      (CH.sub.2).sub.3                                                                              ##STR646##                                                                        N                                       H N(CH.sub.3)SO.sub.2 C.sub.2 H.sub.5                                                               (CH.sub.2).sub.3                                                                              ##STR647##                                                                        N                                       H N(CH.sub.3)SO.sub.2 C.sub.3 H.sub.7 -n                                                            (CH.sub.2).sub.3                                                                              ##STR648##                                                                        N                                       H NHSO.sub.2 CF.sub.3                                                                               (CH.sub.2).sub.3                                                                              ##STR649##                                                                        N                                       H                                                                                 ##STR650##        (CH.sub.2).sub.3                                                                              ##STR651##                                                                        N                                       H NHSO.sub.2C.sub.4 H.sub.9 -n                                                                      (CH.sub.2).sub.3                                                                              ##STR652##                                                                        N                                       H N(CH.sub.3)SO.sub.2 CF.sub.3                                                                      (CH.sub.2).sub.3                                                                              ##STR653##                                                                        N                                       H                                                                                 ##STR654##        (CH.sub.2).sub.3                                                                              ##STR655##                                                                        N                                       H                                                                                 ##STR656##        (CH.sub.2).sub.3                                                                              ##STR657##                                                                        N                                       H                                                                                 ##STR658##        (CH.sub.2).sub.3                                                                              ##STR659##                                                                        N                                       Cl                                                                               OCH.sub.2 CF.sub.3 (CH.sub.2).sub.3                                                                              ##STR660##                                                                        N                                       Cl                                                                               OCF.sub.3          (CH.sub.2).sub.3                                                                              ##STR661##                                                                        N                                       Cl                                                                               OCH.sub.2 CH(CH.sub.3)OC.sub.2 H.sub.5                                                            (CH.sub.2).sub.3                                                                              ##STR662##                                                                        N                                       Cl                                                                                ##STR663##        (CH.sub.2).sub.3                                                                              ##STR664##                                                                        N                                       Cl                                                                               OCH.sub.2CHCH.sub.2                                                                               (CH.sub.2).sub.3                                                                              ##STR665##                                                                        N                                       Cl                                                                               OH                 (CH.sub.2).sub.3                                                                              ##STR666##                                                                        N                                       Cl                                                                               OCH.sub.2C CH      (CH.sub.2).sub.3                                                                              ##STR667##                                                                        N                                       Cl                                                                               SCH.sub.2 C CH     (CH.sub.2).sub.3                                                                              ##STR668##                                                                        N                                       Cl                                                                               OCH.sub.2 COOC.sub.2 H.sub.5                                                                      (CH.sub.2).sub.3                                                                              ##STR669##                                                                        N                                       Cl                                                                               SC(CH.sub.3).sub.3 (CH.sub.2).sub.3                                                                              ##STR670##                                                                        N                                       Cl                                                                               OCH.sub.2COOC.sub.5 H.sub.11 -n                                                                   (CH.sub.2).sub.3                                                                              ##STR671##                                                                        N                                       Cl                                                                               OCH(CH.sub.3)COOC.sub.2 H.sub.5                                                                   (CH.sub.2).sub.3                                                                              ##STR672##                                                                        N                                       Cl                                                                               OCH.sub.2 CH.sub.2OCH.sub.3                                                                       (CH.sub.2).sub.3                                                                              ##STR673##                                                                        N                                       Cl                                                                               OCH.sub.2 CH.sub.2OC.sub.2 H.sub.5                                                                (CH.sub.2).sub.3                                                                              ##STR674##                                                                        N                                       Cl                                                                               O(CH.sub.2 CH.sub.2 O).sub.2OC.sub.2 H.sub.5                                                      (CH.sub.2).sub.3                                                                              ##STR675##                                                                        N                                       Cl                                                                               SC.sub.3 H.sub.7 -n                                                                               (CH.sub.2).sub.3                                                                              ##STR676##                                                                        N                                       Cl                                                                               SC.sub.2 H.sub.5   (CH.sub.2).sub.3                                                                              ##STR677##                                                                        N                                       Cl                                                                               SCH.sub.3          (CH.sub.2).sub.3                                                                              ##STR678##                                                                        N                                       Cl                                                                               SCH.sub.2 COOC.sub.2 H.sub.5                                                                      (CH.sub.2).sub.3                                                                              ##STR679##                                                                        N                                       Cl                                                                               SCH.sub.2 CH.sub.2COOC.sub.2 H.sub.5                                                              (CH.sub.2).sub.3                                                                              ##STR680##                                                                        N                                       Cl                                                                               OCH.sub.2C CCH.sub.3                                                                              (CH.sub.2).sub.3                                                                              ##STR681##                                                                        N                                       Cl                                                                               OCH.sub.2CHCHCl    (CH.sub.2).sub.3                                                                              ##STR682##                                                                        N                                       Cl                                                                               OCH(CH.sub.3)C CH  (CH.sub.2).sub.3                                                                              ##STR683##                                                                        N                                       Cl                                                                               OCH(CH.sub.3)C CCH.sub.3                                                                          (CH.sub.2).sub.3                                                                              ##STR684##                                                                        N                                       Cl                                                                               OCH(CH.sub.3)CHCH.sub.2                                                                           (CH.sub.2).sub.3                                                                              ##STR685##                                                                        N                                       Cl                                                                               OCH.sub.2 CHCHCH.sub.3                                                                            (CH.sub.2).sub.3                                                                              ##STR686##                                                                        N                                       Cl                                                                               OCH.sub.3          (CH.sub.2).sub.3                                                                              ##STR687##                                                                        N                                       Cl                                                                               OC.sub.2 H.sub.5   (CH.sub.2).sub.3                                                                              ##STR688##                                                                        N                                       Cl                                                                               OC.sub.3 H.sub.7 -n                                                                               (CH.sub.2).sub.3                                                                              ##STR689##                                                                        N                                       Cl                                                                               OC.sub.3 H.sub.7 -iso                                                                             (CH.sub.2).sub.3                                                                              ##STR690##                                                                        N                                       Cl                                                                                ##STR691##        (CH.sub.2).sub.3                                                                              ##STR692##                                                                        N                                       Cl                                                                                ##STR693##        (CH.sub.2).sub.3                                                                              ##STR694##                                                                        N                                       Cl                                                                               OCH(CH.sub.2 F).sub.2                                                                             (CH.sub.2).sub.3                                                                              ##STR695##                                                                        N                                       Cl                                                                               OCH.sub.2C(CH.sub.3)CH.sub.2                                                                      (CH.sub.2).sub.3                                                                              ##STR696##                                                                        N                                       Cl                                                                                ##STR697##        (CH.sub.2).sub.3                                                                              ##STR698##                                                                        N                                       Cl                                                                                ##STR699##        (CH.sub.2).sub.3                                                                              ##STR700##                                                                        N                                       Cl                                                                                ##STR701##        (CH.sub.2).sub.3                                                                              ##STR702##                                                                        N                                       Cl                                                                                ##STR703##        (CH.sub.2).sub.3                                                                              ##STR704##                                                                        N                                       Cl                                                                                ##STR705##        (CH.sub.2).sub.3                                                                              ##STR706##                                                                        N                                       Cl                                                                                ##STR707##        (CH.sub.2).sub.3                                                                              ##STR708##                                                                        N                                       Cl                                                                               SCH.sub.2COOC.sub.5 H.sub.11 -n                                                                   (CH.sub.2).sub.3                                                                              ##STR709##                                                                        N                                       Cl                                                                                ##STR710##        (CH.sub.2).sub.3                                                                              ##STR711##                                                                        N                                       Cl                                                                                ##STR712##        (CH.sub.2).sub.3                                                                              ##STR713##                                                                        N                                       Cl                                                                               OCH.sub.2 CH.sub.2OCH(CH.sub.2 F).sub.2                                                           (CH.sub.2).sub.3                                                                              ##STR714##                                                                        N                                       Cl                                                                               SCH(CH.sub.3).sub.2                                                                               (CH.sub.2).sub.3                                                                              ##STR715##                                                                        N                                       Cl                                                                               OCH.sub.2CClCH.sub.2                                                                              (CH.sub.2).sub.3                                                                              ##STR716##                                                                        N                                       Cl                                                                                ##STR717##        (CH.sub.2).sub.3                                                                              ##STR718##                                                                        N                                       Cl                                                                               OCH.sub.2 CN       (CH.sub.2).sub.3                                                                              ##STR719##                                                                        N                                       Cl                                                                               OCH.sub.2 COOC.sub.2 H.sub.4OCH.sub.3                                                             (CH.sub.2).sub.3                                                                              ##STR720##                                                                        N                                       Cl                                                                               OCH.sub.2COOCH(CH.sub.3)COOC.sub.2 H.sub.5                                                        (CH.sub.2).sub.3                                                                              ##STR721##                                                                        N                                       Cl                                                                               OCH.sub.2COOCH.sub.2COOC.sub.2 H.sub.5                                                            (CH.sub.2).sub.3                                                                              ##STR722##                                                                        N                                       Cl                                                                               OCHF.sub.2         (CH.sub.2).sub.3                                                                              ##STR723##                                                                        N                                       Cl                                                                               OCH.sub.2 CH.sub.2OCH.sub.2 CF.sub.3                                                              (CH.sub.2).sub.3                                                                              ##STR724##                                                                        N                                       Cl                                                                               NHCH.sub.3         (CH.sub.2).sub.3                                                                              ##STR725##                                                                        N                                       Cl                                                                               NHC.sub.2 H.sub.5  (CH.sub.2).sub.3                                                                              ##STR726##                                                                        N                                       Cl                                                                               N(CH.sub.3).sub.2  (CH.sub.2).sub.3                                                                              ##STR727##                                                                        N                                       Cl                                                                               NHCH.sub.2COOC.sub.2 H.sub.5                                                                      (CH.sub.2).sub.3                                                                              ##STR728##                                                                        N                                       Cl                                                                                ##STR729##        (CH.sub.2).sub.3                                                                              ##STR730##                                                                        N                                       Cl                                                                                ##STR731##        (CH.sub.2).sub.3                                                                              ##STR732##                                                                        N                                       Cl                                                                               NHSO.sub.2 CH.sub.3                                                                               (CH.sub.2).sub.3                                                                              ##STR733##                                                                        N                                       Cl                                                                               NHSO.sub.2 C.sub.2 H.sub.5                                                                        (CH.sub.2).sub.3                                                                              ##STR734##                                                                        N                                       Cl                                                                               NHSO.sub.2 C.sub.3 H.sub.7 -n                                                                     (CH.sub.2).sub.3                                                                              ##STR735##                                                                        N                                       Cl                                                                               NHSO.sub.2 C.sub.3 H.sub.7 -i                                                                     (CH.sub.2).sub.3                                                                              ##STR736##                                                                        N                                       Cl                                                                               NHSO.sub.2 C.sub.4 H.sub.9 -n                                                                     (CH.sub.2).sub.3                                                                              ##STR737##                                                                        N                                       Cl                                                                               NHSO.sub.2 C.sub.8 H.sub.17 -n                                                                    (CH.sub.2).sub.3                                                                              ##STR738##                                                                        N                                       Cl                                                                               NHCOCH.sub.3       (CH.sub.2).sub.3                                                                              ##STR739##                                                                        N                                       Cl                                                                               NHCOC.sub.2 H.sub.5                                                                               (CH.sub.2).sub.3                                                                              ##STR740##                                                                        N                                       Cl                                                                               NHCOCF.sub.3       (CH.sub.2).sub.3                                                                              ##STR741##                                                                        N                                       Cl                                                                               N(CH.sub.3)SO.sub.2 CH.sub.3                                                                      (CH.sub.2).sub.3                                                                              ##STR742##                                                                        N                                       Cl                                                                               N(CH.sub.3)SO.sub.2 C.sub.2 H.sub.5                                                               (CH.sub.2).sub.3                                                                              ##STR743##                                                                        N                                       Cl                                                                               N(CH.sub.3)SO.sub.2 C.sub.3 H.sub.7 -n                                                            (CH.sub.2).sub.3                                                                              ##STR744##                                                                        N                                       Cl                                                                               NHSO.sub.2 CF.sub.3                                                                               (CH.sub.2).sub.3                                                                              ##STR745##                                                                        N                                       Cl                                                                                ##STR746##        (CH.sub.2).sub.3                                                                              ##STR747##                                                                        N                                       Cl                                                                               NHSO.sub.2C.sub.4 F.sub.9 -n                                                                      (CH.sub.2).sub.3                                                                              ##STR748##                                                                        N                                       Cl                                                                               N(CH.sub.3)SO.sub.2 CF.sub.3                                                                      (CH.sub.2).sub.3                                                                              ##STR749##                                                                        N                                       Cl                                                                                ##STR750##        (CH.sub.2).sub.3                                                                              ##STR751##                                                                        N                                       Cl                                                                                ##STR752##        (CH.sub.2).sub.3                                                                              ##STR753##                                                                        N                                       Cl                                                                                ##STR754##        (CH.sub.2).sub.3                                                                              ##STR755##                                                                        N                                       F OCH(CH.sub.2 F).sub.2                                                                             CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR756##                                                                        N                                       F OCH.sub.2C(CH.sub.3)CH.sub.2                                                                      CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR757##                                                                        N                                       F                                                                                 ##STR758##        CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR759##                                                                        N                                       F                                                                                 ##STR760##        CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR761##                                                                        N                                       F                                                                                 ##STR762##        CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR763##                                                                        N                                       F                                                                                 ##STR764##        CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR765##                                                                        N                                       F                                                                                 ##STR766##        CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR767##                                                                        N                                       F                                                                                 ##STR768##        CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR769##                                                                        N                                       F SCH.sub.2COOC.sub.5 H.sub.11 -n                                                                   CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR770##                                                                        N                                       F                                                                                 ##STR771##        CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR772##                                                                        N                                       F                                                                                 ##STR773##        CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR774##                                                                        N                                       F OCH.sub.2 CH.sub.2OCH(CH.sub.2 F).sub.2                                                           CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR775##                                                                        N                                       F SCH(CH.sub.3).sub.2                                                                               CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR776##                                                                        N                                       F OCH.sub.2CClCH.sub.2                                                                              CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR777##                                                                        N                                       F                                                                                 ##STR778##        CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR779##                                                                        N                                       F OCH.sub.2 CN       CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR780##                                                                        N                                       F OCH.sub.2 COOC.sub.2 H.sub.4OCH.sub.3                                                             CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR781##                                                                        N                                       F OCH.sub.2COOCH(CH.sub.3)COOC.sub.2 H.sub.5                                                        CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR782##                                                                        N                                       F OCH.sub.2COOCH.sub.2COOC.sub.2 H.sub.5                                                            CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR783##                                                                        N                                       F OCHF.sub.2         CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR784##                                                                        N                                       F OCH.sub.2 CH.sub.2OCH.sub.2 CF.sub.3                                                              CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR785##                                                                        N                                       F OCH.sub.2 CF.sub.3 CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR786##                                                                        N                                       F OCF.sub.3          CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR787##                                                                        N                                       F OCH.sub.2 CH(CH.sub.3)OC.sub.2 H.sub.5                                                            CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR788##                                                                        N                                       F                                                                                 ##STR789##        CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR790##                                                                        N                                       F OCH.sub.2CHCH.sub.2                                                                               CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR791##                                                                        N                                       F OH                 CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR792##                                                                        N                                       F OCH.sub.2C CH      CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR793##                                                                        N                                       F SCH.sub.2 C CH     CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR794##                                                                        N                                       F OCH.sub.2 COOC.sub.2 H.sub.5                                                                      CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR795##                                                                        N                                       F SC(CH.sub.3).sub.3 CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR796##                                                                        N                                       F OCH.sub.2COOC.sub.5 H.sub.11 -n                                                                   CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR797##                                                                        N                                       F OCH(CH.sub.3)COOC.sub.2 H.sub.5                                                                   CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR798##                                                                        N                                       F OCH.sub.2 CH.sub.2OCH.sub.3                                                                       CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR799##                                                                        N                                       F OCH.sub.2 CH.sub.2OC.sub.2 H.sub.5                                                                CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR800##                                                                        N                                       F O(CH.sub.2 CH.sub.2 O).sub.2OC.sub.2 H.sub.5                                                      CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR801##                                                                        N                                       F SC.sub.3 H.sub.7 -n                                                                               CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR802##                                                                        N                                       F SC.sub.2 H.sub.5   CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR803##                                                                        N                                       F SCH.sub.3          CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR804##                                                                        N                                       F SCH.sub.2 COOC.sub.2 H.sub.5                                                                      CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR805##                                                                        N                                       F SCH.sub.2 CH.sub.2COOC.sub.2 H.sub.5                                                              CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR806##                                                                        N                                       F OCH.sub.2C CCH.sub.3                                                                              CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR807##                                                                        N                                       F OCH.sub.2CHCHCl    CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR808##                                                                        N                                       F OCH(CH.sub.3)C CH  CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR809##                                                                        N                                       F OCH(CH.sub.3)C CCH.sub.3                                                                          CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR810##                                                                        N                                       F OCH(CH.sub.3)CHCH.sub.2                                                                           CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR811##                                                                        N                                       F OCH.sub.2 CHCHCH.sub.3                                                                            CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR812##                                                                        N                                       F OCH.sub.3          CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR813##                                                                        N                                       F OC.sub.2 H.sub.5   CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR814##                                                                        N                                       F OC.sub.3 H.sub.7 -n                                                                               CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR815##                                                                        N                                       F OC.sub.3 H.sub.7 -iso                                                                             CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR816##                                                                        N                                       F                                                                                 ##STR817##        CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR818##                                                                        N                                       F                                                                                 ##STR819##        CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR820##                                                                        N                                       F NHCH.sub.3         CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR821##                                                                        N                                       F NHC.sub.2 H.sub.5  CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR822##                                                                        N                                       F N(CH.sub.3).sub.2  CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR823##                                                                        N                                       F NHCH.sub.2COOC.sub.2 H.sub.5                                                                      CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR824##                                                                        N                                       F                                                                                 ##STR825##        CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR826##                                                                        N                                       F                                                                                 ##STR827##        CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR828##                                                                        N                                       F NHSO.sub.2 CH.sub.3                                                                               CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR829##                                                                        N                                       F NHSO.sub.2 C.sub.2 H.sub.5                                                                        CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR830##                                                                        N                                       F NHSO.sub.2 C.sub.3 H.sub.7 -n                                                                     CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR831##                                                                        N                                       F NHSO.sub.2 C.sub.3 H.sub.7 -i                                                                     CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR832##                                                                        N                                       F NHSO.sub.2 C.sub.4 H.sub.9 -n                                                                     CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR833##                                                                        N                                       F NHSO.sub.2 C.sub.8 H.sub.17 -n                                                                    CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR834##                                                                        N                                       F NHCOCH.sub.3       CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR835##                                                                        N                                       F NHCOC.sub.2 H.sub.5                                                                               CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR836##                                                                        N                                       F NHCOCF.sub.3       CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR837##                                                                        N                                       F N(CH.sub.3)SO.sub.2 CH.sub.3                                                                      CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR838##                                                                        N                                       F N(CH.sub.3)SO.sub.2 C.sub.2 H.sub.5                                                               CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR839##                                                                        N                                       F N(CH.sub.3)SO.sub.2 C.sub.3 H.sub.7 -n                                                            CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR840##                                                                        N                                       F NHSO.sub.2 CF.sub.3                                                                               CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR841##                                                                        N                                       F                                                                                 ##STR842##        CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR843##                                                                        N                                       F NHSO.sub.2C.sub.4 F.sub.9 -n                                                                      CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR844##                                                                        N                                       F N(CH.sub.3)SO.sub.2 CF.sub.3                                                                      CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR845##                                                                        N                                       F                                                                                 ##STR846##        CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR847##                                                                        N                                       F                                                                                 ##STR848##        CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR849##                                                                        N                                       F                                                                                 ##STR850##        CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR851##                                                                        N                                       H OCH.sub.2 CF.sub.3 CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR852##                                                                        N                                       H OCF.sub.3          CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR853##                                                                        N                                       H OCH.sub.2 CH(CH.sub.3)OC.sub.2 H.sub.5                                                            CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR854##                                                                        N                                       H                                                                                 ##STR855##        CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR856##                                                                        N                                       H OCH.sub.2CHCH.sub.2                                                                               CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR857##                                                                        N                                       H OH                 CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR858##                                                                        N                                       H OCH.sub.2C CH      CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR859##                                                                        N                                       H SCH.sub.2 C CH     CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR860##                                                                        N                                       H OCH.sub.2 COOC.sub.2 H.sub.5                                                                      CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR861##                                                                        N                                       H SC(CH.sub.3).sub.3 CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR862##                                                                        N                                       H OCH.sub.2COOC.sub.5 H.sub.11 -n                                                                   CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR863##                                                                        N                                       H OCH(CH.sub.3)COOC.sub.2 H.sub.5                                                                   CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR864##                                                                        N                                       H OCH.sub.2 CH.sub.2OCH.sub.3                                                                       CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR865##                                                                        N                                       H OCH.sub.2 CH.sub.2OC.sub.2 H.sub.5                                                                CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR866##                                                                        N                                       H O(CH.sub.2 CH.sub.2 O).sub.2OC.sub.2 H.sub.5                                                      CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR867##                                                                        N                                       H SC.sub.3 H.sub.7 -n                                                                               CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR868##                                                                        N                                       H SC.sub.2 H.sub.5   CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR869##                                                                        N                                       H SCH.sub.3          CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR870##                                                                        N                                       H SCH.sub.2 COOC.sub.2 H.sub.5                                                                      CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR871##                                                                        N                                       H SCH.sub.2 CH.sub.2COOC.sub.2 H.sub.5                                                              CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR872##                                                                        N                                       H OCH.sub.2C CCH.sub.3                                                                              CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR873##                                                                        N                                       H OCH.sub.2CHCHCl    CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR874##                                                                        N                                       H OCH(CH.sub.3)C CH  CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR875##                                                                        N                                       H OCH(CH.sub.3)C CCH.sub.3                                                                          CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR876##                                                                        N                                       H OCH(CH.sub.3)CHCH.sub.2                                                                           CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR877##                                                                        N                                       H OCH.sub.2 CHCHCH.sub.3                                                                            CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR878##                                                                        N                                       H OCH.sub.3          CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR879##                                                                        N                                       H OC.sub.2 H.sub.5   CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR880##                                                                        N                                       H OC.sub.3 H.sub.7 -n                                                                               CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR881##                                                                        N                                       H OC.sub.3 H.sub.7 -iso                                                                             CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR882##                                                                        N                                       H                                                                                 ##STR883##        CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR884##                                                                        N                                       H                                                                                 ##STR885##        CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR886##                                                                        N                                       H OCH(CH.sub.2 F).sub.2                                                                             CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR887##                                                                        N                                       H OCH.sub.2C(CH.sub.3)CH.sub.2                                                                      CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR888##                                                                        N                                       H                                                                                 ##STR889##        CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR890##                                                                        N                                       H                                                                                 ##STR891##        CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR892##                                                                        N                                       H                                                                                 ##STR893##        CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR894##                                                                        N                                       H                                                                                 ##STR895##        CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR896##                                                                        N                                       H                                                                                 ##STR897##        CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR898##                                                                        N                                       H                                                                                 ##STR899##        CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR900##                                                                        N                                       H SCH.sub.2 COOC.sub.5 H.sub.11 -n                                                                  CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR901##                                                                        N                                       H                                                                                 ##STR902##        CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR903##                                                                        N                                       H                                                                                 ##STR904##        CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR905##                                                                        N                                       H OCH.sub.2 CH.sub.2OCH(CH.sub.2 F).sub.2                                                           CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR906##                                                                        N                                       H SCH(CH.sub.3).sub.2                                                                               CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR907##                                                                        N                                       H OCH.sub.2CClCH.sub.2                                                                              CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR908##                                                                        N                                       H                                                                                 ##STR909##        CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR910##                                                                        N                                       H OCH.sub.2 CN       CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR911##                                                                        N                                       H OCH.sub.2 COOC.sub.2 H.sub.4OCH.sub.3                                                             CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR912##                                                                        N                                       H OCH.sub.2COOCH(CH.sub.3)COOC.sub.2 H.sub.5                                                        CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR913##                                                                        N                                       H OCH.sub.2COOCH.sub.2COOC.sub.2 H.sub.5                                                            CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR914##                                                                        N                                       H OCHF.sub.2         CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR915##                                                                        N                                       H OCH.sub.2 CH.sub.2OCH.sub.2 CF.sub.3                                                              CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR916##                                                                        N                                       H NHCH.sub.3         CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR917##                                                                        N                                       H NHC.sub.2 H.sub.5  CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR918##                                                                        N                                       H N(CH.sub.3).sub.2  CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR919##                                                                        N                                       H NHCH.sub.2COOC.sub.2 H.sub.5                                                                      CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR920##                                                                        N                                       H                                                                                 ##STR921##        CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR922##                                                                        N                                       H                                                                                 ##STR923##        CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR924##                                                                        N                                       H NHSO.sub.2 CH.sub.3                                                                               CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR925##                                                                        N                                       H NHSO.sub.2 C.sub.2 H.sub.5                                                                        CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR926##                                                                        N                                       H NHSO.sub.2 C.sub.3 H.sub.7 -n                                                                     CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR927##                                                                        N                                       H NHSO.sub.2 C.sub.3 H.sub.7 -i                                                                     CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR928##                                                                        N                                       H NHSO.sub.2 C.sub.4 H.sub.9 -n                                                                     CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR929##                                                                        N                                       H NHSO.sub.2 C.sub.8 H.sub.17 -n                                                                    CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR930##                                                                        N                                       H NHCOCH.sub.3       CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR931##                                                                        N                                       H NHCOC.sub.2 H.sub.5                                                                               CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR932##                                                                        N                                       H NHCOCF.sub.3       CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR933##                                                                        N                                       H N(CH.sub.3)SO.sub.2 CH.sub.3                                                                      CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR934##                                                                        N                                       H N(CH.sub.3)SO.sub.2 C.sub.2 H.sub.5                                                               CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR935##                                                                        N                                       H N(CH.sub.3)SO.sub.2 C.sub.3 H.sub.7 -n                                                            CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR936##                                                                        N                                       H NHSO.sub.2 CF.sub.3                                                                               CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR937##                                                                        N                                       H                                                                                 ##STR938##        CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR939##                                                                        N                                       H NHSO.sub.2C.sub.4 F.sub.9 -n                                                                      CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR940##                                                                        N                                       H N(CH.sub.3)SO.sub.2 CF.sub.3                                                                      CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR941##                                                                        N                                       H                                                                                 ##STR942##        CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR943##                                                                        N                                       H                                                                                 ##STR944##        CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR945##                                                                        N                                       H                                                                                 ##STR946##        CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR947##                                                                        N                                       Cl                                                                               OCH.sub.2 CF.sub.3 CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR948##                                                                        N                                       Cl                                                                               OCF.sub.3          CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR949##                                                                        N                                       Cl                                                                               OCH.sub.2 CH(CH.sub.3)OC.sub.2 H.sub.5                                                            CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR950##                                                                        N                                       Cl                                                                                ##STR951##        CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR952##                                                                        N                                       Cl                                                                               OCH.sub.2CHCH.sub.2                                                                               CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR953##                                                                        N                                       Cl                                                                               OH                 CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR954##                                                                        N                                       Cl                                                                               OCH.sub.2C CH      CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR955##                                                                        N                                       Cl                                                                               SCH.sub.2 C CH     CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR956##                                                                        N                                       Cl                                                                               OCH.sub.2 COOC.sub.2 H.sub.5                                                                      CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR957##                                                                        N                                       Cl                                                                               SC(CH.sub.3).sub.3 CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR958##                                                                        N                                       Cl                                                                               OCH.sub.2COOC.sub.5 H.sub.11 -n                                                                   CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR959##                                                                        N                                       Cl                                                                               OCH(CH.sub.3)COOC.sub.2 H.sub.5                                                                   CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR960##                                                                        N                                       Cl                                                                               OCH.sub.2 CH.sub.2OCH.sub.3                                                                       CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR961##                                                                        N                                       Cl                                                                               OCH.sub.2 CH.sub.2OC.sub.2 H.sub.5                                                                CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR962##                                                                        N                                       Cl                                                                               O(CH.sub.2 CH.sub.2 O).sub.2OC.sub.2 H.sub.5                                                      CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR963##                                                                        N                                       Cl                                                                               SC.sub.3 H.sub.7 -n                                                                               CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR964##                                                                        N                                       Cl                                                                               SC.sub.2 H.sub.5   CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR965##                                                                        N                                       Cl                                                                               SCH.sub.3          CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR966##                                                                        N                                       Cl                                                                               SCH.sub.2 COOC.sub.2 H.sub.5                                                                      CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR967##                                                                        N                                       Cl                                                                               SCH.sub.2 CH.sub.2COOC.sub.2 H.sub.5                                                              CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR968##                                                                        N                                       Cl                                                                               OCH.sub.2C CCH.sub.3                                                                              CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR969##                                                                        N                                       Cl                                                                               OCH.sub.2CHCHCl    CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR970##                                                                        N                                       Cl                                                                               OCH(CH.sub.3)C CH  CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR971##                                                                        N                                       Cl                                                                               OCH(CH.sub.3)C CCH.sub.3                                                                          CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR972##                                                                        N                                       Cl                                                                               OCH(CH.sub.3)CHCH.sub.2                                                                           CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR973##                                                                        N                                       Cl                                                                               OCH.sub.2 CHCHCH.sub.3                                                                            CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR974##                                                                        N                                       Cl                                                                               OCH.sub.3          CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR975##                                                                        N                                       Cl                                                                               OC.sub.2 H.sub.5   CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR976##                                                                        N                                       Cl                                                                               OC.sub.3 H.sub.7 -n                                                                               CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR977##                                                                        N                                       Cl                                                                               OC.sub.3 H.sub.7 -iso                                                                             CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR978##                                                                        N                                       Cl                                                                                ##STR979##        CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR980##                                                                        N                                       Cl                                                                                ##STR981##        CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR982##                                                                        N                                       Cl                                                                               OCH(CH.sub.2 F).sub.2                                                                             CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR983##                                                                        N                                       Cl                                                                               OCH.sub.2C(CH.sub.3)CH.sub.2                                                                      CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR984##                                                                        N                                       Cl                                                                                ##STR985##        CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR986##                                                                        N                                       Cl                                                                                ##STR987##        CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR988##                                                                        N                                       Cl                                                                                ##STR989##        CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR990##                                                                        N                                       Cl                                                                                ##STR991##        CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR992##                                                                        N                                       Cl                                                                                ##STR993##        CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR994##                                                                        N                                       Cl                                                                                ##STR995##        CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR996##                                                                        N                                       Cl                                                                               SCH.sub.2COOC.sub.5 H.sub.11 -n                                                                   CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR997##                                                                        N                                       Cl                                                                                ##STR998##        CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR999##                                                                        N                                       Cl                                                                                ##STR1000##       CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR1001##                                                                       N                                       Cl                                                                               OCH.sub.2 CH.sub.2OCH(CH.sub.2 F).sub.2                                                           CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR1002##                                                                       N                                       Cl                                                                               SCH(CH.sub.3).sub.2                                                                               CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR1003##                                                                       N                                       Cl                                                                               OCH.sub.2CClCH.sub.2                                                                              CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR1004##                                                                       N                                       Cl                                                                                ##STR1005##       CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR1006##                                                                       N                                       Cl                                                                               OCH.sub.2 CN       CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR1007##                                                                       N                                       Cl                                                                               OCH.sub.2 COOC.sub.2 H.sub.4OCH.sub.3                                                             CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR1008##                                                                       N                                       Cl                                                                               OCH.sub.2COOCH(CH.sub.3)COOC.sub.2 H.sub.5                                                        CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR1009##                                                                       N                                       Cl                                                                               OCH.sub.2COOCH.sub.2COOC.sub.2 H.sub.5                                                            CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR1010##                                                                       N                                       Cl                                                                               OCHF.sub.2         CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR1011##                                                                       N                                       Cl                                                                               OCH.sub.2 CH.sub.2OCH.sub.2 CF.sub.3                                                              CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR1012##                                                                       N                                       Cl                                                                               NHCH.sub.3         CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR1013##                                                                       N                                       Cl                                                                               NHC.sub.2 H.sub.5  CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR1014##                                                                       N                                       Cl                                                                               N(CH.sub.3).sub.2  CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR1015##                                                                       N                                       Cl                                                                               NHCH.sub.2COOC.sub.2 H.sub.5                                                                      CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR1016##                                                                       N                                       Cl                                                                                ##STR1017##       CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR1018##                                                                       N                                       Cl                                                                                ##STR1019##       CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR1020##                                                                       N                                       Cl                                                                               NHSO.sub.2 CH.sub.3                                                                               CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR1021##                                                                       N                                       Cl                                                                               NHSO.sub.2 C.sub.2 H.sub.5                                                                        CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR1022##                                                                       N                                       Cl                                                                               NHSO.sub.2 C.sub.3 H.sub.7 -n                                                                     CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR1023##                                                                       N                                       Cl                                                                               NHSO.sub.2 C.sub.3 H.sub.7 -i                                                                     CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR1024##                                                                       N                                       Cl                                                                               NHSO.sub.2 C.sub.4 H.sub.9 -n                                                                     CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR1025##                                                                       N                                       Cl                                                                               NHSO.sub.2 C.sub.8 H.sub.17 -n                                                                    CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR1026##                                                                       N                                       Cl                                                                               NHCOCH.sub.3       CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR1027##                                                                       N                                       Cl                                                                               NHCOC.sub.2 H.sub.5                                                                               CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR1028##                                                                       N                                       Cl                                                                               NHCOCF.sub.3       CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR1029##                                                                       N                                       Cl                                                                               N(CH.sub.3)SO.sub.2 CH.sub.3                                                                      CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR1030##                                                                       N                                       Cl                                                                               N(CH.sub.3)SO.sub.2 C.sub.2 H.sub.5                                                               CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR1031##                                                                       N                                       Cl                                                                               N(CH.sub.3)SO.sub.2 C.sub.3 H.sub.7 -n                                                            CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR1032##                                                                       N                                       Cl                                                                               NHSO.sub.2 CF.sub.3                                                                               CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR1033##                                                                       N                                       Cl                                                                                ##STR1034##       CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR1035##                                                                       N                                       Cl                                                                               NHSO.sub.2C.sub.4 F.sub.9 -n                                                                      CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR1036##                                                                       N                                       Cl                                                                               N(CH.sub.3)SO.sub.2 CF.sub.3                                                                      CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR1037##                                                                       N                                       Cl                                                                                ##STR1038##       CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR1039##                                                                       N                                       Cl                                                                                ##STR1040##       CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR1041##                                                                       N                                       Cl                                                                                ##STR1042##       CH.sub.2 C(CH.sub.3).sub.2CH.sub.2                                                            ##STR1043##                                                                       N                                       F OCH(CH.sub.2 F).sub.2                                                                             (CH.sub.2).sub.5                                                                              ##STR1044##                                                                       N                                       F OCH.sub.2C(CH.sub.3)CH.sub.2                                                                      (CH.sub.2).sub.5                                                                              ##STR1045##                                                                       N                                       F                                                                                 ##STR1046##       (CH.sub.2).sub.5                                                                              ##STR1047##                                                                       N                                       F                                                                                 ##STR1048##       (CH.sub.2).sub.5                                                                              ##STR1049##                                                                       N                                       F                                                                                 ##STR1050##       (CH.sub.2).sub.5                                                                              ##STR1051##                                                                       N                                       F                                                                                 ##STR1052##       (CH.sub.2).sub.5                                                                              ##STR1053##                                                                       N                                       F                                                                                 ##STR1054##       (CH.sub.2).sub.5                                                                              ##STR1055##                                                                       N                                       F                                                                                 ##STR1056##       (CH.sub.2).sub.5                                                                              ##STR1057##                                                                       N                                       F SCH.sub.2COOC.sub.5 H.sub.11 -n                                                                   (CH.sub.2).sub.5                                                                              ##STR1058##                                                                       N                                       F                                                                                 ##STR1059##       (CH.sub.2).sub.5                                                                              ##STR1060##                                                                       N                                       F                                                                                 ##STR1061##       (CH.sub.2).sub.5                                                                              ##STR1062##                                                                       N                                       F OCH.sub.2 CH.sub.2OCH(CH.sub.2 F).sub.2                                                           (CH.sub.2).sub.5                                                                              ##STR1063##                                                                       N                                       F SCH(CH.sub.3).sub.2                                                                               (CH.sub.2).sub.5                                                                              ##STR1064##                                                                       N                                       F OCH.sub.2CClCH.sub.2                                                                              (CH.sub.2).sub.5                                                                              ##STR1065##                                                                       N                                       F                                                                                 ##STR1066##       (CH.sub.2).sub.5                                                                              ##STR1067##                                                                       N                                       F OCH.sub.2 CN       (CH.sub.2).sub.5                                                                              ##STR1068##                                                                       N                                       F OCH.sub.2 COOC.sub.2 H.sub.4OCH.sub.3                                                             (CH.sub.2).sub.5                                                                              ##STR1069##                                                                       N                                       F OCH.sub.2COOCH(CH.sub.3)COOC.sub.2 H.sub.5                                                        (CH.sub.2).sub.5                                                                              ##STR1070##                                                                       N                                       F OCH.sub.2COOCH.sub.2COOC.sub.2 H.sub.5                                                            (CH.sub.2).sub.5                                                                              ##STR1071##                                                                       N                                       F OCHF.sub.2         (CH.sub.2).sub.5                                                                              ##STR1072##                                                                       N                                       F OCH.sub.2 CH.sub.2OCH.sub.2 CF.sub.3                                                              (CH.sub.2).sub.5                                                                              ##STR1073##                                                                       N                                       F OCH.sub.2 CF.sub.3 (CH.sub.2).sub.5                                                                              ##STR1074##                                                                       N                                       F OCF.sub.3          (CH.sub.2).sub.5                                                                              ##STR1075##                                                                       N                                       F OCH.sub.2 CH(CH.sub.3)OC.sub.2 H.sub.5                                                            (CH.sub.2).sub.5                                                                              ##STR1076##                                                                       N                                       F                                                                                 ##STR1077##       (CH.sub.2).sub.5                                                                              ##STR1078##                                                                       N                                       F OCH.sub.2CHCH.sub.2                                                                               (CH.sub.2).sub.5                                                                              ##STR1079##                                                                       N                                       F OH                 (CH.sub.2).sub.5                                                                              ##STR1080##                                                                       N                                       F OCH.sub.2C CN      (CH.sub.2).sub.5                                                                              ##STR1081##                                                                       N                                       F SCH.sub.2 C CH     (CH.sub.2).sub.5                                                                              ##STR1082##                                                                       N                                       F OCH.sub.2 COOC.sub.2 H.sub.5                                                                      (CH.sub.2).sub.5                                                                              ##STR1083##                                                                       N                                       F SC(CH.sub.3).sub.3 (CH.sub.2).sub.5                                                                              ##STR1084##                                                                       N                                       F OCH.sub.2COOC.sub.5 H.sub.11 -n                                                                   (CH.sub.2).sub.5                                                                              ##STR1085##                                                                       N                                       F OCH(CH.sub.3)COOC.sub.2 H.sub.5                                                                   (CH.sub.2).sub.5                                                                              ##STR1086##                                                                       N                                       F OCH.sub.2 CH.sub.2OCH.sub.3                                                                       (CH.sub.2).sub.5                                                                              ##STR1087##                                                                       N                                       F OCH.sub.2 CH.sub.2OC.sub.2 H.sub.5                                                                (CH.sub.2).sub.5                                                                              ##STR1088##                                                                       N                                       F O(CH.sub.2 CH.sub.2 O).sub.2OC.sub.2 H.sub.5                                                      (CH.sub.2).sub.5                                                                              ##STR1089##                                                                       N                                       F SC.sub.3 H.sub.7 -n                                                                               (CH.sub.2).sub.5                                                                              ##STR1090##                                                                       N                                       F SC.sub.2 H.sub.5   (CH.sub.2).sub.5                                                                              ##STR1091##                                                                       N                                       F SCH.sub.3          (CH.sub.2).sub.5                                                                              ##STR1092##                                                                       N                                       F SCH.sub.2 COOC.sub.2 H.sub.5                                                                      (CH.sub.2).sub.5                                                                              ##STR1093##                                                                       N                                       F SCH.sub.2 CH.sub.2COOC.sub.2 H.sub.5                                                              (CH.sub.2).sub.5                                                                              ##STR1094##                                                                       N                                       F OCH.sub.2C CCH.sub.3                                                                              (CH.sub.2).sub.5                                                                              ##STR1095##                                                                       N                                       F OCH.sub.2CHCHCl    (CH.sub.2).sub.5                                                                              ##STR1096##                                                                       N                                       F OCH(CH.sub.3)C CH  (CH.sub.2).sub.5                                                                              ##STR1097##                                                                       N                                       F OCH(CH.sub.3)C CCH.sub.3                                                                          (CH.sub.2).sub.5                                                                              ##STR1098##                                                                       N                                       F OCH(CH.sub.3)CHCH.sub.2                                                                           (CH.sub.2).sub.5                                                                              ##STR1099##                                                                       N                                       F OCH.sub.2 CHCHCH.sub.3                                                                            (CH.sub.2).sub.5                                                                              ##STR1100##                                                                       N                                       F OCH.sub.3          (CH.sub.2).sub.5                                                                              ##STR1101##                                                                       N                                       F OC.sub.2 H.sub.5   (CH.sub.2).sub.5                                                                              ##STR1102##                                                                       N                                       F OC.sub.3 H.sub.7 -n                                                                               (CH.sub.2).sub.5                                                                              ##STR1103##                                                                       N                                       F OC.sub.3 H.sub.7 -iso                                                                             (CH.sub.2).sub.5                                                                              ##STR1104##                                                                       N                                       F                                                                                 ##STR1105##       (CH.sub.2).sub.5                                                                              ##STR1106##                                                                       N                                       F                                                                                 ##STR1107##       (CH.sub.2).sub.5                                                                              ##STR1108##                                                                       N                                       F NHCH.sub.3         (CH.sub.2).sub.5                                                                              ##STR1109##                                                                       N                                       F NHC.sub.2 H.sub.5  (CH.sub.2).sub.5                                                                              ##STR1110##                                                                       N                                       F N(CH.sub.3).sub.2  (CH.sub.2).sub.5                                                                              ##STR1111##                                                                       N                                       F NHCH.sub.2COOC.sub.2 H.sub.5                                                                      (CH.sub.2).sub.5                                                                              ##STR1112##                                                                       N                                       F                                                                                 ##STR1113##       (CH.sub.2).sub.5                                                                              ##STR1114##                                                                       N                                       F                                                                                 ##STR1115##       (CH.sub.2).sub.5                                                                              ##STR1116##                                                                       N                                       F NHSO.sub.2 CH.sub.3                                                                               (CH.sub.2).sub.5                                                                              ##STR1117##                                                                       N                                       F NHSO.sub.2 C.sub.2 H.sub.5                                                                        (CH.sub.2).sub.5                                                                              ##STR1118##                                                                       N                                       F NHSO.sub.2 C.sub.3 H.sub.7 -n                                                                     (CH.sub.2).sub.5                                                                              ##STR1119##                                                                       N                                       F NHSO.sub.2 C.sub.3 H.sub.7 -i                                                                     (CH.sub.2).sub.5                                                                              ##STR1120##                                                                       N                                       F NHSO.sub.2 C.sub.4 H.sub.9 -n                                                                     (CH.sub.2).sub.5                                                                              ##STR1121##                                                                       N                                       F NHSO.sub.2 C.sub.8 H.sub.17 -n                                                                    (CH.sub.2).sub.5                                                                              ##STR1122##                                                                       N                                       F NHCOCH.sub.3       (CH.sub.2).sub.5                                                                              ##STR1123##                                                                       N                                       F NHCOC.sub.2 H.sub.5                                                                               (CH.sub.2).sub.5                                                                              ##STR1124##                                                                       N                                       F NHCOCF.sub.3       (CH.sub.2).sub.5                                                                              ##STR1125##                                                                       N                                       F N(CH.sub.3)SO.sub.2 CH.sub.3                                                                      (CH.sub.2).sub.5                                                                              ##STR1126##                                                                       N                                       F N(CH.sub.3)SO.sub.2 C.sub.2 H.sub.5                                                               (CH.sub.2).sub.5                                                                              ##STR1127##                                                                       N                                       F N(CH.sub.3)SO.sub.2 C.sub.3 H.sub.7 -n                                                            (CH.sub.2).sub.5                                                                              ##STR1128##                                                                       N                                       F NHSO.sub.2 CF.sub.3                                                                               (CH.sub.2).sub.5                                                                              ##STR1129##                                                                       N                                       F                                                                                 ##STR1130##       (CH.sub.2).sub.5                                                                              ##STR1131##                                                                       N                                       F NHSO.sub.2C.sub.4 F.sub.9 -n                                                                      (CH.sub.2).sub.5                                                                              ##STR1132##                                                                       N                                       F N(CH.sub.3)SO.sub.2 CF.sub.3                                                                      (CH.sub.2).sub.5                                                                              ##STR1133##                                                                       N                                       F                                                                                 ##STR1134##       (CH.sub.2).sub.5                                                                              ##STR1135##                                                                       N                                       F                                                                                 ##STR1136##       (CH.sub.2).sub.5                                                                              ##STR1137##                                                                       N                                       F                                                                                 ##STR1138##       (CH.sub.2).sub.5                                                                              ##STR1139##                                                                       N                                       H OCH.sub.2 CF.sub.3 (CH.sub.2).sub.5                                                                              ##STR1140##                                                                       N                                       H OCF.sub.3          (CH.sub.2).sub.5                                                                              ##STR1141##                                                                       N                                       H OCH.sub.2 CH(CH.sub.3)OC.sub.2 H.sub.5                                                            (CH.sub.2).sub.5                                                                              ##STR1142##                                                                       N                                       H                                                                                 ##STR1143##       (CH.sub.2).sub.5                                                                              ##STR1144##                                                                       N                                       H OCH.sub.2CHCH.sub.2                                                                               (CH.sub.2).sub.5                                                                              ##STR1145##                                                                       N                                       H OH                 (CH.sub.2).sub.5                                                                              ##STR1146##                                                                       N                                       H OCH.sub.2C CH      (CH.sub.2).sub.5                                                                              ##STR1147##                                                                       N                                       H SCH.sub.2 C CH     (CH.sub.2).sub.5                                                                              ##STR1148##                                                                       N                                       H OCH.sub.2 COOC.sub.2 H.sub.5                                                                      (CH.sub.2).sub.5                                                                              ##STR1149##                                                                       N                                       H SC(CH.sub.3).sub.3 (CH.sub.2).sub.5                                                                              ##STR1150##                                                                       N                                       H OCH.sub.2COOC.sub.5 H.sub.11 -n                                                                   (CH.sub.2).sub.5                                                                              ##STR1151##                                                                       N                                       H OCH(CH.sub.3)COOC.sub.2 H.sub.5                                                                   (CH.sub.2).sub.5                                                                              ##STR1152##                                                                       N                                       H OCH.sub.2 CH.sub.2OCH.sub.3                                                                       (CH.sub.2).sub.5                                                                              ##STR1153##                                                                       N                                       H OCH.sub.2 CH.sub.2OC.sub.2 H.sub.5                                                                (CH.sub.2).sub.5                                                                              ##STR1154##                                                                       N                                       H O(CH.sub.2 CH.sub.2 O).sub.2OC.sub.2 H.sub.5                                                      (CH.sub.2).sub.5                                                                              ##STR1155##                                                                       N                                       H SC.sub.3 H.sub.7 -n                                                                               (CH.sub.2).sub.5                                                                              ##STR1156##                                                                       N                                       H SC.sub.2 H.sub.5   (CH.sub.2).sub.5                                                                              ##STR1157##                                                                       N                                       H SCH.sub.3          (CH.sub.2).sub.5                                                                              ##STR1158##                                                                       N                                       H SCH.sub.2 COOC.sub.2 H.sub.5                                                                      (CH.sub.2).sub.5                                                                              ##STR1159##                                                                       N                                       H SCH.sub.2 CH.sub.2COOC.sub.2 H.sub.5                                                              (CH.sub.2).sub.5                                                                              ##STR1160##                                                                       N                                       H OCH.sub.2C CCH.sub.3                                                                              (CH.sub.2).sub.5                                                                              ##STR1161##                                                                       N                                       H OCH.sub.2 CHCHCl   (CH.sub.2).sub.5                                                                              ##STR1162##                                                                       N                                       H OCH(CH.sub.3)C CH  (CH.sub.2).sub.5                                                                              ##STR1163##                                                                       N                                       H OCH(CH.sub.3)C CCH.sub.3                                                                          (CH.sub.2).sub.5                                                                              ##STR1164##                                                                       N                                       H OCH(CH.sub.3)CHCH.sub.2                                                                           (CH.sub.2).sub.5                                                                              ##STR1165##                                                                       N                                       H OCH.sub.2 CHCHCH.sub.3                                                                            (CH.sub.2).sub.5                                                                              ##STR1166##                                                                       N                                       H OCH.sub.3          (CH.sub.2).sub.5                                                                              ##STR1167##                                                                       N                                       H OC.sub.2 H.sub.5   (CH.sub.2).sub.5                                                                              ##STR1168##                                                                       N                                       H OC.sub.3 H.sub.7 -n                                                                               (CH.sub.2).sub.5                                                                              ##STR1169##                                                                       N                                       H OC.sub.3 H.sub.7 -iso                                                                             (CH.sub.2).sub.5                                                                              ##STR1170##                                                                       N                                       H                                                                                 ##STR1171##       (CH.sub.2).sub.5                                                                              ##STR1172##                                                                       N                                       H                                                                                 ##STR1173##       (CH.sub.2).sub.5                                                                              ##STR1174##                                                                       N                                       H OCH(CH.sub.2 F).sub.2                                                                             (CH.sub.2).sub.5                                                                              ##STR1175##                                                                       N                                       H OCH.sub.2C(CH.sub.3)CH.sub.2                                                                      (CH.sub.2).sub.5                                                                              ##STR1176##                                                                       N                                       H                                                                                 ##STR1177##       (CH.sub.2).sub.5                                                                              ##STR1178##                                                                       N                                       H                                                                                 ##STR1179##       (CH.sub.2).sub.5                                                                              ##STR1180##                                                                       N                                       H                                                                                 ##STR1181##       (CH.sub.2).sub.5                                                                              ##STR1182##                                                                       N                                       H                                                                                 ##STR1183##       (CH.sub.2).sub.5                                                                              ##STR1184##                                                                       N                                       H                                                                                 ##STR1185##       (CH.sub.2).sub.5                                                                              ##STR1186##                                                                       N                                       H                                                                                 ##STR1187##       (CH.sub.2).sub.5                                                                              ##STR1188##                                                                       N                                       H SCH.sub.2COOC.sub.5 H.sub.11 -n                                                                   (CH.sub.2).sub.5                                                                              ##STR1189##                                                                       N                                       H                                                                                 ##STR1190##       (CH.sub.2).sub.5                                                                              ##STR1191##                                                                       N                                       H                                                                                 ##STR1192##       (CH.sub.2).sub.5                                                                              ##STR1193##                                                                       N                                       H OCH.sub.2 CH.sub.2OCH(CH.sub.2 F).sub.2                                                           (CH.sub.2).sub.5                                                                              ##STR1194##                                                                       N                                       H SCH(CH.sub.3).sub.2                                                                               (CH.sub.2).sub.5                                                                              ##STR1195##                                                                       N                                       H OCH.sub.2CClCH.sub.2                                                                              (CH.sub.2).sub.5                                                                              ##STR1196##                                                                       N                                       H                                                                                 ##STR1197##       (CH.sub.2).sub.5                                                                              ##STR1198##                                                                       N                                       H OCH.sub.2 CN       (CH.sub.2).sub.5                                                                              ##STR1199##                                                                       N                                       H OCH.sub.2 COOC.sub.2 H.sub.4OCH.sub.3                                                             (CH.sub.2).sub.5                                                                              ##STR1200##                                                                       N                                       H OCH.sub.2COOCH(CH.sub.3)COOC.sub.2 H.sub.5                                                        (CH.sub.2).sub.5                                                                              ##STR1201##                                                                       N                                       H OCH.sub.2COOCH.sub.2COOC.sub.2 H.sub.5                                                            (CH.sub.2).sub.5                                                                              ##STR1202##                                                                       N                                       H OCHF.sub.2         (CH.sub.2).sub.5                                                                              ##STR1203##                                                                       N                                       H OCH.sub.2 CH.sub.2OCH.sub.2 CF.sub.3                                                              (CH.sub.2).sub.5                                                                              ##STR1204##                                                                       N                                       H NHCH.sub.3         (CH.sub.2).sub.5                                                                              ##STR1205##                                                                       N                                       H NHC.sub.2 H.sub.5  (CH.sub.2).sub.5                                                                              ##STR1206##                                                                       N                                       H N(CH.sub.3).sub.2  (CH.sub.2).sub.5                                                                              ##STR1207##                                                                       N                                       H NHCH.sub.2COOC.sub.2 H.sub.5                                                                      (CH.sub.2).sub.5                                                                              ##STR1208##                                                                       N                                       H                                                                                 ##STR1209##       (CH.sub.2).sub.5                                                                              ##STR1210##                                                                       N                                       H                                                                                 ##STR1211##       (CH.sub.2).sub.5                                                                              ##STR1212##                                                                       N                                       H NHSO.sub.2 CH.sub.3                                                                               (CH.sub.2).sub.5                                                                              ##STR1213##                                                                       N                                       H NHSO.sub.2 C.sub.2 H.sub.5                                                                        (CH.sub.2).sub.5                                                                              ##STR1214##                                                                       N                                       H NHSO.sub.2 C.sub.3 H.sub.7 -n                                                                     (CH.sub.2).sub.5                                                                              ##STR1215##                                                                       N                                       H NHSO.sub.2 C.sub.3 H.sub.7 -i                                                                     (CH.sub.2).sub.5                                                                              ##STR1216##                                                                       N                                       H NHSO.sub.2 C.sub.4 H.sub.9 -n                                                                     (CH.sub.2).sub.5                                                                              ##STR1217##                                                                       N                                       H NHSO.sub.2 C.sub.8 H.sub.17 -n                                                                    (CH.sub.2).sub.5                                                                              ##STR1218##                                                                       N                                       H NHCOCH.sub.3       (CH.sub.2).sub.5                                                                              ##STR1219##                                                                       N                                       H NHCOC.sub.2 H.sub.5                                                                               (CH.sub.2).sub.5                                                                              ##STR1220##                                                                       N                                       H NHCOCF.sub.3       (CH.sub.2).sub.5                                                                              ##STR1221##                                                                       N                                       H N(CH.sub.3)SO.sub.2 CH.sub.3                                                                      (CH.sub.2).sub.5                                                                              ##STR1222##                                                                       N                                       H N(CH.sub.3)SO.sub.2 C.sub.2 H.sub.5                                                               (CH.sub.2).sub.5                                                                              ##STR1223##                                                                       N                                       H N(CH.sub.3)SO.sub.2 C.sub.3 H.sub.7 -n                                                            (CH.sub.2).sub.5                                                                              ##STR1224##                                                                       N                                       H NHSO.sub.2 CF.sub.3                                                                               (CH.sub.2).sub.5                                                                              ##STR1225##                                                                       N                                       H                                                                                 ##STR1226##       (CH.sub.2).sub.5                                                                              ##STR1227##                                                                       N                                       H NHSO.sub.2C.sub.4 F.sub.9 -n                                                                      (CH.sub.2).sub.5                                                                              ##STR1228##                                                                       N                                       H N(CH.sub.3)SO.sub.2 CF.sub.3                                                                      (CH.sub.2).sub.5                                                                              ##STR1229##                                                                       N                                       H                                                                                 ##STR1230##       (CH.sub.2).sub.5                                                                              ##STR1231##                                                                       N                                       H                                                                                 ##STR1232##       (CH.sub.2).sub.5                                                                              ##STR1233##                                                                       N                                       H                                                                                 ##STR1234##       (CH.sub.2).sub.5                                                                              ##STR1235##                                                                       N                                       Cl                                                                               OCH.sub.2 CF.sub.3 (CH.sub.2).sub.5                                                                              ##STR1236##                                                                       N                                       Cl                                                                               OCF.sub.3          (CH.sub.2).sub.5                                                                              ##STR1237##                                                                       N                                       Cl                                                                               OCH.sub.2 CH(CH.sub.3)OC.sub.2 H.sub.5                                                            (CH.sub.2).sub.5                                                                              ##STR1238##                                                                       N                                       Cl                                                                                ##STR1239##       (CH.sub.2).sub.5                                                                              ##STR1240##                                                                       N                                       Cl                                                                               OCH.sub.2CHCH.sub.2                                                                               (CH.sub.2).sub.5                                                                              ##STR1241##                                                                       N                                       Cl                                                                               OH                 (CH.sub.2).sub.5                                                                              ##STR1242##                                                                       N                                       Cl                                                                               OCH.sub.2C CH      (CH.sub.2).sub.5                                                                              ##STR1243##                                                                       N                                       Cl                                                                               SCH.sub.2 C CH     (CH.sub.2).sub.5                                                                              ##STR1244##                                                                       N                                       Cl                                                                               OCH.sub.2 COOC.sub.2 H.sub.5                                                                      (CH.sub.2).sub.5                                                                              ##STR1245##                                                                       N                                       Cl                                                                               SC(CH.sub.3).sub.3 (CH.sub.2).sub.5                                                                              ##STR1246##                                                                       N                                       Cl                                                                               OCH.sub.2 COOC.sub.2 H.sub.5 H.sub.11 -n                                                          (CH.sub.2).sub.5                                                                              ##STR1247##                                                                       N                                       Cl                                                                               OCH(CH.sub.3)COOC.sub.2 H.sub.5                                                                   (CH.sub.2).sub.5                                                                              ##STR1248##                                                                       N                                       Cl                                                                               OCH.sub.2 CH.sub.2OCH.sub.3                                                                       (CH.sub.2).sub.5                                                                              ##STR1249##                                                                       N                                       Cl                                                                               OCH.sub.2 CH.sub.2OC.sub.2 H.sub.5                                                                (CH.sub.2).sub.5                                                                              ##STR1250##                                                                       N                                       Cl                                                                               O(CH.sub.2 CH.sub.2 O).sub.2OC.sub.2 H.sub.5                                                      (CH.sub.2).sub.5                                                                              ##STR1251##                                                                       N                                       Cl                                                                               SC.sub.3 H.sub.7 -n                                                                               (CH.sub.2).sub.5                                                                              ##STR1252##                                                                       N                                       Cl                                                                               SC.sub.2 H.sub.5   (CH.sub.2).sub.5                                                                              ##STR1253##                                                                       N                                       Cl                                                                               SCH.sub.3          (CH.sub.2).sub.5                                                                              ##STR1254##                                                                       N                                       Cl                                                                               SCH.sub.2 COOC.sub.2 H.sub.5                                                                      (CH.sub.2).sub.5                                                                              ##STR1255##                                                                       N                                       Cl                                                                               SCH.sub.2 CH.sub.2COOC.sub.2 H.sub.5                                                              (CH.sub.2).sub.5                                                                              ##STR1256##                                                                       N                                       Cl                                                                               OCH.sub.2C CCH.sub.3                                                                              (CH.sub.2).sub.5                                                                              ##STR1257##                                                                       N                                       Cl                                                                               OCH.sub.2CHCHCl    (CH.sub.2).sub.5                                                                              ##STR1258##                                                                       N                                       Cl                                                                               OCH(CH.sub.3)C CH  (CH.sub.2).sub.5                                                                              ##STR1259##                                                                       N                                       Cl                                                                               OCH(CH.sub.3 C CCH.sub.3                                                                          (CH.sub.2).sub.5                                                                              ##STR1260##                                                                       N                                       Cl                                                                               OCH(CH.sub.3)CHCH.sub.2                                                                           (CH.sub.2).sub.5                                                                              ##STR1261##                                                                       N                                       Cl                                                                               OCH.sub.2 CHCHCH.sub.3                                                                            (CH.sub.2).sub.5                                                                              ##STR1262##                                                                       N                                       Cl                                                                               OCH.sub.3          (CH.sub.2).sub.5                                                                              ##STR1263##                                                                       N                                       Cl                                                                               OC.sub.2 H.sub.5   (CH.sub.2).sub.5                                                                              ##STR1264##                                                                       N                                       Cl                                                                               OC.sub.3 H.sub.7 -n                                                                               (CH.sub.2).sub.5                                                                              ##STR1265##                                                                       N                                       Cl                                                                               OC.sub.3 H.sub.7 -iso                                                                             (CH.sub.2).sub.5                                                                              ##STR1266##                                                                       N                                       Cl                                                                                ##STR1267##       (CH.sub.2).sub.5                                                                              ##STR1268##                                                                       N                                       Cl                                                                                ##STR1269##       (CH.sub.2).sub.5                                                                              ##STR1270##                                                                       N                                       Cl                                                                               OCH(CH.sub.2 F).sub.2                                                                             (CH.sub.2).sub.5                                                                              ##STR1271##                                                                       N                                       Cl                                                                               OCH.sub.2C(CH.sub.3)CH.sub.2                                                                      (CH.sub.2).sub.5                                                                              ##STR1272##                                                                       N                                       Cl                                                                                ##STR1273##       (CH.sub.2).sub.5                                                                              ##STR1274##                                                                       N                                       Cl                                                                                ##STR1275##       (CH.sub.2).sub.5                                                                              ##STR1276##                                                                       N                                       Cl                                                                                ##STR1277##       (CH.sub.2).sub.5                                                                              ##STR1278##                                                                       N                                       Cl                                                                                ##STR1279##       (CH.sub.2).sub.5                                                                              ##STR1280##                                                                       N                                       Cl                                                                                ##STR1281##       (CH.sub.2).sub.5                                                                              ##STR1282##                                                                       N                                       Cl                                                                                ##STR1283##       (CH.sub.2).sub.5                                                                              ##STR1284##                                                                       N                                       Cl                                                                               SCH.sub.2COOC.sub.5 H.sub.11 -n                                                                   (CH.sub.2).sub.5                                                                              ##STR1285##                                                                       N                                       Cl                                                                                ##STR1286##       (CH.sub.2).sub.5                                                                              ##STR1287##                                                                       N                                       Cl                                                                                ##STR1288##       (CH.sub.2).sub.5                                                                              ##STR1289##                                                                       N                                       Cl                                                                               OCH.sub.2 CH.sub.2OCH(CH.sub.2 F).sub.2                                                           (CH.sub.2).sub.5                                                                              ##STR1290##                                                                       N                                       Cl                                                                               SCH(CH.sub.3).sub.2                                                                               (CH.sub.2).sub.5                                                                              ##STR1291##                                                                       N                                       Cl                                                                               OCH.sub.2CClCH.sub.2                                                                              (CH.sub.2).sub.5                                                                              ##STR1292##                                                                       N                                       Cl                                                                                ##STR1293##       (CH.sub.2).sub.5                                                                              ##STR1294##                                                                       N                                       Cl                                                                               OCH.sub.2 CN       (CH.sub.2).sub.5                                                                              ##STR1295##                                                                       N                                       Cl                                                                               OCH.sub.2 COOC.sub.2 H.sub.4 OCH.sub.3                                                            (CH.sub.2).sub.5                                                                              ##STR1296##                                                                       N                                       Cl                                                                               OCH.sub.2COOCH(CH.sub.3)COOC.sub.2 H.sub.5                                                        (CH.sub.2).sub.5                                                                              ##STR1297##                                                                       N                                       Cl                                                                               OCH.sub.2COOCH.sub.2COOC.sub.2 H.sub.5                                                            (CH.sub.2).sub.5                                                                              ##STR1298##                                                                       N                                       Cl                                                                               OCHF.sub.2         (CH.sub.2).sub.5                                                                              ##STR1299##                                                                       N                                       Cl                                                                               OCH.sub.2 CH.sub.2OCH.sub.2 CF.sub.3                                                              (CH.sub.2).sub.5                                                                              ##STR1300##                                                                       N                                       Cl                                                                               NHCH.sub.3         (CH.sub.2).sub.5                                                                              ##STR1301##                                                                       N                                       Cl                                                                               NHC.sub.2 H.sub.5  (CH.sub.2).sub.5                                                                              ##STR1302##                                                                       N                                       Cl                                                                               N(CH.sub.3).sub.2  (CH.sub.2).sub.5                                                                              ##STR1303##                                                                       N                                       Cl                                                                               NHCH.sub.2COOC.sub.2 H.sub.5                                                                      (CH.sub.2).sub.5                                                                              ##STR1304##                                                                       N                                       Cl                                                                                ##STR1305##       (CH.sub.2).sub.5                                                                              ##STR1306##                                                                       N                                       Cl                                                                                ##STR1307##       (CH.sub.2).sub.5                                                                              ##STR1308##                                                                       N                                       Cl                                                                               NHSO.sub.2 CH.sub.3                                                                               (CH.sub.2).sub.5                                                                              ##STR1309##                                                                       N                                       Cl                                                                               NHSO.sub.2 C.sub.2 H.sub.5                                                                        (CH.sub.2).sub.5                                                                              ##STR1310##                                                                       N                                       Cl                                                                               NHSO.sub.2 C.sub.3 H.sub.7 -n                                                                     (CH.sub.2).sub.5                                                                              ##STR1311##                                                                       N                                       Cl                                                                               NHSO.sub.2 C.sub.3 H.sub.7 -i                                                                     (CH.sub.2).sub.5                                                                              ##STR1312##                                                                       N                                       Cl                                                                               NHSO.sub.2 C.sub.4 H.sub.9 -n                                                                     (CH.sub.2).sub.5                                                                              ##STR1313##                                                                       N                                       Cl                                                                               NHSO.sub.2 C.sub.8 H.sub.17 -n                                                                    (CH.sub.2).sub.5                                                                              ##STR1314##                                                                       N                                       Cl                                                                               NHCOCH.sub.3       (CH.sub.2).sub.5                                                                              ##STR1315##                                                                       N                                       Cl                                                                               NHCOC.sub.2 H.sub.5                                                                               (CH.sub.2).sub.5                                                                              ##STR1316##                                                                       N                                       Cl                                                                               NHCOCF.sub.3       (CH.sub.2).sub.5                                                                              ##STR1317##                                                                       N                                       Cl                                                                               N(CH.sub.3)SO.sub.2 CH.sub.3                                                                      (CH.sub.2).sub.5                                                                              ##STR1318##                                                                       N                                       Cl                                                                               N(CH.sub.3)SO.sub.2 C.sub.2 H.sub.5                                                               (CH.sub.2).sub.5                                                                              ##STR1319##                                                                       N                                       Cl                                                                               N(CH.sub.3)SO.sub.2 C.sub.3 H.sub.7 -n                                                            (CH.sub.2).sub.5                                                                              ##STR1320##                                                                       N                                       Cl                                                                               NHSO.sub.2 CF.sub.3                                                                               (CH.sub.2).sub.5                                                                              ##STR1321##                                                                       N                                       Cl                                                                                ##STR1322##       (CH.sub.2).sub.5                                                                              ##STR1323##                                                                       N                                       Cl                                                                               NHSO.sub.2C.sub.4 F.sub.9 -n                                                                      (CH.sub.2).sub.5                                                                              ##STR1324##                                                                       N                                       Cl                                                                               N(CH.sub.3)SO.sub.2 CF.sub.3                                                                      (CH.sub.2).sub.5                                                                              ##STR1325##                                                                       N                                       Cl                                                                                ##STR1326##       (CH.sub.2).sub.5                                                                              ##STR1327##                                                                       N                                       Cl                                                                                ##STR1328##       (CH.sub.2).sub.5                                                                              ##STR1329##                                                                       N                                       Cl                                                                                ##STR1330##       (CH.sub.2).sub.5                                                                              ##STR1331##                                                                       N                                       __________________________________________________________________________

The above-listed general radical definitions, or those given in preference ranges, apply both to the end products of the formula (I) and, correspondingly, to the starting compounds or intermediates which are in each case required for the preparation. These radical definitions may be combined among themselves arbitrarily, i.e. between the given ranges of preferred compounds as well.

If, for example, 1- N-(4-cyano-2,5-difluoro-phenyl)!2-imino-piperidine-thiocarboxamide is used as the starting compound, and sulphur as the oxidizing agent, the course of the reaction in process (a) according to the invention can then be outlined by the following formula scheme: ##STR1332##

If, for example, 1- N-(4-cyano-2-chloro-5-ethoxyphenyl)!-tetrahydro-(2H)-pyridazine-thiocarboxamide and phosgene are used as the starting compounds, the course of the reaction in process (b) according to the invention can then be outlined by the following formula scheme: ##STR1333##

If, for example, 9-(4-cyano-2,5-difluoro-phenyl-imino)-8-thia-1,6-diazabicyclo 4.3.0!nonan-7-one and methane-sulphonamide are used as the starting compounds, the course of the reaction in process (c) according to the invention can then be outlined by the following formula scheme: ##STR1334##

The substituted thiocarbonylamino compounds to be used in process (a) according to the invention as starting compounds for preparing the compounds of the formula (I) are defined generally by the formula (II). In formula (II), R¹, R² and A preferably or in particular have those meanings which have already been indicated above, in connection with the description of the compounds of the formula (I) according to the invention, as being preferred or in particular preferred for R¹, R² and A.

The substituted thiocarbonylamino compounds of the formula (II) required as starting compounds are still not known from the literature; as novel compounds, they are a subject of the present application.

The novel compounds of the formula (II) are obtained when cyanoaryl isothiocyanates of the general formula (VIII) ##STR1335## in which R¹ and R² have the abovementioned meanings,

are reacted with imino compounds of the general formula (IX) ##STR1336## in which A has the abovementioned meaning,

optionally in the presence of a diluent, such as, for example, toluene, and at temperatures of between 0° C. and 100° C. (cf. the preparation examples).

With the exception of 3-chloro-4-cyano-phenyl isothiocyanate and 3-trifluoromethyl-4-cyanophenyl isothiocyanate, the cyanoaryl isothiocyanates of the formula (VIII) required as precursors are still not known from the literature; as novel compounds, they are a subject of the present application.

The novel cyanoaryl isothiocyanates of the formula (VIII) are obtained when corresponding cyanoarylamines of the general formula (X) ##STR1337## in which R¹ and R² have the abovementioned meanings,

are reacted with thiophosgene, optionally in the presence of a reaction auxiliary, such as, for example, calcium carbonate, and optionally in the presence of diluents, such as, for example, methylene chloride and water, and at temperatures of between 0° C. and 100° C. (cf. the preparation examples).

The cyanoarylamines of the general formula (X) are known and/or can be prepared by processes which are known per se (cf. EP-A 224001).

The cyanoarylamines of the general formula (Xa) ##STR1338## in which R¹, R⁴ and R⁵ have the abovementioned meanings, and

Y represents CO or SO₂,

are still not known from the literature and, as novel compounds, are a subject of the present application.

The novel cyanoarylamines of the formula (Xa) are obtained when corresponding halogenoarylamines of the general formula (XI) ##STR1339## in which R¹ and X¹ have the abovementioned meanings,

are reacted with amides of the general formula (XII)

    R.sup.4 --NH--Y--R.sup.5 (XII)

in which

R⁴, R⁵ and Y have the abovementioned meanings,

optionally in the presence of an acid acceptor, such as, for example, potassium carbonate, and optionally in the presence of a diluent, such as, for example, N-methylpyrrolidone, and at temperatures of between 100° C. and 200° C. (cf. the preparation examples).

The imino compounds of the formula (IX), which are additionally required as precursors, are known and/or can be prepared by processes which are known per se (cf. Angew. Chem. 81 (1969), 431-432; loc. cit. Int. Ed. Engl. 8 (1969), 457-458; J. Org. Chem. 33 (1968), 2109-2111).

The process (a) according to the invention is carried out using oxidizing agents or dehydrogenating agents. In this context, practically all reagents are suitable which are customarily used for oxidizing or dehydrogenating organic chemical compounds. Those which may be mentioned by way of example are oxygen, sulphur, hydrogen peroxide, sodium persulphate, sodium thiosulphate, chlorine, bromine and iodine.

The process (a) according to the invention is preferably carried out using a diluent. All customary organic or inorganic solvents are suitable for use as diluents. These include, in particular, aliphatic, alicyclic or aromatic, optionally halogenated, hydrocarbons, such as, for example, benzine, benzene, toluene, xylene, chlorobenzene, dichlorobenzene, petroleum ether, hexane, cyclohexane, dichloromethane, chloroform or carbon tetrachloride; ethers, such as diethyl ether, diisopropyl ether, dioxane, tetrahydrofuran, ethylene glycol dimethyl ether or ethylene glycol diethyl ether; ketones, such as acetone, butanone or methyl isobutyl ketone; nitriles, such as acetonitrile, propionitrile or benzonitrile; amides, such as N,N-dimethylformamide, N,N-dimethylacetamide, N-methylformanilide, N-methylpyrrolidone or hexamethylphosphoric triamide; esters, such as methyl acetate or ethyl acetate; sulphoxides, such as dimethyl sulphoxide, or alcohols, such as methanol, ethanol, n- or i-propanol, or n-, i-, s- or t-butanol, as well as water.

The process (a) according to the invention is optionally carried out in the presence of a suitable reaction auxiliary. The customary inorganic or organic bases are particularly suitable for use as such reaction auxiliaries. These bases include, for example, alkaline earth metal or alkali metal hydroxides, such as sodium hydroxide, potassium hydroxide, calcium hydroxide, and also ammonium hydroxide, alkali metal (hydrogen)carbonates, such as sodium (hydrogen)carbonate, potassium (hydrogen)carbonate or ammonium carbonate, alkali metal or alkaline earth metal acetates, such as sodium acetate, potassium acetate, calcium acetate or ammonium acetate, alkali metal alcoholates, such as sodium or potassium methoxide, sodium or potassium ethoxide, or sodium or potassium tert-butoxide, as well as tertiary amines, such as trimethylamine, triethylamine, tributylamine, N,N-dimethylaniline, pyridine, N-methylpyridine, 4-dimethylaminopyridine, diazabicyclooctane (DABCO), diazabicyclononene (DBN) or diazabicycloundecene (DBU).

In carrying out the process (a) according to the invention, the reaction temperatures can be varied over a relatively wide range. In general, temperatures of between 0° C. and 150° C., preferably temperatures of between 20° C. and 120° C., are employed.

In general the process (a) according to the invention is carried out under atmospheric pressure. However, it is also possible to carry it out under elevated or reduced pressure.

For carrying out the process (a) according to the invention, the starting compounds which are in each case required are generally employed in approximately equimolar or equivalent quantities. However, it is also possible to use one of the components employed on each occasion in a relatively large excess. In general, the reaction is carried out in a suitable diluent and the reaction mixture is stirred, until conversion is complete, at the temperature which is required in each case. The working up is effected in accordance with customary methods.

The substituted thiocarbonylamino compounds to be used in process (b) according to the invention as starting compounds for preparing the compounds of the formula (I) are defined generally by the formula (III).

In formula (III), R¹, R² and A preferably or in particular have those meanings which have already been indicated above, in connection with the description of the compounds of the formula (I) according to the invention, as being preferred or particularly preferred for R¹, R² and A.

The substituted thiocarbonylamino compounds of the formula (III) which are required as starting compounds are still not known from the literature; as novel compounds, they are a subject of the present application.

The novel compounds of the formula (III) are obtained when diazacycloalkanes or diazacycloalkenes of the general formula (XI) ##STR1340## in which A has the abovementioned meaning,

are reacted with cyanoaryl isothiocyanates of the-general formula (VIII)--above--

optionally in the presence of a diluent, such as, for example, toluene, and at temperatures of between 0° C. and 100° C. (cf. the preparation examples).

The diazacycloalkanes or diazacycloalkenes of the formula (XI) which are required as precursors are known and/or can be prepared by processes which are known per se (cf. J. Org. Chem. 35 (1970), 1468-1471; Tetrahedron 31 (1975), 165-170).

The process (b) according to the invention is preferably carried out using a diluent. All customary inert organic solvents are suitable as diluents. The solvents include, in particular, aliphatic, alicyclic or aromatic, optionally halogenated, hydrocarbons, such as, for example, benzine, benzene, toluene, xylene, chlorobenzene, dichlorobenzene, petroleum ether, hexane, cyclohexane, dichloromethane, chloroform or carbon tetrachloride; ethers, such as diethyl ether, diisopropyl ether, dioxane, tetrahydrofuran, ethylene glycol dimethyl ether or ethylene glycol diethyl ether; amides, such as N,N-dimethylformamide, N,N-dimethylacetamide, N-methylformanilide, N-methylpyrrolidone or hexamethylphosphoric triamide; esters, such as methyl acetate or ethyl acetate; sulphoxides, such as dimethyl sulphoxide.

In carrying out process (b) according to the invention, the reaction temperatures can be varied over a relatively wide range. In general, temperatures of between 0° C. and 150° C., preferably temperatures of between 10° C. and 100° C., are employed.

In general, process (b) according to the invention is carried out under atmospheric pressure. However, it is also possible to carry it out under elevated or reduced pressure.

For carrying out process (b) according to the invention, the starting compounds which are required in each case are generally employed in approximately equimolar or equivalent quantities. However, it is also possible to use one of the components employed on each occasion in a relatively large excess. In general, the reaction is carried out in a suitable diluent and the reaction mixture is stirred, until the conversion is complete, at the temperature which is required in each case. The working up is effected in accordance with customary methods (cf. the preparation examples).

The substituted cyanoarylimino heterocycles to be used as starting compounds in process (c) according to the invention are defined generally by the formula (Ia). In formula (Ia), R¹, A, E and G preferably or in particular have those meanings which have already been indicated above, in connection with the description of the compounds of the formula (I) according to the invention, as being preferred or particularly preferred for R¹, A, E and G;

X¹ preferably represents fluorine or chlorine, and, in particular, represents fluorine.

The starting compounds of the formula (Ia) are novel compounds, in accordance with the invention; they may be prepared by processes (a) or (b) according to the invention.

Process (c) according to the invention is preferably carried out using a diluent. All customary organic or inorganic solvents are suitable for use as diluents. These solvents include, in particular, aliphatic, alicyclic or aromatic, optionally halogenated, hydrocarbons, such as, for example, benzine, benzene, toluene, xylene, chlorobenzene, dichlorobenzene, petroleum ether, hexane, cyclohexane, dichloromethane, chloroform or carbon tetrachloride; ethers, such as diethyl ether, diisopropyl ether, dioxane, tetrahydrofuran, ethylene glycol dimethyl ether or ethylene glycol diethyl ether; ketones, such as acetone, butanone -or methyl isobutyl ketone; nitriles, such as acetonitrile, propionitrile or benzonitrile; amaides, such as N,N-dimethylformamide, N,N-dimethylacetamide, N-methylformanilide, N-methylpyrrolidone or hexamethylphosphoric triamide; esters, such as methyl acetate or ethyl acetate; sulphoxides, such as dimethyl sulphoxide, or alcohols, such as methanol, ethanol, n- or i-propanol or n-, i-, s- or t-butanol, as well as water.

The process (c) according to the invention is optionally carried out in the presence of an acid acceptor. The customary inorganic or organic bases are particularly suitable for use as such acceptors. These bases include, for example, alkaline earth metal or alkali metal hydroxides, such as sodium hydroxide, potassium hydroxide, calcium hydroxide, and also ammonium hydroxide, alkali metal (hydrogen)carbonates, such as sodium (hydrogen)carbonate, potassium (hydrogen)carbonate or ammonium carbonate, alkali metal or alkaline earth metal acetates, such as sodium acetate, potassium acetate, calcium acetate or ammonium acetate, alkali metal alcoholates, such as sodium or potassium methoxide, sodium or potassium ethoxide or sodium or potassium tertbutoxide, as well as tertiary amines, such as trimethylamine, triethylamine, tributylamine, N,N-dimethylaniline, pyridine, N-methylpiperidine, 4-dimethylaminopyridine, diazabicyclooctane (DABCO), diazabicyclononene (DBN) or diazabicycloundecene (DBU).

In carrying out process (c) according to the invention, the reaction temperatures can be varied over a relatively wide range. In general, temperatures of between 0° C. and 150° C., preferably temperatures of between 10° C. and 120° C., are employed.

In general, process (c) according to the invention is carried out under atmospheric pressure. However, it is also possible to carry it out under elevated or reduced pressure.

For carrying out process (c) according to the invention, the starting compounds which are required in each case are generally employed in approximately equimolar or equivalent quantities. However, it is also possible to use one of the components employed on each occasion in a relatively large excess. In general, the reaction is carried out in a suitable diluent and the reaction mixture is stirred, until the conversion is complete, at the temperature which is required in each case. The working up is effected in accordance with customary methods.

The active compounds according to the invention can be used as defoliants, desiccants, agents for destroying broad-leaved plants and, especially, as weed-killers. By weeds, in the broadest sense, there are to be understood all plants which grow in locations where they are undesired. Whether the substances according to the invention act as total or selective herbicides depends essentially on the amount used.

The active compounds according to the invention can be used, for example, in connection with the following plants:

Dicotyledon weeds of the genera: Sinapis, Lepidium, Galium, Stellaria, Matricaria, Anthemis, Galinsoga, Chenopodium, Urtica, Senecio, Amaranthus, Portulaca, Xanthium, Convolvulus, Ipomoea, Polygonum, Sesbania, Ambrosia, Cirsium, Carduus, Sonchus, Solanum, Rorippa, Rotala, Lindernia, Lamium, Veronica, Abutilon, Emex, Datura, Viola, Galeopsis, Papaver, Centaurea, Trifolium, Ranunculus and Taraxacum.

Dicotyledon cultures of the genera: Gossypium, Glycine, Beta, Daucus, Phaseolus, Pisum, Solanum, Linum, Ipomoea, Vicia, Nicotiana, Lycopersicon, Arachis, Brassica, Lactuca, Cucumis and Cucurbita.

Monocotyledon weeds of the genera: Echinochloa, Setaria, Panicum, Digitaria, Phleum, Poa, Festuca, Eleusine, Brachiaria, Lolium, Bromus, Avena, Cyperus, Sorghum, Agropyron, Cynodon, Monochoria, Fimbristylis, Sagittaria, Eleocharis, Scirpus, Paspalum, Ischaemum, Sphenoclea, Dactyloctenium, Agrostis, Alopecurus and Apera.

Monocotyledon cultures of the genera: Oryza, Zea, Triticum, Hordeum, Avena, Secale, Sorghum, Panicum, Saccharum, Ananas, Asparagus and Allium.

However, the use of the active compounds according to the invention is in no way restricted to these-genera-, but also extends in the same manner to other plants.

The compounds are suitable, depending on the concentration, for the total combating of weeds, for example on industrial terrain and rail tracks, and on paths and squares with or without tree plantings. Equally, the compounds can be employed for combating weeds in perennial cultures, for example afforestations, decorative tree plantings, orchards, vineyards, citrus groves, nut orchards, banana plantations, coffee plantations, tea plantations, rubber plantations, oil palm plantations, cocoa plantations, soft fruit plantings and hopfields, in lawns, turf and pasture-land, and for the selective combating of weeds in annual cultures.

The compounds of the formula (I) according to the invention are particularly suitable for selectively combating monocotyledonous and dicotyledonous weeds in monocotyledonous cultures, both in the pre-emergence and postemergence processes.

The active compounds can be converted into the customary formulations, such as solutions, emulsions, suspensions, powders, foams, pastes, granules, aerosols, natural and synthetic materials impregnated with active compound, and very fine capsules in polymeric substances.

These formulations are produced in a known manner, for example by mixing the active compounds with extenders, that is liquid solvents, liquified gases under pressure and/or solid carriers, optionally with the use of surface-active agents, that is emulsifying agents and/or dispersing agents and/or foam-forming agents.

In the case of the use of water as an extender, organic solvents can, for example, also be used as auxiliary solvents. As liquid solvents, there are suitable in the main: aromatics, such as xylene, toluene or alkylnaphthalenes, chlorinated aromatics or chlorinated aliphatic hydrocarbons, such as chlorobenzenes, chloroethylenes or methylene chloride, aliphatic hydrocarbons, such as cyclohexane or paraffins, for example petroleum fractions, mineral and vegetable oils, alcohols, such as butanol or glycol as well as their ethers and esters, ketones, such as acetone, methyl ethyl ketone, methyl isobutyl ketone or cyclohexanone, strongly polar solvents, such as dimethylformamide and dimethyl sulphoxide, as well as water.

As solid carriers there are suitable: for example ammonium salts and ground natural minerals, such as kaolins, clays, talc, chalk, quartz, attapulgite, montmorillonite or diatomaceous earth, and ground synthetic minerals, such as highly disperse silica, alumina and silicates; as solid carriers for granules there are suitable: for example crushed and fractionated natural rocks such as calcite, marble, pumice, sepiolite and dolomite, as well as synthetic granules of inorganic and organic meals, and granules of organic material such as sawdust, coconut shells, maize cobs and tobacco stalks; as emulsifying and/or foam-forming agents there are suitable: for example non-ionic and anionic emulsifiers, such as polyoxyethylene fatty acid esters, polyoxyethylene fatty alcohol ethers, for example alkylaryl polyglycol ethers, alkylsulphonates, alkyl sulphates, arylsulphonates as well as albumen hydrolysis products; as dispersing agents there are suitable: for example lignin-sulphite waste liquors and methylcellulose.

Adhesives such as carboxymethylcellulose and natural and synthetic polymers in the form of powders, granules or latexes, such as gum arabic, polyvinyl alcohol and polyvinyl acetate, as well as natural phospholipids, such as cephalins and lecithins, and synthetic phospholipids, can be used in the formulations. Further additives can be mineral and vegetable oils.

It is possible to use colorants such as inorganic pigments, for example iron oxide, titanium oxide and Prussian Blue, and organic dyestuffs, such as alizarin dyestuffs, azo dyestuffs and metal phthalocyanine dyestuffs, and trace nutrients such as salts of iron, manganese, boron, copper, cobalt, molybdenum and zinc.

The formulations in general contain between 0.1 and 95 percent by weight of active compound, preferably between 0.5 and 90%.

For controlling weeds, the active compounds according to the invention, as such or in the form of their formulations, can also be used as mixtures with known herbicides, finished formulations or tank mixes being possible.

Suitable herbicides for the mixtures are known herbicides, for example anilides such as, for example, diflufenican and propanil; arylcarboxylic acids such-as, for example, dichloropicolinic acid, dicamba or picloram; aryloxyalkanoic acids such as, for example, 2,4-D, 2,4-DB, 2,4-DP, fluroxypyr, MCPA, MCPP and triclopyr; aryloxy-phenoxy-alkanoic esters such as, for example, diclofop-methyl, fenoxaprop-ethyl, fluazifop-butyl, haloxyfop-methyl and quizalofop-ethyl; azinones such as, for example, chloridazon and norflurazon; carbamates such as, for example, chloropropham, desmedipham, phenmedipham and propham; chloroacetanilides such as, for example, alachlor, acetochlor, butachlor, metazachlor, metolachlor, pretilachlor and propachlor; dinitroanilines such as, for example, oryzalin, pendimethalin and trifluralin; diphenyl ethers such as, for example, acifluorfen, bifenox, fluoroglycofen, fomesafen, halosafen, lactofen and oxyfluorfen; ureas such as, for for example chlortoluron, diuron, fluometuron, isoproturon, linuron and methabenzthiazuron; hydroxylamines such as, for example, alloxydim, clethodim, cycloxydim, sethoxydim and tralkoxydim; imidazolinones such as, for example, imazethapyr, imazamethabenz, imazapyr and imazaquin; nitriles such as, for example, bromoxynil, dichlobenil and ioxynil; oxyacetamides such as, for example, mefenacet; sulphonylureas such as, for example, amidosulfuron, bensulfuron-methyl, chlorimuron-ethyl, chlorsulfuron, cinosulfuron, metsulfuron-methyl, nicosulfuron, primisulfuron, pyrazosulfuron-ethyl, thifensulfuronmethyl, triasulfuron and tribenuron-methyl; thiocarbamates such as, for example, butylate, cycloate, diallate, EPTC, esprocarb, molinate, prosulfocarb, thiobencarb and triallate; triazines such as, for example, atrazine, cyanazine, simazine, simetryn, terbutryn and terbutylazine; triazinones such as, for example, hexazinone, metamitron and metribuzin; others such as, for example, aminotriazole, benfuresate, bentazone, cinmethylin, clomazone, clopyralid, difenzoquat, dithiopyr, ethofumesate, fluorochloridone, glufosinate, glyphosate, isoxaben, pyridate, quinchlorac, quinmerac, sulphosate and tridiphane.

Mixtures with other known active compounds, such as fungicides, insecticides, acaricides, nematicides, bird repellants, plant nutrients and agents which improve soil structure, are also possible.

The active compounds can be used as such, in the form of their formulations or in the use forms prepared therefrom by further dilution, such as ready-to-use solutions, suspensions, emulsions, powders, pastes and granules.

They are used in the customary manner, for example by watering, spraying, atomizing or scattering.

The active compounds according to the invention can be applied either before or after emergence of-the plants. They can also be incorporated into the soil before sowing.

The amount of active compound used can vary within a substantial range. it depends essentially on the nature of the desired effect. In general, the amounts used are between 0.001 and 10 kg of active compound per hectare of soil surface, preferably between 0.005 and 5 kg per hectare.

The preparation and use of the active compounds according to the invention can be seen from the following examples.

The preparation and use of the active compounds according to the invention can be seen from the following examples.

Preperations examples:

EXAMPLE 1 ##STR1341## 26 ml (0.05 mol) of a 20% solution of phosgene in toluene are added dropwise, at 20° C., to a solution of 9.7 g (0.03 mol) of 1- N-(4-cyano-2-fluoro-5-i-propoxyphenyl)!-tetrahydro-(2H)-pyridazine-thiocarboxamide in 150 ml of dichloromethane. The reaction mixture is stirred at 20° C. for 3 hours and then added to about the same quantity of ice water. The organic phase is separated off, dried with magnesium sulphate and filtered. The filtrate is concentrated in a water suction vacuum and the residue is purified by column chromatography (silica gel, dichloromethane).

1.4 g (13% of theory) of 9-(4-cyano-2-fluoro-5-isopropoxy-phenyl-imino)-8-thia-1,6-diazabiazabicyclo 4.3.0!-nonan-7-one are obtained with a melting point of 108° C.

EXAMPLE 2 ##STR1342##

A solution of 3.2 g (0.08 mol) of sodium hydroxide in 10 ml of water is added, at 0° C., to a mixture of 10.8 g (0.08 mol) of 2-iminopiperidine hydrochloride and 100 ml of dichloromethane. The mixture is then stirred for one hour, after which a solution of 15.7 g (0.08 mol) of 4-cyano-2,5-difluorophenyl isothiocyanate in 150 ml of dichloromethane is added dropwise at from 0° C. to 5° C. The mixture is then stirred at room temperature for three hours. Subsequently, the reaction mixture is cooled down to -20° C. and 12.8 g (0.08 mol) of bromine in 40 ml of dichloromethane are added to it. This mixture is then stirred for three hours, after which the solid is filtered off and the filtrate is washed successively with sodium hydrogencarbonate solution and water. The organic phase is dried over magnesium sulphate and freed of solvent in vacuo. The remaining solid is recrystallized from a little acetonitrile.

3.1 g (13% of theory) of 9-(4-cyano-2,5-difluoro-phenylimino)-8-thia-1,7-diazabicyclo 4.3.0!non-6-ene are obtained with a melting point of 137° C.

The compounds of the formula (I) listed in Table 2 below, for example, can also be prepared in analogy with Examples 1 and 2 and in correspondence with the general description of the preparation processes according to the invention.

                                      TABLE 2                                      __________________________________________________________________________     Examples of compounds of the formula (I)                                                                         Melting                                      Ex.                               point                                        No.                                                                               R.sup.1                                                                          R.sup.2                                                                               A            E   G    (°C.)                                 __________________________________________________________________________     3  F NHSO.sub.2 CH.sub.3                                                                   (CH.sub.2).sub.4                                                                            C   N                                                 4  F OCH(CH.sub.3).sub.2                                                                   (CH.sub.2).sub.4                                                                            C   N                                                 5  F NHSO.sub.2 C.sub.2 H.sub.5                                                            (CH.sub.2).sub.4                                                                            C   N                                                 6  F OCH(CH.sub.3).sub.2                                                                   CH.sub.2(CH.sub.3).sub.2CH.sub.2                                                            C   N                                                 7  F F      CH.sub.2CH.sub.2CHCH                                                                        N                                                                                   ##STR1343##                                                                         85                                          8  F NHSO.sub.2 C.sub.3 H.sub.7                                                            (CH.sub.2).sub.4                                                                            C   N    140                                          9  F F      (CH.sub.2).sub.4                                                                            C   N    200                                          10 F OC.sub.2 H.sub.5                                                                      (CH.sub.2).sub.4                                                                            C   N    194                                          11 F OC.sub.2 H.sub.5                                                                      CH.sub.2CH.sub.2CHCH                                                                        N                                                                                   ##STR1344##                                                                        135                                          12 F                                                                                 ##STR1345##                                                                          CH.sub.2CH.sub.2CHCH                                                                        N                                                                                   ##STR1346##                                                                        (amorph)                                     13 F NHSO.sub.2 C.sub.2 H.sub.5                                                            (CH.sub.2).sub.4                                                                            N                                                                                   ##STR1347##                                                                        174                                          14 F NHSO.sub.2 CH.sub.3                                                                   (CH.sub.2).sub.4                                                                            N                                                                                   ##STR1348##                                                                        215                                          15 F NHSO.sub.2 C.sub.3 H.sub.7                                                            (CH.sub.2).sub.4                                                                            N                                                                                   ##STR1349##                                                                        176                                          16 F OCH(CH.sub.3).sub.2                                                                   (CH.sub.2).sub.4                                                                            N                                                                                   ##STR1350##                                                                        106                                          __________________________________________________________________________

Starting Compounds of the Formula (III) EXAMPLE (III-1) ##STR1351##

8.0 g (34 mmol) of 4-cyano-2-fluoro-5-isopropoxy-phenyl isothiocyanate are added, at 20° C. and while stirring, to a solution of 2.9 g (34 mmol) of hexahydropyridazine in 40 ml of toluene. The reaction mixture is stirred at 20° C. for 16 hours and subsequently concentrated in a water suction vacuum.

10.3 g (94% of theory) of 1- N-(4-cyano-2-fluoro-5-isopropoxy-phenyl)!-tetrahydro-(2H)-pyridazine-thio-carboxamide are obtained as an oily residue which gradually solidifies in crystalline form.

Melting point: 42° C.

                                      TABLE 3                                      __________________________________________________________________________     Example of compounds of the formula (III)                                      Ex. No.                                                                            R.sup.1                                                                          R.sup.1  A              Melting point (°C.)                       __________________________________________________________________________     III-2                                                                              F F        --CH.sub.2 --CH.sub.2 --CH.sub.2 --CH═                                                    126                                              III-3                                                                              F OC.sub.2 H.sub.4 OC.sub.2 H.sub.4 OCH.sub.3                                             --CH.sub.2 --CH.sub.2 --CH═CH--                                                            58                                              III-4                                                                              F NHSO.sub.2 CH.sub.3                                                                     --(CH.sub.2).sub.4 --                                           III-5                                                                              F OCH(CH.sub.3).sub.2                                                                     --CH.sub.2 --CH.sub.2 --CH═CH--                                                           147                                              __________________________________________________________________________

Starting Compounds of the Formula (VIII) EXAMPLE (VIII-1) ##STR1352##

7.8 g (0.04 mol) of 4-cyano-2-fluoro-5-isopropoxy-aniline in 25 ml of dichloromethane are added, at about 30° C. and while stirring, to a mixture consisting of 6 g (0.06 mol) of calcium carbonate, 30 ml of water, 6.9 g (0.06 mol) of thiophosgene and 30 ml of dichloromethane. The reaction mixture is stirred at 30° C. to 35° C. for about 18 hours. After filtration, the organic phase is then separated off, dried with magnesium sulphate and filtered. The solvent is carefully distilled off from the filtrate in a water suction vacuum.

8.4 g (89% of theory) of 4-cyano-2-fluoro-5-isopropoxyphenyl isothiocyanate are obtained as an oily residue which gradually solidifies in crystalline form.

Melting point: 73° C.

                  TABLE 4                                                          ______________________________________                                         Examples of the compounds of the formula (VIII)                                                               Melting                                         Example No.                                                                               R.sup.1   R.sup.2   point (°C.)                              ______________________________________                                         (VIII-2)   F         F          37                                             (VIII-3)   F         NHSO.sub.2 CH.sub.3                                                                      166                                             ______________________________________                                    

Starting Compounds of the Formula (X): EXAMPLE X-1 ##STR1353##

A mixture consisting of 92.4 g (0.6 mol) of 4-cyano-2,5difluoro-aniline, 60 g (0.60 mol) of methanesulphonamide, 166 g of potassium carbonate and 80 ml of N-methylpyrrolidone is heated at 180° C. for 10 hours. After having been cooled down, the mixture is stirred into 5 litres of water and the resulting solution is washed twice with 400 ml of ethyl acetate on each occasion. The aqueous phase is then overlaid with 300 ml of ethyl acetate and acidified with 10% hydrochloric acid. The product, which arises in crystalline form, is then isolated by filtering off with suction.

70 g (51% of theory) of N-(5-amino-2-cyano-4-fluorophenyl)-methanesulphonamide are obtained with a melting point of 238° C.

                  TABLE 5                                                          ______________________________________                                         Examples of the compounds of the formula (X)                                   Example No.                                                                              R.sup.1                                                                              R.sup.2         Melting point (°C.)                     ______________________________________                                         X-2       F     NHSO.sub.2 C.sub.2 H.sub.5                                     X-3       H     NHSO.sub.2 CH.sub.3                                            X-4       F     NHSO.sub.2 C.sub.3 H.sub.7 -n                                  X-5       F     NHSO.sub.2 C.sub.3 H.sub.7 -iso                                X-6       F                                                                                     ##STR1354##                                                   X-7       F                                                                                     ##STR1355##                                                   X-8       H     NHSO.sub.2 C.sub.2 H.sub.5                                     X-9       Cl    NHSO.sub.2 CH.sub.3                                             X-10     Cl    NHSO.sub.2 C.sub.2 H.sub.5                                     ______________________________________                                    

Application Examples EXAMPLE A

Post-emergence test

Solvent: 5 parts by weight of acetone Emulsifier: 1 part by weight of alkylaryl polyglycol ether

To produce a suitable preparation of active compound, 1 part by weight of active compound is mixed with the stated amount of solvent, the stated amount of emulsifier is added and the concentrate is diluted with water to the desired concentration.

Test plants which have a height of 5-15 cm are sprayed with the preparation of the active compound in such a way as to apply the particular amounts of active compound desired per unit area. After three weeks, the degree of damage to the plants is rated in % damage in comparison to the development of the untreated control.

The figures denote:

0%=no action (like untreated control)

100%=total destruction

When used in a quantity of 15 g/ha, the compound in accordance with Preparation Example 1, for example, exhibits a strong effect in this test against weeds such as Abutilon (100%), Amaranthus (80%), Chenopodium (95%), Ipomoea (100%) and Veronica (85%), while being very well tolerated by cultivated plants, such as, for example, barley (0%).

EXAMPLE B

Pre-emergence test

Solvent: 5 parts by weight of acetone Emulsifier: 1 part by weight of alkylaryl polyglycol ether

To produce a suitable preparation of active compound, 1 part by weight of active compound is mixed with the stated amount of solvent, the stated amount of emulsifier is added and the concentrate is diluted with water to the desired concentration.

Seeds of the test plants are sown in normal soil and, after 24 hours, watered with the preparation of the active compound. It is expedient to keep constant the amount of water per unit area. The concentration of the active compound in the preparation is of no importance, only the amount of active compound applied per unit area being decisive.

After three weeks, the degree of damage to the plants is rated in % damage in comparison to the development of the untreated control.

The figures denote:

0%=no action (like untreated control)

100%=total destruction

When used in a quantity of 60 g/ha, the compound in accordance with Preparation Example 1, for example, exhibits a strong effect in this test against weeds such as Aeopecurus (90%), Digiteria (95%), Abutilon 100%), Chenopodium 100%), Matricaria (100%) and Dinapis (80%), while being very well tolerated by cultivated plants, such as, for example, barley (0%).

It will be understood that the specification and examples are illustrative but not limitative of the present invention and that other embodiments within the spirit and scope of the invention will suggest themselves to those skilled in the art. 

What is claimed is:
 1. A substituted 4-cyanoaniline of the general formula (Xa) ##STR1356## wherein R¹ represents hydrogen or halogen,R⁴ represents hydrogen or alkyl, R⁵ represents alkyl, alkenyl, alkinyl, cycloalkyl, cycloalkylalkyl, aryl or arylalkyl each of which is optionally substituted, and Y represents CO or SO₂. 